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1 Exam I CHEM 1303.001 KEY Part 1. Nomenclature. 10 pts. total. 2 pts. each. FALL 2009 Fill in the names and formulas in the table below. Name Formula potassium chromate K2CrO4 chlorous acid HClO2 magnesium hydroxide Mg(OH)2 tetraarsenic pentoxide As4O5 vanadium(III) carbonate V2(CO3)3 Name Formula magnesium hydroxide Mg(OH)2 tetraarsenic pentoxide As4O5 vanadium(III) carbonate V2(CO3)3 potassium chromate K2CrO4 chlorous acid HClO2 Name Formula lithium dichromate Li2Cr2O7 chloric acid HClO3 calcium hydroxide Ca(OH)2 tetraarsenic hexasulfide As4S6 chromium(III) carbonate Cr2(CO3)3 2 Name Formula calcium hydroxide Ca(OH)2 tetraarsenic hexasulfide As4S6 chromium(III) carbonate Cr2(CO3)3 lithium dichromate Li2Cr2O7 chloric acid HClO3 Part 2. Multiple choice (use answer card). 90 pts. total. 3 pts. each. Indicate the BEST answer for the questions in this section by completely filling in the appropriate space on the answer card with a #2 pencil. Mark only one space per question. How many of the following numbers have 4 significant figures? 0.008 1.008 10.080 0.080 8.000 2 The scientist who first proposed the nuclear model of the atom after studying the scattering of alpha particles by gold foil is Rutherford. Express 3.0 × 10–6 pL in mL? 3.0 x 10–15 Isotopes of an element contain different numbers of neutrons. Aluminum has a density of 2.70 g/cm3. A sheet of aluminum foil has a mass of 1.20 g and a total area of 0.0330 m2. What is the thickness of the foil in cm? 0.00135 From the list below, which is the LEAST metallic. F 3 The alkaline-earth metals are located where in the periodic table? Group 2A A common laboratory preparation of oxygen gas is the thermal decomposition of KClO3 (molar mass = 123) to produce KCl and O2. Calculate the number of grams of O2 gas produced by the thermal decomposition of 61.5 g of KClO3. 24.0 The total number of electrons in the polyatomic CN– anion is 14 Which of the following is LEAST likely to be covalent? CaO The empirical formula of a compound is found to be CF2. If the molar mass of this compound is 200, determine the molecular formula. C4F8 All of the following elements exist naturally as diatomic molecules EXCEPT sulfur Classify the following four substances as to type of electrolyte. NH3(ammonia) NaOH C12H22O11(sucrose) NaOH, KBr are strong electrolytes; NH3 is a weak electrolyte; KBr C12H22O11 is a nonelectrolyte A compound consists of 56.64% Fe and 43.36% S by mass. Determine the empirical formula of this compound. Fe3S4 The number of atoms of Mn in 0.250 grams of Mn3O4 is 1.97 x 1021 How many atoms of F are present in 0.20 moles of SF4? 4.8 x 1023 White phosphorus exists as P4 molecules. The number of molecules of P4 that contains the same number of phosphorus atoms as 3.5 moles of Ca3(PO4)2 is 1.1 x 1024 4 For the following FOUR questions, consider the balanced reaction shown. Molar masses are given below each formula. Fe2O3(s) molar mass: + 3CO(g) 160 --> 2Fe(s) 28.0 + 3CO2(g) 55.85 44.0 How many grams of Fe will be produced from the reaction of 8.00 g of Fe2O3 with excess CO? 5.59 If the above reaction yields 2.0 g of Fe, calculate the percent yield? 35.8 If 2.00 moles of Fe2O3 are mixed with 4.00 moles of CO, how many moles of CO2 will be formed? 4.00 How many grams of the excess reagent remain unreacted in the previous question? 107 Group the following elements in pairs that you would expect to show similar chemical properties: K F P Na Cl N K and Na; F and Cl; P and N Consider the following balanced equation: Zn(s) + 2 AgNO3(aq) --> 2 Ag(s) + Zn(NO3)2(aq) The correct net ionic equation for this reaction is Zn(s) + 2 Ag+(aq) --> 2 Ag(s) + Zn2+(aq) Which of the following can act as both a Bronsted acid and base? HCO3– HPO42– NH4+ SO42– HCO3– and HPO42– ONLY Mixing of which two solutions will result in formation of a precipitate? NH4Cl (aq) BaCl2 (aq) LiS (aq) Na2CO3 (aq) KOH (aq) BaCl2 (aq) and Na2CO3 (aq) 5 How many moles of Ba(OH)2 are needed to completely neutralize 0.50 moles of H3PO4? 0.75 From the list below, which are strong acids? HCl H3PO4 HF H2SO4 HNO3 HCl, H2SO4, and HNO3 ONLY Silver, Ag, has two naturally occurring isotopes in an approximate 50:50 ratio. One of these isotopes has a mass of 108.90476 amu. Of the following, which one must be the other isotope? 107 € Ag Consider the reaction between (NH4)2S and MgCl2 in aqueous solution. Which of the following is the correct net ionic equation for this reaction? 2– 2+ S (aq) + Mg (aq) --> MgS(s) The following are properties of the element lithium. Which one is a chemical property? It generates hydrogen gas from water.