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JRE SCHOOL OF Engineering PREUNIVERSITY EXAMINATIONS MAY15 Subject Name Engineering Physics-II Roll No. of Student Date 02May 2014 All Branches Subject Code Max Marks Max Duration Time NAS-201 50 Marks 2 Hr. 10.00AM-12.00Noon Set- II SECTION – A (2x5=10) NOTE: ATTEMPT ALL QUESTIONS 1. (a) Calculate coordination number of Body centered and face centered cube. Coordination number of BCC: Case I: In case of corner atom 4 body centered atoms in the bottom plane and 4 body centered atoms in the top plane are available. Case II: In case body centered atom 4 atoms on the top plane and 4 atoms on the bottom plane are available. Therefore the coordination number in BCC is 8 Coordination number of FCC: ☼ 8 atoms are in 8 corners of a cube and 6 atoms at all 6 faces. ☼ For any corner atom the nearest atom is face centered atom. Hence for corner atom there are 4 face centered atoms in the same plane and 4 atoms above and below the plane. Therefore, the coordination number is 4 + 4 + 4 = 12 atoms (b) Differentiate magnetic materials in terms of susceptibility. For Diamagnetic materials magnetic susceptibility is negative. ( m 1) For Paramagnetic materials magnetic susceptibility is positive. ( m 1) For ferromagnetic materials magnetic susceptibility is positive and very high. ( m 1 ) (c) Write the dimensions of magnitude of pointing vector. S = E X H = Watt/ m2 or J/s m2. (d) What is Meissner effect? Meissner effect is the repulsion of all magnetic flux from the interior of a super conductor. It occurs as a result of surface current in the super conductor that produce a magnetic field which exactly opposes the applied field inside the super conductor .the super conductor behaves as if it were a perfect diamagnetic with =-1. (e) Give important applications of nanotechnology. Ans:-(1) Because of great mechanical properties of the carbon nano tube ,a variety of structure have been proposed ranging from everyday items likes clothes, and sports gear to combat jackets. (2) Nano tube based transistors have been made that operate at room temp. (3) The carbon nano tube is often used as a vessel for transporting drugs into the body..the nano tubes allows for the drug dosage to hopefully be lowered by localizing its distribution as well as significantly cut costs to pharmaceutical companies and their consumers. (4) Bulk carbon nano tubes have been used as composite fibers in polymers to improve the mechanical, thermal and electrical properties of bulk product. (5) Carbon nano tubes have also been implemented in nano electromechanical systems including mechanical memory elements and nano scale electric motors. SECTION – B (5 x 3 = 15) NOTE: ATTEMPT ANY THREE QUESTIONS 2. (a) X Rays of wavelength 0.3 Ao are incident on a crystal with a lattice spacing 0.5 Ao. Find the angles at which second and third order Bragg’s diffraction maxima are observed. Solution:- According to Bragg’s law of diffraction 2d sin θ = nλ or sin θ = n 2d λ =0.30 A0 and d = 0.5 A0 For second order maxima ,n=2 sin θ = 2 x 0 .3 0 .6 2 x 0.5 and θ = sin-1 (0.6) =36.860 For third order maxima ,n=3 Sin θ= 3 x 0 .3 0 .9 2 x 0.5 and θ = sin-1 (0.9) =64.150 (b) Calculate the ratio between electronic and ionic polarizability for a material having εr = 4.94 and n2 = 2.69. According to clausius mossotti relation r 1 N e i -------------------(1) r 2 3 0 Where αe and αi are the electronic and ionic polarizability for the given material. In optical frequency region : Therefore eqn (1) becomes έr = n2 and αi = 0 n 2 1 N e n 2 2 3 0 ------------------(2) Dividing eqn(1) by eqn(2), we get r 1 n2 2 e i . r 2 n2 1 e (4.94 1) (2.69 2) 1 i . e (4.94 2) (2.69 1) i 3.94 4.69 x 1 e 6.94 1.69 i 1.576 1 e i 0.576 e e 1.736 i (c) If the upper atmosphere of earth receives 1.38 K Wm-2 energy from the sun, what will be peak value of electric and magnetic field at the layer? Energy flux or poynting vector S is given by S E rms E xB 0 orS EB 0 E 2 rms 0c E0 2 E0 2 0 c S 0 = 4π x 10-7 Hm-1 c= 3x108 m/s and S = 1.38 x kwm-2 E0 = B0= 2 x4 x3.14 x10 7 x3x108 x1380 1.02kVm1 E0 1.02 x103 3.4 x10 6 Wbm 2 8 c 3x10 (d) For a specimen, the critical fields are 0.176 T and 0.528 T at 14 K and 12 K resp. Find transition temperature and critical fields at 0 K and 4.2 K. T 2 Solution:--- we know that Hc (T) = Hc (0) 1 Tc Given At T=14K , Hc (T)=0.176T and at T = 12 K Hc (T)= 0.528T 14 2 There fore 0.176 = Hc(0) 1 --------------(1) Tc 12 2 0.528 = Hc(0) 1 ----------------(2) Tc Equation (2) by (1) we get 2 12 1 Tc = 0.528 3 2 0.176 14 1 Tc 1 Tc = 444 2 = 14.9 K 2 Putting the value of Tc in eqn(1) we get Hc(0) 1.512 Tesla For T =4.2 K 4.2 2 Hc (T ) 221 14.9 Hc(T)= 1.51 x 0.6789 = 1.392 Tesla Ans. (e) What would be mobility of electrons in copper if there are 9x109 valence electrons per m3 and conductivity of copper is 6 x 107 mho/m ? The conductivity of metal is given by σ=neµ or ne where n is the density of the electron in metal and µ its mobility. σ= 6x 107 mho/m , n=9x109 /m3 6 x10 7 4.16 x1016 m 3 / volt sec 9 19 9 x10 x1.6 x10 Page 1 of 2 SECTION – C (5 x 5 = 25) NOTE: ATTEMPT ANY ONE PART FROM EACH QUESTIONS Q.3 (a) Show that distance between successive planes of Miller indices (hkl) for cubic lattice d hkl = a (h k 2 l 2 ) 2 Also find the interplanar spacing between successive planes in Simple Cubic Lattice. As per notes given (b) Explain the principle of x-ray diffraction. Derive Bragg’s law. How interplanar spacing and lattice are constant determined using a Bragg’s spectrometer. Bragg law identifies the angles of the incident radiation relative to the lattice planes for which diffraction peaks occurs. W.L. Bragg considered crystals to be made up of parallel planes of atoms. Incident waves are reflected specularly from parallel planes of atoms in the crystal, with each plane is reflecting only a very small fraction of the radiation, like a lightly silvered mirror. These two x-ray beams travel slightly different distances. The difference in the distances traveled is related to the distance between the adjacent layers. Connecting the two beams with perpendicular lines shows the difference between the top and the bottom beams. The length DE is the same as EF, so the total distance traveled by the bottom wave is expressed by: DE d sin EF d sin DE EF 2d sin Or n 2d sin Constructive interference of the radiation from successive planes occurs when the path difference is an integral number of wavelenghts. This is the Bragg Law. For a particular crystal Braggs reflections for three planes with spacing d 1, d2 d3 are obtained for angles θ1,θ2 and θ3 for first order then 2 d1 Sin θ1, = 2 d2 Sin θ2 =2 d3 Sin θ3 = λ Hence d1 : d2 :d3 = 1/ Sin θ1 = 1/ Sin θ2 = 1/ Sin θ3 Rewriting the Bragg law d 2 sin n which makes n-th order diffraction off (hkl) planes of spacing ‘d’ look like first-order diffraction off planes of spacing d/n. Planes of this reduced spacing would have Miller indices (nh nk nl). Q.4 (a) Define polarization. Explain different types of polarization in solids. The induced electric moment per unit volume of the dielectric is called dielectric polarization (P). The induced dipole moment μ is proportional to electric field acting on the molecule 𝐸 E E or (1) If there are N molecules per unit volume then Dielectric Polarization: P NE P N or (2) Types of Polarization: A. B. C. D. Electronic Polarization Ionic Polarization Orientational Polarization Space charge Polarization A. Electronic Polarization [Pe]: In non-polar dielectric polarizability arises due to displacement of electrons relative to nucleus by the action of electric field. At equilibrium Lorentz force = Coulomb force Ze 1( Ze)(ch arg edisplaced ) 4o d 2 The equation becomes ZeE Ze 3Ze 4R 3 4R 3 3 We know Volume charge density (3) Ze( 1 4o (4) 4d 3 ) 3 d2 Substituting 𝜌 from (4) 3Ze ) 4R 3 ) 3 4d 3 ( ZeE Ze( 1 4o d 4o R 3 Ze d2 (5) Hence induced dipole moment Zed Ze E 4o R 3 E Ze or Where e is called as Electronic Polarizability given by Hence Electronic Polarization e E e 4o R 3 Pe N e N e E (6) (7) B. Ionic Polarization [Pi]: Ionic polarization occurs in ionic crystals. On applying electric field, positive and negative charges are further separated in opposite directions. This leads to increase in separation (d). The induced dipole moment due to ionic polarization i i E Where i (8) is ionic polarizability. If there are N molecules per unit volume then Ionic polarization Pi N i N i E (9) For most of the materials, ionic polarizability is less than electronic polarizability. i 1 10 e C. Orientational Polarization [Po]: Orientational polarization occurs in polar molecules having permanent dipole moment. If there are N molecules per unit volume then Orientational polarization Po N o N o E (10) Orientational polarization is temperature dependent and frequency dependent. o o2 3kT (11) D. Space charge Polarization [Ps]: Surface, grain boundaries may be charged, i.e. they contain dipoles which may become oriented to some degree in an external field thus contributes to the polarization of the material. The contribution from space charge polarization is negligible. Hence may be ignored (b)What is local field? Derive Clausius Mossotti equation in dielectrics subjected to static field. Solution: The internal field is the electric field that acts at the site of any given atom of a solid or liquid dielectric subject to an external electric field and is the resultant of the applied field and the field due to all the surrounding dipoles. When an electric field is applied, atoms of liquid and solid become electric dipoles which produce an electric field. This field is different from the applied field. The total field at atomic site is called local (internal) field or Lorentz field Ei E P 3 0 Clausius-Mossotti relation: For non-polar dielectric, when placed in Electric field induces dipole moment 𝜇 = 𝛼 𝐸𝑖 Where 𝜇 is induced dipole moment, 𝛼 is polarizability and 𝐸𝑖 is local field. Also as per definition of Polarization if N is the number of molecules per unit volume then 𝑃 = 𝑁 𝜇 = 𝑁 𝛼 𝐸𝑖 Also Ei E P o Ei E {substituting P 3 o P P N E 3 o Therefore Polarization 1 for crystals having cubic symmetry} 3 Or P N o N 1 3 o Using the definition of Polarization P: P o ( r 1) E o E Inserting it into the above equations above gives as final result the connection between the polarizability (the microscopic quantity) and the relative dielectric constant (macroscopic quantity) N r 1 E 3 o r 1 3 Also 0 N 3 o 2 0 Named as specific Polarization of Dielectrics Q.5 (a) Write the Maxwell’s equation in differential and integral form. Explain the physical significance of each equation. (I) GAUSS LAW IN ELECTROSTATICS s 1 E .ds 0 q q dv volumech arg edensity v E 1 0 .ds Displacement current .D = έ0 E D D dv .ds dv .dI div.D ds Using Gauss divergence Theorem div.D dv dv div.D ..D It represents Gauss’s law. It is time independent or steady state equation. The flux of the lines of electric force depends upon charge density. Charge acts as a source or sink for the lines of electric force. (II) Gauss law in Magneto statics (Magnetic mono pole does not exist.) B .ds 0 div.B dv 0 Magnetic flux density div.B 0 It expresses that isolated magnetic poles do not exist. It is time independent equation and state those equal numbers of lines of magnetic induction enters and leave a given volume. There is no source or sink for lines of magnetic force. (III) Faraday law of Electro-Magnetic Induction B t B t xE curlE It relates the electric field and magnetic induction. It is a time dependent or time varying equation. It summarizes the well known Faraday’s maws or Lenz’s law of electromagnetic induction. It relates the space variation of E with the time variation of B or H. (IV) Ampere’s Law---- If H→ is the magnetic field intensity and J→ is current density H .ds J .ds Stoke' sTheorem curlH .ds J .ds curlH J It relates the magnetic field B with electric displacement vector D and the current density J. It is also time dependent equation. It represents Ampere’s law. (b) Deduce pointing theorem for the flow of energy in an electromagnetic field. Give the physical significance of each term. Poynting Theorem: Energy can be transported from one point (transmitter) to another point (receiver) by mean of electromagnetic wave .the rate of such energy transportation can be obtained from Maxwell’s equation. Electric flux density j=σ E and D= έE H (1) t E (2) t xE xH E Dotting both side of equation (2) with .E .E .(xH ) E 2 E E (3) t but .( AxB) B.(xA) A.(xB) ( A HandB E ) H .(xE) .( HxE) E 2 E E t . from equation(1) H ) ( H .H ) t 2 t H 2 1 2E ( ExH ) E 2 2 2 t 2 t H .(xE) H .( Applying volume integral both side 1 ( ExH )dv t 2 E 2 1 H 2 dv E 2 dv v 2 Applying gauss div. theorem 1 ( ExH )ds t 2 E v Total power 2 1 H 2 dv 2 rate of decrease in energy E 2 dv Ohmic power dissipated Leaving the volume stored in electric and magnetic field This equation reflect to as pointing‘s theorem. This various terms in the equation are identified using energy conservation arguments for electromagnetic field. The first term on R.H.S. is interpreted as the rate of decrease in energy stored in electric and magnetic field. Second term is power dissipated due to the fact that the medium is conducting σ ≠ 0. The quantity E x H is known as Poynting vectors in watt/m2. P= E x H Poynting theorem stated that the net power flowing out of a given volume v is equal to the time rate of decreases in energy stored with in v minus the conduction losses. Power out Stored electrical engergy. E Ohmic losses Ohmic loss σ Stored in magnetic energy Power in Q.6 (a) Explain Type I and Type II superconductor. Write a note on high temperature superconductors. Type I and Type II superconductor: The presence of a magnetic field causes the critical temperature of type I super conductor to decrease as shown in fig. If the magnetic field exceeds a certain critical value Hc. which depends on material and its temperature it super conductivity disappears altogether. Such materials are super conductor only for value of T and Hc below their suspective curves and are normal conductor for values of T and B above these curves. The critical field Hc would be maximum at 0K. Type I super conductor exist only in two states, normal and super conducting. Type II super conductor, which discovered later on usually alloys, have normal super conductor and intermediate state as well. Such materials have two critical magnetic field ,Hc 1 and Hc2 , a type II super conductor behave just like type I counter part when H<Hc ,for an applied magnetic field less than Hc1 .It is super conducting with no magnetic field in its interior. When H>Hc, a type II super conductor exhibits normal behavior, again same as a type I super conductor. However in applied field between Hc1 and Hc2 ,a type II super conductor is in a mixed state in which it contains some magnetic flux but is super conducting. The stronger external magnetic field,the more flux penetrates the materials up to the higher critical field Hc 2 . A type II super conductor behaves as though it consists of filaments of normal and of superconducting matter fixed together. A magnetic field can exist in the normal filament ,while the super conducting filaments are diamagnetic and resistanceless like type I super conductor .Because of Hc2 can be quick high, Type II super conductors are used to make high field( up to 20 tesla) magnets for particle accelerators. (b)What are nanotubes? Discuss its structure, creation, properties and applications. Carbon nano tubes (CNT’s) are sheets of graphite (Graphite is an allotropic form of pure and brittle form of carbon) up to make a tube i.e. carbon macro molecules in cylindrical form. The nano tube dimensions are variable and can be as small as 0.4 in diameters. Properties of Carbon nano tubes: CNT’s are very light, flexible, thermally stable and durable and posses extra ordinary tensile strength .CNT’s have tensile strength about 65Gpa.which is 50 times higher than sheet. They also exhibit interesting electrical properties i.e. depending on the way the graphite structure spirals around the tube .CNT’s be insulating, semiconducting or conducting. Carbon nano tubes are very hydrophobic (i.e. they do not like water) and can easily be bind to proteins. Because of this property they can serve as chemical and biological sensors. Structure of carbon nano tubes: The bonding in carbon nano tubes is sp2 the each atom joined to three neighbors similar to those in graphite structure. The tubes can therefore be considered as rolled up graphite sheets. The structure of a nano tubes can be specified by a chiral vector (n,m,) defines how the graphite sheet is rolled up, where n and m are integers of vector equation R = na1+ma2 The chiral vector can be understood. The value of n and m determines the chirality, or twist of the nano tube .The chirality affects the conductance ,density, lattice, structure and other proposed a single walled nano tube is considered metallic. If the value (n- m) is divisible by 3, otherwise nano tube is semi conducting. Consequently which nanotube are formed with random value of n and m we could expect that two-third of nano tubes would be semi conducting ,while the rest would be metallic. Given the chiral vector (n,m,).the diameter of a carbon nano tube can be determining using relation ship. d= (n2 +m2 +nm)1/2 x 0.0783nm Types of Carbon nano tubes: Depending upon the value of n and m the carbon nano tubes have been divided into following three categories -- If m = 0 nano tubes are called “zig-zag’ If n=m the nano tubes are called ‘Arm chair’ For any other combination of n and m nano tubes are called ‘chiral’ Uses of Carbon Nano tubes: i. ii. Because of great mechanical properties of the carbon nano tube ,a variety of structure have been proposed ranging from everyday items likes clothes, and sports gear to combat jackets. Nano tube based transistors have been made that operate at room temp. iii. iv. v. vi. The carbon nano tube is often used as a vessel for transporting drugs into the body..the nano tubes allows for the drug dosage to hopefully be lowered by localizing its distribution as well as significantly cut costs to pharmaceutical companies and their consumers. Bulk carbon nano tubes have been used as composite fibers in polymers to improve the mechanical, thermal and electrical properties of bulk product. Carbon nano tubes have also been implemented in nano electromechanical systems including mechanical memory elements and nano scale electric motors. Other applications including conductive and high strength composites energy storage and energy conversion devices,sensors,field emissive display and radiation sources, hydrogen storage media and nano meter sized semi conductor devices ,probes and inter connect. SWNT: Single cylindrical wall. The structure of a SWNT can be visualized as a layer of graphite, a single atom thick, called graphene, which is rolled into a seamless cylinder. Most SWNT typically have a diameter of close to 1 nm. The tube length, however, can be many thousands of times longer. SWNT are more pliable yet harder to make than MWNT. They can be twisted, flattened, and bent into small circles or around sharp bends without breaking. SWNT have unique electronic and mechanical properties which can be used in numerous applications, such as field-emission displays, nanocomposite materials, nanosensors, and logic elements. These materials are on the leading-edge of electronic fabrication, and are expected to play a major role in the next generation of miniaturized electronics. MWNT: Multi-wall nanotubes can appear either in the form of a coaxial assembly of SWNT similar to a coaxial cable, or as a single sheet of graphite rolled into the shape of a scroll. The diameters of MWNT are typically in the range of 5 nm to 50 nm. The interlayer distance in MWNT is close to the distance between graphene layers in graphite. MWNT are easier to produce in high volume quantities than SWNT. However, the structure of MWNT is less well understood because of its greater complexity and variety. Regions of structural imperfection may diminish its desirable material properties. The challenge in producing SWNT on a large scale as compared to MWNT is reflected in the prices of SWNT, which currently remain higher than MWNT. SWNT, however, have a performance of up to ten times better, and are outstanding for very specific applications. Q.7 (a) Explain why ferromagnetic materials can be permanently magnetized whereas paramagnetic ones cannot. Ferromagnetism: When you think of magnetic materials, you probably think of iron, nickel or magnetite. Unlike paramagnetic materials, the atomic moments in these materials exhibit very strong interactions. These interactions are produced by electronic exchange forces and result in a parallel or anti-parallel alignment of atomic moments. Exchange forces are very large, equivalent to a field on the order of 1000 Tesla, or approximately a 100 million times the strength of the earth's field. The exchange force is a quantum mechanical phenomenon due to the relative orientation of the spins of two electrons. The elements Fe, Ni, and Co and many of their alloys are typical ferromagnetic materials. Paramagnetism: This class of materials, some of the atoms or ions in the material has a net magnetic moment due to unpaired electrons in partially filled orbital. One of the most important atoms with unpaired electrons is iron. However, the individual magnetic moments do not interact magnetically, and like diamagnetism, the magnetization is zero when the field is removed. In the presence of a field, there is now a partial alignment of the atomic magnetic moments in the direction of the field, resulting in a net positive magnetization and positive susceptibility. In addition, the efficiency of the field in aligning the moments is opposed by the randomizing effects of temperature. This results in a temperature dependent susceptibility, known as the Curie Law. (b) Explain Fermi-Dirac probability distribution function. Obtain an expression for the electrical conductivity of an intrinsic and extrinsic semiconductor. The Fermi Level is defined as the highest occupied molecular orbital in the valence band at 0 K, so that there are many states available to accept electrons, if the case were a metal. In metals and semimetals the Fermi level EF lies inside at least one band. In insulators and semiconductors the Fermi level is inside a band gap; however, in semiconductors the bands are near enough to the Fermi level to be thermally populated with electrons or holes. The Fermi– Dirac distribution 𝑓(𝑒) gives the probability that (at thermodynamic equilibrium) an electron will occupy a state having energy e. alternatively; it gives the average number of electrons that will occupy that state given the restriction imposed by the Pauli exclusion principle. 1 𝑓(𝑒) = 1+ 𝑒 𝐸−𝐸𝑓 ( 𝑘𝑇 ) (1) Here, 𝐸𝑓 is energy in fermi level, T is the absolute temperature and k is Boltzmann's constant. If there is a state at the Fermi level (E = 𝐸𝑓 ), then this state will have a 50% chance of being occupied at any given time. AS PER GIVEN NOTE’S Semiconductors can be intrinsic or extrinsic. Intrinsic means that electrical conductivity does not depend on impurities, thus intrinsic means pure. In extrinsic semiconductors the conductivity depends on the concentration of impurities. Conduction is by electrons and holes. In an electric field, electrons and holes move in opposite direction because they have opposite charges. The current density is: J = (nμn+ pμp) eE = σE (n= electron and p= holes and σ is conductivity) σ = (nμn +pμp) e here p is the hole concentration and h the hole mobility In an intrinsic semiconductor, a hole is produced by the promotion of each electron to the conduction band. Thus for intrinsic semiconductor, n = p = ni σi = (μn + μp) ni e In semiconductor, electron- hole pairs are created. The mobility of electron is μe and that of hole is μp. The electron and holes move in opposite directions in the electric field as they are of opposite sign. For N-type semiconductor, n >> p, therefore, σn ≈ neμn ≈ Ndeμn Where Nd is concentration of donor atoms For P-type semiconductor, p>>n, therefore σp ≈ peμp ≈ NA e μp NA is concentration of acceptor atoms. ************ Page 2 of 2