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Chapter 5 Electrons In Atoms 5.1 Models of the Atom The Development of Atomic Models The model for the atom consisted of protons and neutrons making up a nucleus surrounded by electrons. The Bohr Model Bohr proposed that an ______________ is found only in specific circular paths, or orbits, around the nucleus. The fixed energies an electron can have are called __________________ levels. The fixed energy levels of electrons are somewhat like the rungs of the ladder . A ___________________ of energy is the amount of energy required to move an electron from one energy level to another energy level. The Quantum Mechanical Model The quantum mechanical model determines the allowed energies an _____________ can have and how likely it is to find the electron in various locations around the nucleus. The quantum mechanical model description of how the ___________________ moving around the nucleus is similar to the motion of a rotating propeller blade. Atomic Orbitals An _______________________ orbital is often thought of as a region of space in which there is a high probability of finding an electron. The energy levels of _____________________________ in the quantum mechanical model are labeled by principal quantum numbers (n). These are assigned the values n=1, 2, 3, 4 and so forth. 1 Each energy sublevel corresponds to an orbital of a different shape, which describes where the _____________________ is likely to be found. Four of the five kinds of d orbitals have clover leaf shapes. The lowest principal energy level (n=1) has only one sublevel, called___________ The number of electron allowed in each of the first four energy levels is shown in table 5.2 5.2 Electron Arrangement in Atoms Electron Configurations The ways in which ___________________ are arranged in various orbitals around the nuclei of atoms are called electron configurations. Three rules - the aufbau principle, the Pauli exclusion principle, and Hund's rule - tell you how to find the electron configuration of atoms. According to the _____________ principle, electrons occupy the orbitals of lowest energy first. According to the ______________ exclusion principle, an atomic orbital may describe at most two electrons. ______________ rule states that electrons occupy orbitals of the same energy in a way that makes the number of electrons with the same spin direction as large as possible. Exceptional Electron Configurations Copper has an ____________________ configuration that is an exception to the aufbau principle. You can obtain correct electron configurations for the elements up to vanadium. Some actual electron configurations differ from those assigned using the _____________ principle because half-filled sublevels are not as stable as filled sublevels, but they are more stable than other configurations. 2