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1st semester exam review Chapter 1 Vocab • Chemistry – • Mass – • Volume – • Types of data: – Qualitative – how something looks, feels, sounds, tastes, smells • Ex: – Quantitative – uses numbers • Ex: • Independent variable – in an experiment, the variable the experimenter plans to change • Dependent variable – the thing the scientist measures – Dependent on the independent variable • Control – standard for comparison, does not receive the independent variable Chapter 2: Significant Figures • all the digits that are known precisely plus one last one that is estimated. Rules for Significant Digits 1. Every nonzero digit is significant Ex. 24.7 m 2. Zeros appearing between nonzero digits are significant Ex. 24.07 m 3. Zeros after significant digits are only significant if there is a decimal point Ex. 2470 Ex. 2470.0 4. Zeros in front of numbers are NOT significant, even after a decimal point Ex. 0.0000247 Ex. 0.247 5. When a number is in scientific notation, all numbers in the coefficient are significant Ex. 2.470 x 103 Significant Digits in Calculations • An answer cannot be more precise than the least precise measurement from which it was calculated. • To round off an answer you must first decide how many significant digits the answer should have. • Your calculator DOES NOT keep track of significant digits, you have to do it! Addition & Subtraction • Answer can have no more decimal places than the number in the problem with the fewest decimal places. – Ex: 4.5 + 6.007 + 13.39 = • Correct sig figs = Multiplication & Division • Answer can have no more significant digits than the number in the problem with the fewest significant digits – Ex: 3.24 x 7.689 x 12.0 = • Correct Sig. Figs = Chapter 2 Vocab • Temperature – quantitative measurement of the average kinetic energy of the particles that make up an object • Accuracy - how close a single measurement comes to the actual dimension or true value of what is measured • Precision - how close several measurements are to the same value • Base unit – measurements that can be taken with one instrument – Time – Length – Mass – Temperature – Amount Chapter 2: Density • Density = amount of mass per unit volume – Units = • Always the same for a given substance –D= • What is the density of a cube that has a mass of 29.8 g and a volume of 4.3 cm3? • What is the mass of an object with a density of 19.32 g and a volume of 2.568 cm3? • What is the volume of an object with a mass of 13.5 g and a density of 1.4 g/mL? Chapter 2: Conversions Convert 8.96L to milliliters • Convert 525 km to cm • Convert 365 miles/hr to feet/s • Convert 15.9 m/s to km/h Chapter 3 • Solids – • Liquids – • Gas – Chapter 3: Physical Properties • Characteristic that can be observed or measured without changing the samples composition – Ex: Chapter 3: Chemical Properties • The ability of a substance to combine with or change into one or more other substances • Magic word: – Burning – Iron rusting – Inert gasses Chapter 3: Physical Changes • Alters a substance without changing its composition • Ex: Chapter 3: Chemical Changes • One or more substances changing into new substances • Chemical reactions • New substances have different composition & properties • Decompose, explode, rust, oxidize, corrode, burn Chapter 3: Mixtures • Heterogeneous mixture • Homogeneous mixture Chapter 3: Separating Mixtures • Filtration – uses a porous barrier to separate a solid from a liquid • Distillation – separates a mixture whose components have different boiling points Chapter 3: Elements and Compounds • Element – pure substance that cannot be separated into simpler substances – Found on the periodic table – Ex: • Compounds – made up of two or more elements that are chemically combined – Represented by chemical formulas – Ex: Chapter 3: Laws • Law of conservation of mass - Mass is neither created nor destroyed during a chemical reaction, it is conserved – Mass of reactants = mass of products • Law of definite proportions - A compound is always composed of the same elements in the same proportion by mass, regardless of size of the sample Chapter 4: Scientists • J.J. Thomson: – Discovered – Model = positively charged matter with electrons dispersed throughout it – Picture: • Rutherford – Discovered: – Model = atom is mostly empty space with positively charged nucleus & electrons flying around it – Picture: • Chadwick – Discovered - Chapter 4: The atom • Atom = • Structure: – Nucleus – Outside nucleus – Picture • Isotopes = Atoms with the same number of protons but different number of neutrons • Which two are isotopes of one another? P N E- 1 9 10 9 2 8 10 8 3 10 9 4 9 10 12 9 Chapter 4: Atomic Shorthand • Beryllium- - -atomic number 4 mass number 9 • The mass number is written as a superscript. • The atomic number is written as a subscript. Be Element 16 2O 8 27 13Al 80 35Br 3+ - 31 P315 39 + K 19 Atomic # Protons Neutrons Electrons Mass number Chapter 4: average atomic mass • Unknown element X has two isotopes. 6X has a 7.59 % abundance. 7X has a 92.41% abundance. What is the atomic mass of the unknown element? Chapter 5: Vocab • Amplitude: Waves height from origin to crest or origin to trough • Wavelength (λ): Shortest distance between equivalent points on a wave • Frequency (ν): number of waves that pass a given point per second Chapter 5: Problems • c = λν • What is the wavelength of a microwave that has a frequency of 3.44 x 109 Hz? • E = hv • What is the energy of a photon from violet light if it has a frequency of 7.230 x 1014 Hz • What kind of wave has a wavelength of 10-8 m? • What kind of wave has a frequency of 1014 hZ? Chapter 5: electron configurations • What are the electron configurations of the following? – Co – Kr – Ba Chapter 5: Dot Structures • Dot structures show only the valence electrons • Valence electrons determine an atoms properties • Valence electrons & group: • Draw the dot structures for the following atoms: –P – Li – Br Chapter 6: Scientists • Antoine Lavoisier – Compiled first list of elements known at the time (33 of them) – Organized elements into four categories 1. 2. 3. 4. • John Newlands – Noticed when elements were arranged by increasing atomic mass their properties repeated every 8th element • Pattern is periodic (repeats in a specific manner) – Named this the law of octaves • Dmitri Mendeleev – Arranged elements in order of increasing atomic mass into columns with similar properties • Henry Moseley – Arranged table by atomic number Chapter 6: Periodic Table • S, p, d, f block • Columns = groups – Numbered 1 – 18 – Everything in the same group has the same number of • Rows = periods – Numbered 1 – 7 • Use the electron configuration to determine the group and period of the following – [Ne]4s23d104p4 • Metals – Found: – Good conductors of heat & electricity – Malleable – Ductile • Nonmetals – Found – Poor conductors of heat and electricity • Families – Alkali metals – Alkaline earth metals – Transition metals – Halogens – Nobel gases • Which family has electron configurations that end in s2? • Which family has electron configurations that end in p5? Chapter 6: Trends • Electronegativity - The ability of an atom to attract electrons in a chemical bond – Within period – increases from left to right – Within group – decreases from top to bottom • Pick the element in each group that has the highest electronegativity – Li, B, N, O – As, Se, Sb, Te • Ionization energy - Energy required to remove an electron from a gaseous atom – Within period – increases from left to right – Within group – decreases from top to bottom • Pick the element in each group that has the lowest ionization energy – K, Ca, Se, Br – Rb, Sr, Cs, Ba • Atomic size – Within period – decreases from left to right – Within group – increases from top to bottom • Ion size: – Cations are always bigger than the neutral atom • Ex: – Anions are always smaller than the neutral atom • Ex: • In which group is the one on the left bigger than the one on the right? – F, F– Ca, Ca2+ – Li, Na – N, B Chapter 7: Vocab • Chemical bond – • Ionic compound – compound that contains ionic bonds (electrons are lost/gained) • Binary ionic compound – Chapter 7: Properties • Ionic Compounds – High melting point – High boiling point – Hard, rigid, brittle solids – Electrolytes only when dissolved or melted not when solid • Metals – High melting points – High boiling points – Malleable & ductile – Good conductors of heat and electricity Chapter 7: Ratios • Group 1 & group 17 = – Ratio • Group 2 & group 17 = – Ratio • Group 2 & group 15 = – Ratio Chapter 7: Naming • Name the following: – KOH – Ca(NO3)2 – (NH4)3PO4 • Name the following: – CuCl2 – CoN – Hg3P2 • Give the formulas for the following: – Calcium oxide – Chromium (IV) Chlorite – Sodium Nitride