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Matter and Energy - Identify a chemical physical change Identify a substance as either element compound mixture, etc Endothermic vs. exothermic 1. Physical or chemical change? You make scrambled eggs You light a candle Iron combines with oxygen to form rust Wood burn in the air Milk turns sour Crush a piece of chalk Steam from your shower condenses on the mirror Iron metal is melted A rock is broken into smaller pieces Salt dissolves in water 2. Which is an example of a homogeneous mixture? a. sand c. vegetable soup b. clean air d. fresh-squeezed orange juice 3. Which of the following is exothermic? a. Solid to liquid b. Liquid to solid c. Solid to gas d. Liquid to gas 4. Which formula represents a homogeneous mixture? a. H2O(l) b. H2S(g) c. NaH(s) d. HCl(aq) Atomic Structure - Thomson Dalton Rutherford Atomic number Mass number How to find the number of protons neutrons and electrons Isotopes Part 1 – complete the chart Atomic symbol Atomic number Mass Number Protons B Neutrons Electrons 6 11 24 31 37 39 29 89 35 43 100 207 Pb 102 70 89 Mo 225 53 Part 2 – answer the following 1. Describe Rutherford’s gold foil experiment, his conclusions, and his model of the atom. 2. Draw Thomson’s model of the atom. 3. How did the Dalton’s model of the atom look? Why did it look like that? Part 3 – multiple choice 1. Today’s model of the atom is due to a. The work of one scientist today b. The work of one scientist from a long time ago c. The work of many scientist today d. The work of many scientist over a long period of time 2. As an ion is formed, the mass number a. Increases b. Decreases c. Remains the same 3. If a neutral atom loses two electrons, the charge of the ion formed is a. -2 b. -1 c. 0 d. +1 e. +2 4. Compared to a proton, an electron a. Is smaller with the same charge b. Is larger with same charge c. Is smaller with opposite charge d. Is larger with opposite charge Modern Atomic Theory - ROYGBIV Energy, frequency Orbital Bohr model Paramagnetic vs. diamagnetic Isoelectronic Aufbau Principle Heisenberg Uncertainty Principle Hund’s rule Pauli exclusion Principle Ground and excited state Sublevels s p d f - How many p orbitals can be in an energy level? o 1 o 3 o 5 o 7 - According to the Pauli exclusion principle, o Electrons fill in lowest levels possible o Electrons will be placed in an empty orbital before pairing up to keep lowest energy possible o Orbitals can only hold 2 electrons causing no electron to have the same four quantum numbers o The exact position of the electron is unknown - Given the following electron configuration, what are possible quantum numbers for the valence electrons (in bold)? 1s22s22p1 o n=2, l=0, ml=0, ms=+1/2 o n=2, l=0, ml=0, ms=-1/2 o n=2, l=1, ml=1, ms=+1/2 o n=2, l=2, ml=-1, ms=-1/2 - Which color is associated with longest wavelength? o Red o Yellow o Green o Blue How much energy is associated with a wave that has a wavelength of 6.5x10-7 meters? Write electron configuration for Cl and draw an orbital diagram. - Periodicity - Properties of metals and nonmetals Arrangement of the table - Which element’s ionic radius is smaller than its atomic radius? o Neon o Nitrogen o Sodium o Sulftur - Which group contains a liquid non-metal at STP? o 12 o 14 o 17 o 18 - Which of these Group 14 elements has the most metallic properties? o C o Ge o Si o Sn - At STP, which substance is the best conductor of electricity? o Nitrogen o Neon o Sulfur o Silver - Boron and arsenic are similar in that they both o Have the same ionization energy o Have the same covalent radius o Are in the same family o Are metalloids Bonding - Properties of ionic and covalent Bond formation energy Polarity of bond Polarity of molecule Lewis structures Part I – Bond Types Ionic Covalent Metallic Electrons are… Between elements of… Hardness… Boiling Point… Conductivity… Example… Part II – Polarity of a Bond Polarity of a bond depends on the _______________________________ _____________________. The more polar the bond the bigger the _________________________ _____________________. Part III – Polarity of a Molecule Polarity of a molecule depend on the ______________________ of the molecule. Polar molecules are ________________________. Non-polar molecules are ____________________. It is possible to have a non-polar molecule that has polar bonds. Give an example of such a molecule. Nomenclature - How to name and write formulas - Barium oxide ___________________________________ - Iron (II) Nitride _______________________________ - Cobalt(I) carbonate _____________________________ - Iron(II) Phosphate ________________________________ - (NH4)2SO3 ___________________________________________ - Mn2(CO3)3 _______________________________________________ - Mg(ClO3)2________________________________________ - Potassium Nitrate ____________________________________ Organic Chemistry - Name Saturated and unsaturated hydrocarbons 1. Draw the structure of 3-nonyne 2. Draw the structure of butane and state whether its saturated or unsaturated. 3. Draw the structure of 2-hexene. Scientific Measurement - Scientific notation Metric conversion Significant figures (identify, rounding, calculating) Dimensional analysis How many significant figures do the following numbers have? 1) 1234 _____ 2) 0.023 _____ 3) 890 _____ 4) 91010 _____ 5) 9010.0 _____ Convert the following numbers into scientific notation: 1) 3,400 _______________________________ 2) 0.000023 _______________________________ 3) 101,000 _______________________________ Convert the following numbers into standard notation: 9) 2.30 x 104 _______________________________ 10) 1.76 x 10-3 _______________________________ 11) 1.901 x 10-7 _______________________________