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ATOMIC THEORY OF MATTER DEVELOPMENT OF ATOMIC THEORY •Matter is made up of fundamental particles called atoms 19 20 ANCIENT GREECE • Four elements DEMOCRITUS • Greek Philosopher (~ 400 B.C.) parts of matter • not divisible • **Matter was empty space and atoms. • **Each type of matter had its own type of atom • Did not test their ideas with experiments • “Atomos” smallest • Fire • Air • Water • Earth • Other Greek philosophers disagreed with Democritus 21 22 LAVOISIER’S LAW CONSERVATION OF MASS • Total mass of a reactants must be the same as mass of products • “Matter cannot be created or destroyed” • Atoms • 1782 are “recycled” PROUST’S LAW DEFINITE PROPORTIONS • Elements occur in specific ratios (proportions) in substances • Proportions • Ex: - • significance are always the same CO2 • 1799 in history?? 23 www.wise.k12.va.us/ jjk/Chemistry/dalton2.gif www.nndb.com www.wise.k12.va.us/ jjk/Chemistry/dalton2.gif 24 DALTON’S THEORY JOHN DALTON •Early • All matter is composed of tiny indivisible particles called atoms 1800s •English • All •Studied the work of Lavoisier and Proust •First complete atomic theory www.learner.org atoms of one element are exactly alike, but atoms of different elements are different from each other • Atoms are neither created or destroyed in any chemical reaction (Lavoisier) & Compounds always have the same ratio of elements (Proust). 25 26 HYPOTHESES,LAWS, THEORIES HYPOTHESES,LAWS, THEORIES • Law: • Hypothesis: • Possible explanation for an observation of something in the natural world - must be testable 27 • Observation about nature that has been repeated and is predictable. • Does not provide any explanation. 28 HYPOTHESES,LAWS, THEORIES • Theory: • Possible explanation that has been supported by a lot of observations and experiments. • Remains a valid theory until disproven. DISCOVERING PARTS OF THE ATOM SOME SCIENTISTS SUSPECTED THAT ATOMS CONTAINED EVEN SMALLER PARTICLES. THESE ARE THEIR STORIES :) 29 30 ELECTRONS • J.J. ELECTRONS Thomson • 1890s, • J.J. English Thomson • “Plum Pudding” or “Raisin Bun” model • Discovered first subatomic particle (e-) dwb.unl.edu/.../demos/jpeg/cath7.jpg 31 32 dwb.unl.edu/.../demos/jpeg/cath7.jpg CATHODE RAY TUBES • “electron” • • Thomson: calculated charge:mass ratio of e- - charge • in all matter • Also detected + rays, which lead to discovery of protons _ cathode + anode dwb.unl.edu/.../demos/jpeg/cath7.jpg 33 • Oil matter is composed of tiny indivisible particles called atoms • All atoms of one element are exactly alike, but atoms of different elements are different from each other • Atoms are neither created or destroyed in any chemical reaction & Compounds always have the same ratio of elements ELECTRONS Millikan • American • All 34 ELECTRONS • Robert DALTON’S POSTULATES Which parts of Dalton’s theory was proven incorrect… - 1909 drop experiments www-news.uchicago.edu • Discovered www-news.uchicago.edu that e- had a -1 charge 35 http://people.clarkson.edu/~ekatz/scientists/millikan_scheme2.jpg 36 AS OF 1900… ELECTRONS • Thomson • Plum Pudding Model (Cookie-dough) • Nagaoka www-news.uchicago.edu • Japan ~ same time as Rutherford that e- travel around the nucleus like planets • Proposed http://people.clarkson.edu/~ekatz/scientists/millikan_scheme2.jpg 37 THE NUCLEUS 38 GOLD FOIL EXPERIMENT • Lord Rutherford, English, 1912-1913 • Gold Foil Experiments • Atom was mostly empty space w/ solid, dense, + charged center (nucleus) 39 THE NUCLEUS • Lord Rutherford, English, • Proved NUCLEAR/Planetary MODEL OF THE ATOM 41 GOLD FOIL EXPERIMENT • Thomson NEUTRONS • discovered that 3 types of Ne atoms existed (3 different masses) • Isotopes • In order to explain the different masses of isotopes, scientist now believed there must be a 3rd particle (later called neutrons). 43 DALTON’S POSTULATES Which parts of Dalton’s theory was proven incorrect… • All matter is composed of tiny indivisible particles called atoms • All atoms of one element are exactly alike, but atoms of different elements are different from each other • Atoms are neither created or destroyed in any chemical reaction & Compounds always have the same ratio of elements 44