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Ch. 4.1 Defining the Atom Early Models of the Atom Atom—the smallest particle of an element that retains its identity in a chemical reaction. Democritus—460 B.C. – 370 B.C., believed that atoms were indivisible and indestructible…his ideas did not explain chemical behavior. Dalton’s Atomic Theory John Dalton (1766-1844)—used experimental methods to change Democritus’ ideas into a scientific theory of atoms… 1. All substances are composed of tiny indivisible particles called atoms. 2. Atoms of the same element are identical and different from other elements. 3. Atoms of different elements can physically mix, or can chemically combine in whole-number ratios to form compounds. 4. Chemical reactions occur when atoms are separated, joined, or rearranged. Atoms of one element are never changed into another element by a chemical reaction. Sizing up the Atom Very small. Average size is 5 x 10-11m to 2 x 10-10m. Individual atoms are observable with scanning tunneling electron microscopes.