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5/1/2015 4.01 – Introduction to Nutrients Bi l Biology 11 Chemistry y The branch of chemistry we will look at is biochemistry and/or organic chemistry. y We are interested in looking at organic molecules – they contain carbon (C). Hydrogen and oxygen are, also, typically, present. y In proteins, nitrogen is also present. Chemical Compounds y Compounds are formed when 2 or more elements are joined. y They join by bonding – this is represented by a bar or “line.” 1 5/1/2015 Bonding y Bonds formed between atoms can be either: a) Ionic – held together by opposite charges (like a magnet) b) Covalent – atoms share electrons to make bonds. e.g. Carbon can form 4 covalent bonds with other atoms. HONC 1234 Biochemistry y What makes different organic molecules different are what functional groups are attached to them: y Hydroxyl − OH y Carboxyl −COOH y Amino −NH2 A functional group is what gives a molecule its specific identity. Reaction Basics: 3 Classes 1. Dehydration Synthesis - carbs y Small molecules are bonded together into a larger molecule by removing water. y E.g. glucose + glucose − water = maltose Maltose syrup 2 5/1/2015 2. Hydrolysis - Carbs y Reversal of dehydration synthesis y Add water to a larger molecule to split it into smaller molecules. y E.g. Sucrose + water = glucose + fructose Sugars tend to be isomers of each other – same chemical formula but different arrangement of chemical bonds. 3. Condensation y Condensation (removal of a water molecule) links amino acids link together to form chains called polypeptides. 3 5/1/2015 Macro Nutrients y 4 main types: 1. Carbohydrates (carbs) 2. Proteins 3. Fats (lipids) 4. Nucleic Acids All of the macronutrients start as a small unit – a monomer – which will link up with other monomers to form longer chains called polymers. 4 5/1/2015 Macro Functions 1. Production of energy. 2. for growth, repair and maintenance of hard and soft tissue. 3. for regulation of the body’s processes. 1. Carbohydrates (= 4 cals) y Most important source of energy and makes up the majority of most diets. y 3 classes: A. Simple sugars – Monosaccharides: made up of single sugar molecules or chains containing many sugar molecules B. Disaccharides – sugars made up of 2 sugar molecules. E.g. sucrose (brown/white sugar) C. Polysaccharides – Complex carbs – made up of many monosaccharides E.g. starch, cellulose, glycogen 2. Lipids (= 9 cals) 3 groups of lipids: a) Fats/oils/waxes b) Phospholipids c) Steroids When glycogen stores are full in animals, excess carbs are converted into fat. They are insoluble in water. Share a common functional group as protein: carboxyl group. 5 5/1/2015 Saturated vs. Unsaturated Fatty Acids y Saturated fats – have maximum number of hydrogen atoms. y Unsaturated fats – have double bonds and not the maximum amounts of hydrogen atoms. Cholesterols 1. HDL – high-density lipoprotein – “good” 2. LDL – Low-density lipoprotein – “bad” These are groups of proteins covered with cholesterol (lipoprotein). Difference – HDL has more protein than cholesterol; LDL has less protein. Lipid Function y Excellent energy source. y Cholesterol is important in cell membranes. It also makes up male and female sex hormones. y Phospholipids make up cell membranes membranes. y Waxes create water-proof coating for plant leaves, animal feathers, or furs. y Cholesterol + other fats = plaque that blocks blood vessels. 6 5/1/2015 3. Proteins y Used by cells to build structures and used in chemical activities. y Giant molecules made up of hundreds of units called amino acids. 7 5/1/2015 Proteins y Not usually used for energy (like lipids and carbohydrates). y Not just used to build cells (muscle) y Enzymes, hormones, antibodies, and hemoglobin (molecule of the blood) are made from proteins. 4. Nucleic Acids y Nucleic acids are polymers essential for all known forms of life. y include DNA (deoxyribonucleic acid) and RNA (ribonucleic acid) y are made from monomers known as nucleotides. 8