* Your assessment is very important for improving the workof artificial intelligence, which forms the content of this project
Download 6 chapter 4 Holocene - Edinburgh Research Archive
Survey
Document related concepts
Transcript
CHAPTER 4 Holocene Variability in the intensity of the Arabian Sea Monsoon Abstract Holocene changes in the intensity of the Arabian Sea Summer Monsoon (ASSM) have been reconstructed using proxies of organic productivity, water column denitrification and lithogenic input from a Somali margin sediment core. This reconstruction indicates that the strength of the ASSM has decreased gradually over the last 10 kyr, following the decrease in precessional forcing. The early Holocene experienced the strongest monsoon winds, which are reflected by high productivity (Si/Al, P/Al Ba/Al) values, increased denitrification (δ 15N) and increased rainfall (Ti/Al). The late Holocene increase in grain size (Zr/Al, % quartz) at site 905 reflects the consequent reduction in continental moisture as the monsoon intensity diminished. Though marine proxies of monsoon strength respond gradually to the decrease in precessional forcing, terrestrial proxies of continental aridity exhibit a threshold response and indicate that the transition from the African Humid Period to the dry late Holocene was abrupt and occurred at approximately 5.5 kyr. Sub-orbital variations in monsoon intensity are superimposed upon the precessional signal with an evident periodicity of 1830 years. A comparison of the core 905 records with tropical rainfall records suggests that the strong monsoon of the early Holocene coincides with a northern position of the ITCZ and that the gradual decline in monsoon strength over the Holocene has been by accompanied by a progressive shift of the ITCZ to a more southerly position. By mediating tropical wetland emissions of methane, changes in the strength of the ASSM and the position of the ITCZ may impact atmospheric greenhouse gas concentrations. A period of decreased monsoon intensity has been identified between 8.4-7.8 kyr before present. Though the onset of this event coincides with the Northern polar 8.2 kyr event, the recovery of the monsoon occurs 2 kyr later than indicated by the Greenland (GISP2) records. Chapter 4. Holocene Variations Introduction The seasonal monsoon winds of the Arabian Sea are driven by the temperature differential between the Indian Ocean and the Asian continent. As the plateau warms in the boreal summer, the southwesterly winds flowing from the coast of Somalia over the Arabian Sea to India bring moisture laden winds onshore, resulting in heavy regional precipitation. These Southwest winds create an anti-cyclonic gyre in the Arabian Sea inducing intense upwelling off the coast of Oman, which supplies the surface waters with nutrients and supports high local productivity (Nair et al., 1989). As the land cools, winter winds become northeasterly, the precipitation over India diminishes and upwelling ceases in the western Arabian Sea. There is sound evidence that the intensity of the ASSM has fluctuated dramatically in the past, varying with precessional changes in the distribution of solar radiation reaching the earth (Clemens et al., 1991; Kutzbach, 1981; Leuschner et al., 2003). The Holocene epoch has spanned half of a precessional cycle. During this time the Northern Hemisphere has changed from having maximum seasonality approximately 11 thousand years before present (kyr BP), when the summer solstice was aligned with perihelion, to a minimum today. The tropical seasonal monsoons are highly influenced by precessional variations in insolation, resulting in a wetter tropical climate as monsoon intensity increases (Clemens et al., 1991; Kutzbach, 1981; Leuschner et al., 2003). The modern Sahara region of Africa is the largest desert on Earth. In the early Holocene, between 10 – 6 kyr BP, the same area was a region of widespread lakes and abundant vegetation (deMenocal et al., 2000; Gasse, 2000). Though the precessional-scale frequency is not detectable in a human life span, it is possible that non-linear responses to changing insolation can cause dramatic environment change on a human timescale(deMenocal et al., 2000). Throughout the last glacial period large amplitude, millennial-scale (suborbital) variation is seen globally. Both the intensity of the ASSM (Altabet et al., 2002; Leuschner et al., 2000; Schulz et al., 1998) and the interplay between the summer monsoon and winter monsoon (Porter et al., 1995) fluctuate significantly on millennial timescales. Recently, millennial-scale climate changes have been recognised in Holocene records. Although the amplitude of change is less than during the last glacial period, climate variations over the last 10 kyr are seen in the North Atlantic (Bond et al., 2001; Bond et al., 1997), throughout the Northern Hemisphere 67 Chapter 4. Holocene Variations (Haug et al., 2001; Hu et al., 2003; Noren et al., 2002; Xiao et al., 2004), the southern Hemisphere (deMenocal et al., 2000; Gasse, 2000; Russell et al., 2003) and within the Arabian Sea monsoon system (Fleitmann et al., 2003; Gupta et al., 2003; Jung et al., 2002a; Jung et al., 2003; Neff et al., 2001). Such widespread indications of climatic change during the Holocene, a period of limited ice coverage, suggest that ice discharge and freshwater inputs to the North Atlantic are not the sole force of the millennial-scale signal. Understanding millennial-scale climate variability is crucial in determining both the impact of anthropogenic actions and natural climate variability. Shorter timescale (centennial) specific events, such as the 8.2 event (Alley et al., 1997; Barber et al., 1999) have been identified in various climate proxies from terrestrial (Fleitmann et al., 2003; Hu et al., 1999) and marine sources (Haug et al., 2001) and indicate that discrete occurrences can also have widespread implications. Though believed to be initiated in the Northern Hemisphere (Barber et al., 1999), the 8.2 kyr event may have influenced change in the tropical hydrological cycle (Fleitmann et al., 2003; Haug et al., 2001). In order to determine the orbital and sub-orbital variations in the Arabian Sea monsoon over the past 10 kyr, a reconstruction of the summer monsoon intensity has been developed using proxies of productivity, water column denitrification, continental aridity and wind strength. The use of multiple proxies, all influenced by the ASSM, allows marine and terrestrial environmental signals to be compared within the same sediment core. When multiple proxies are presented together, a more detailed understanding of monsoon variations can be achieved and the discussion can be focussed on variations in the local, regional and global context. Setting of core 905 Core 905 was collected from a water depth of 1586 m during the 1993 Netherlands Indian Ocean Project (NIOP). This southwestern Arabian Sea site (10˚.46’N; 51˚.57’E) is located beneath the core of the ASSM southwesterly winds flowing from Somalia over the Arabian Sea to India and is therefore distinctly influenced by summer monsoon induced upwelling (Figure 1)(Van Weering et al., 1997). Initiated by the same low-pressure cell over Asia, northwesterly winds flow across the Arabian Peninsula entraining dust. These winds rise above the southswesterly monsoon winds and deposit sediments over the Arabian Sea. The northern limb of these northwesterly winds travels down through the Persian Gulf and 68 Chapter 4. Holocene Variations is known as the “Shamal” winds (Clemens et al., 1991; Clemens, 1998; Glennie et al., 2002b; Membery, 1983). The modern Shamal winds veer to the south and along the Arabian coast and merge with the southern limb of the northwesterly winds that travels through the Red Sea region (Figure 1). NW Shamal 905 SW monsoon Figure 1. Topographic map of the Arabian Peninsula. Site 905, Qunf Cave and the Omani Coast are identified with red diamonds. The direction of the SW summer monsoon wind (solid line) and the NW winds (dashed lines) are depicting a scenario of the Early Holocene. Today, the northeasterly winter monsoon winds are associated with low aerosol concentrations (Sirocko et al., 2000; Sirocko et al., 1991) and are not readily traceable in the 905 lithogenic record. The “inter-monsoon” northwesterly winds have a much higher dust load but only impact the sediments of the Northeast Arabian Sea (Sirocko et al., 1991). In the western Arabian Sea, where river runoff is negligible, the sedimentary records reflect the eolian transport of dust to the sea floor (Clemens, 1998; Clemens et al., 1990; Reichart et al., 1997; Shimmield et al., 1991; Sirocko et al., 2000; Sirocko et al., 1989). Therefore, although the wind patterns and dust 69 Chapter 4. Holocene Variations transport of the Arabian Sea area is complex, site 905 is ideally located to record variations in the ASSM wind intensity. At site 905 variations in the ASSM intensity can be monitored by changes in the overhead productivity (Banse, 1987; Honjo et al., 1999; Prell et al., 1981). A sediment trap study indicates that there is a seasonal frequency in the particle flux of the western basin, with over 65 % of the organic sedimentation occurring during the summer monsoon season from June to September (Nair et al., 1989; Conan and Brummer, 2000). Today both the large flux of organic matter through the water column and the poorly ventilated intermediate waters (Sarma, 2002) support a stable basin-wide OMZ between 200-1250m. Methods (see chapter 1 and appendix A) Chronology The Holocene chronology of core 905 is based on 11 AMS 14C dates from a mixed planktic foraminiferal assemblage and a comparison with the nearby U/Th dated Q5 speleothem from Oman. (see Chapter 3) Arabian Sea Monsoon Reconstruction Measurements of % Organic Carbon (% Corg) indicate that the Somali margin is a highly productive system where sedimentary % Corg values vary from 1-2.6 %. 70 Chapter 4. Holocene Variations However, the overall structure of the % Corg profile mirrors that of % CaCO3 suggesting that dilution by CaCO3, the dominant constituent of the 905 sediments, is obscuring the productivity variations of the % Corg profile (Figure 2). The CaCO3 concentrations decrease from 80 % in the early Holocene to 60 % in the youngest sediments collected (Figure 2). Figure 3. Determining biogenic silica. A. A comparison of % organic carbon, biogenic Si (% opal) (provided by E. Koning) and the Si/Al record of core 905. The arrow indicates the crustal Si/Al value of 3.1. B. A plot of Si vs. Al indicating both the influence of biogenic Si on the 905 sediments (encircled samples) and two lithogenic sources (linear relationships). Line “a” describes pre-Holocene samples. Line “b” describes samples from both the early and late Holocene. The Holocene record of productivity therefore must be compiled from addition productivity proxies: Si/Al, Ba/Al and P/Al. The Si/Al record at this site registers both variations in the biogenic Si (opal) from diatoms and other siliceous phytoplankton and lithogenic Si (Figure 3a). From the regression plot (Figure 3b), Si vs. Al, two apparent lithogenic sources to the site and the opal signal can be identified. The linear Si to Al relationships are related to samples dated between 1211 kyr and 11-10, 2.5-0 kyr. The former has a Si/Al ratio of approximately 3.6, which is slightly above the crustal average of 3.1 (Wedepohl, 1971) and likely reflects the input of coarse-grained quartz. The latter, the combined transition and late Holocene samples, have an elevated Si/Al ratio of approximately 6.4, suggesting that the lithogenic Si source is highly Si-enriched. Opal, which has no relationship with lithogenic input, generates a dispersed, non-linear mass in the Si vs. Al plot (Figure 71 Chapter 4. Holocene Variations 4), these samples all date from 9.6-2.5 kyr. The comparison of the Holocene Si/Al and opal records indicates that this intermediate Holocene period is dominated by variations in opal, which is related to an increase in overhead diatom production. Therefore throughout the mid-Holocene, from 9.6-2.5 kyr, Si/Al can be used as a proxy of productivity. Figure 4. Determining lithogenic and biogenic Ba and P. In the core 905 sediments, both Ba and P are also elevated above crustal values and show a non-linear relationship with Al (Figure 4) indicating that biogenic Ba and P are dominating the sedimentary records off this site. The Ba/Al (x10-4) and P/Al records vary from 150-600 and 0.038-0.07 respectively. Though the records are highly variable, spectral analysis indicates a large frequency peak corresponding to a period of 1830 years (Figure 5). Low Ba/Al and P/Al values of the pre-Holocene (approximately 12 kyr) are followed by a distinct increase in the early Holocene. The late Holocene values decrease to a minimum at approximately 2 kyr (Figure 6). The combined productivity records of core 905, Si/Al, Ba/Al and P/Al, indicate that the onset of the Holocene is accompanied by an increase in productivity. Sub-orbital variations in productivity are evident throughout the Holocene. At approximately 4.5 kyr, the average values of the productivity proxies begin to decline, reaching a minimum at 2 kyr before present (Figure 6). 72 Chapter 4. Holocene Variations Figure 5. Frequency analysis of the Holocene productivity proxies and the North Atlantic record of ice rafted debris. A. The frequency spectra of the N. Atlantic record of hematite stained grains (Bond et al, 1997) identifies a period of 1810 years. B. The frequency vs. power plot for the 905 P/Al and C. the frequency vs. power plot for the 905 Ba/Al record indicates a period of 1830 years is evident in both of these records. D. The frequency vs. power plot for 905 Ti/Al record. 2 10 -5 642 Ti/Al power 1828 1 10 -5 0 0.0004 0.0008 0.0012 0.0016 T i/Al frequency 73 0.002 Chapter 4. Holocene Variations 8 !15 N 7.5 7 7.5 6.5 6.5 Si/Al 6 5.5 4.5 0.065 3.5 P/Al 0.055 600 Ba/Al 0.045 400 0.035 200 0 2 4 6 8 10 12 Calendar age (kyr) Figure 6 from core 905. A. The record of denitrification indicating changes in monsoon upwelling. B. The P/Al record. C. The Si/Al record. D. The Ba/Al record. The bold line is a 3 point smooth of the data, which is in plotted in grey. The dashed lines highlight transitions in the record that are discussed in the text. Water column denitrification is enhanced through the degradation of organic matter in the intermediate waters. Upwelling, induced by the summer monsoon winds, replenishes the surface waters with this residual pool of “heavy” nitrate, which is incorporated by phytoplankton and subsequently transferred to the sediments with the flux of organic matter. Therefore, the core 905 denitrification record is used to support the productivity proxies in the generation of the Holocene Arabian Sea monsoon reconstruction as a proxy of both intermediate water suboxia and monsoon induced upwelling. The δ15N values from core 905 decrease from an early Holocene maximum of 8.1 permil to approximately 6.5 permil in the most recent sediments (Figure 6). The early Holocene (10.5-8.3 kyr) is characterized by large (0.7 permil), rapid shifts in the δ15N record over an average of approximately 7.7 permil. Beginning 74 Chapter 4. Holocene Variations at 8.3 kyr, and continuing over the following 500 years, the δ15N values drop more than 1.0 permil. A partial recovery to 7.3 permil occurs at 7.7 kyr. Between 7.6 and 5.5 kyr there is a gradual decline in the δ15N values. A plateau occurs between 5.5-3 kyr that is followed by a final decrease to late Holocene values of 6.5 permil. As with the productivity proxies, the dominant feature of the δ15N record is the sharp increase at 10 kyr, and the gradual decline to minimum values in the late Holocene. The combined productivity and denitrification records indicate that the ASSM intensity was enhanced in the Early Holocene and diminished throughout the Holocene to minimum intensity at approximately 2 kyr. 8 5.5 kyr 7.5 !15 N 0.08 7 6.5 0.075 Ti/Al 6 0.07 36 0.065 Zr/Al 28 6 20 4 % quartz %dolomite 12 2 0 0 2 4 6 8 10 Figure 7. The lithogenic records of core 905. A. The denitrification record is used as a reference to determine changes in the monsoon intensity. B. The Ti/Al (3 pt smooth) indicates changes in seasonal precipitation. Tirich soils are produced during concentrated rainfall events. C. A 3 pt smooth of the Zr/Al record indicates that coarse-grained sediments increase in the late Holocene. The black lines indicate the average value before and after the 5.5 kyr transition. D. The core 905 % quartz (black) and % dolomite (grey). The dashed black line highlights the 5.5 ky transition from Humid to Arid conditions. The dashed grey lines identify changes in the early Holocene that may be associated with eth 8.2 kyr event. 12 Calendar age (kyr) 75 Chapter 4. Holocene Variations The lithogenic records of core 905 contribute to the monsoon reconstruction by adding information relating to monsoon induced changes in the continental environment, terrestrial aridity and wind strength. The Ti/Al record, which closely resembles the records of denitrification and productivity, reaches an early Holocene maximum of 0.078 and declines to 0.07 in the most recent sediments, always remaining above the average shale value of 0.05 (Wedepohl, 1971) (Figure7). The core 905 Ti/Al values are comparable to values of 0.65-0.08 determined by Sirocko et al. (2001) and Shimmield et al. (1990) in the northern Arabian Sea. The Ti/Al record is periodically punctuated by sharp decreases between 12-10.5, 8.6-7.9, 6.6-6.2, 5.55.1 and 2.5-2 kyr (Figure 7). Frequency analysis of the Ti/Al record reveals a periodicity of 1828, which is similar to that of the productivity proxies, and a second more dominant periodicity of 642 years (Figure 5). The Zr/Al ratio has a stepwise transition at 5.5 kyr (Figure 7). Prior to 5.5 kyr the record rapidly fluctuates around a mean of ~ 20, after 5.5 kyr the frequency of variation diminishes even though larger amplitude variation occurs. The average value in the late Holocene is approximately 27 (Figure 7). The differences between the core 905 Ti/Al and Zr/Al records can be used to gain information about the monsoon variability over the last 10 kyr. The lower values of Zr/Al in the early Holocene, a period of intense monsoon activity, suggests that continental moisture is restricting the deflation of large grained sediment at this time. Zr/Al is negatively impacted by increased continental moisture but positively impacted by increased wind strength. Consequently, over the duration of the Holocene, the concentration of Zr/Al in the 905 sediments responds (in a threshold manner) to the increase in continental aridity as the monsoon intensity diminishes. However, on sub-orbital scale frequencies, relative peaks in the Zr/Al record occur during periods of relative increases in wind strength. The 905 % quartz record resembles the Zr/Al record responding to both changes in winds speed continental aridity (Figure 7). Quartz is a coarse-grained component of marine sediments (Shimmield et al., 1991; Shimmield et al., 1990) and therefore supports the use of Zr/Al as a proxy of sediment grain size. The grain size proxies of core 905 (Zr/Al, % quartz) indicate that a significant transition occurred in the local terrestrial 76 Chapter 4. Holocene Variations environment at 5.5 kyr. Prior to 5.5 kyr, monsoon related precipitation and soil moisture limited the deflation of large grained sediments. After 5.5 kyr, the terrestrial environment was arid and dusty. Conversely, the Ti/Al record indicates that higher concentrations of Ti are present in the 905 sediments during the early Holocene, when the monsoon is strong. Therefore Ti/Al and Zr/Al are not proxies of the same aspect of the monsoon system. Titanium is concentrated in tropical soils as a result of the seasonal cycle of intense rainfall (that leaches away highly reactive elements) and then intense drying (McFarlane, 1976). The Ti/Al record resembles the δ15N record of upwelling induced by the monsoon winds (Figure 7) and frequency analysis indicates periodicities of 1828 years and 642 year, the former being shared with the proxies of paleoproductivity. The 905 Ti/Al record is likely reflecting the production of Ti-rich lateritic soils and is therefore a proxy of intense monsoon rainfall. Holocene Variations in the Tropical Hydrological Cycle The seasonal migration of the position of the ITCZ determines the amount of precipitation over southern Oman, which is recorded in the δ18O record of speleothem calcite from Qunf Cave (Q5) (17°10 N, 54°18 E) (Figure 8). This record indicates that changes in precipitation rates, and therefore continental moisture, have occurred throughout the Holocene. More negative δ18O values result from an increase in precipitation when the ITCZ is overhead. When the ITCZ moves south, precipitation decreases and the δ18O values become more positive (Fleitmann et al., 2003). Changes in the ITCZ position during the Holocene are also recorded in the sedimentary record of the Cariaco Basin off the coast of Northern Venezuela (Haug et al., 2001) where increased terrestrial runoff (% Ti and % Fe) occurs during periods of high seasonal precipitation (Figure 8). A comparison between the Q5 δ18O record, the Cariaco % Ti and the core 905 δ15N record indicates that changes in the ITCZ position closely resemble changes in the intensity of the ASSM. The similarity in the overall structure and the detail between the three records suggests that changes in ITCZ precipitation, both over Asia and S. America, and monsoon driven upwelling off the Somali coast are responding to a common external forcing (Figure 8). The dominant Early Holocene maximum and gradual decrease towards the present day signifies that the precessional signal is 77 Chapter 4. Holocene Variations underlying the higher frequency changes seen in the tropical records of both ITCZ position and monsoon intensity. Variation in the strength of the global monsoon winds is associated with the precessional cycle (Clemens et al., 1991; Clemens et al., 2003; Kutzbach, 1981; Leuschner et al., 2003), which determines variations in seasonality. The “Precession of the Equinox” changes the relationship between the Earth - Sun distance and the season such that over a period of approximately 21 kyr, summer migrates through perihelion (least Earth - Sun distance) to aphelion (largest Earth - Sun distance). The relationship of monsoon intensity to the precessional cycle reflects changes in seasonal warming and the resulting variations in land-ocean temperature gradient. Figure 8. Holocene variations in the Arabian Sea Monsoon intensity and the position of the Intertropical Convergence Zone (ITCZ). A.The downcore sedimentary Ti concentrations from the Cariaco Basin (coastal Venezuela) indicating more terrestrial runoff (increased % Ti) associated with increased precipitation as the ITCZ moves to a southerly position. Decreases in % Ti and lower rainfall indicate a southerly position of the ITCZ. (Haug et al., 2001) B. The rainfall reconstruction from Qunf Cave (Oman). More negative δ18O values indicate increased rainfall (Fleitmann et al., 2003). C. The 905 δ15N record. Larger values reflect increased denitrification. D. The upwelling record of G. bulloides from coastal Oman (Gupta et al., 2003). The shaded band highlights the 8.2 kyr event. Orange lines are for visual comparison of the structure of these three records. The red dots are AMS 14 C dated samples from the 905 record. 78 Chapter 4. Holocene Variations The independent age models generated for these three sites substantiate the coherent variation in ITCZ movement and ASSM intensity throughout the Holocene. The G. bulloides upwelling record of from a coastal Omani site presented by Gupta et al. (2003) further confirms the Holocene variability of ASSM intensity (Figure 8). The 905 δ15N record provides evidence of Holocene changes in wind driven upwelling, primary productivity and water column denitrification, all variables directly related to the strength of the ASSM. The Q5 δ18O record and Cariaco % Ti show a global variation in the ITCZ position that relates to ASSM intensity, where a northern position of the ITCZ coincides with increased ASSM intensity and a southern position of the ITCZ coincides with decreased ASSM intensity. The paleorecords presented here indicate that significant change in the tropical hydrological cycle has occurred throughout the Holocene with the underlying precessional forcing being the strongest signal evident. Changes in the tropical hydrological cycles have global consequences, not only through changes in atmospheric water vapour, the most abundant greenhouse gas, but through the mediation of additional greenhouse gas emissions from tropical wetland areas. Methane (CH4), the third most abundant greenhouse gas after water vapour and carbon dioxide, has multiple natural sources as well as anthropogenic sources, the latter which have now become dominant (Wuebbles et al., 2002). A conservative estimate of the natural sources of methane indicates that tropical wetlands release approximately 100 Tg CH4/yr to the atmosphere, accounting for over 50% of the natural annual emissions (IPCC, 2001). Boreal wetlands account for approximately 21 % of naturally produced CH4, oceanic gas hydrates, termites and wild ruminants make up the balance of 28 % (Wuebbles et al., 2002). Methane is optimally produced during the anaeobic breakdown of organic matter in water-logged soils when temperatures reach 37 °C (Wuebbles et al., 2002). Therefore changes in the hydrological cycle are likely to have impacted CH4 production in tropical wetlands through changes in precipitation patterns and regional waters table levels. A comparison of the 905 δ15N record and CH4 recorded in the EPICA Dome C Antarctic ice core (Flückiger et al., 2002) and the Greenland GRIP ice core (Blunier et al., 1995) indicate that there is a close precessional-scale relationship between tropical monsoon intensity and atmospheric CH4 concentrations (Figure 9). Although methane is mixed in the atmosphere quickly, an offset between the two hemispheres exists as a 79 Chapter 4. Holocene Variations result of the higher CH4 production rate in the north (Chappellaz et al., 1993). This explains the consistently lower CH4 values in the Dome C record compared to the two GRIP records that are duplicate measurements of the same core done in two different laboratories (Flückiger et al., 2002) (Figure 9). The chronology of the Dome C and GRIP records are independent from one another and not synchronised with core 905 therefore the differences in the Early Holocene profiles of the CH4 records and the 905 δ15N are likely related to chronology discrepancies. Following the Early Holocene precessional maximum, a 20 % reduction in CH4 corresponds to the gradual decrease in monsoon strength over the last 10 kyr. After 3.2 kyr, the monsoon records and CH4 records diverge: the CH4 records increase without an identifiable monsoon increase. As atmospheric CH4 concentrations are increased through rice cultivation and other human activities, the divergence between the CH4 and monsoon records at 3.2 kyr may mark the onset of anthropogenic CH4 emissions (Ruddiman, 2003). 80 Chapter 4. Holocene Variations Though over the past 90 kyr atmospheric CH4 has varied in common with the changes in monsoon intensity (see Chapter 1) and has responded to changing temperatures over the last 400 kyr (Petit et al., 1999), anthropogenic emissions of CH4 have disrupted this balance. The modern day concentration of atmospheric CH4 is approximately 1700 ppm, more than double the concentrations seen over the last four glacial cycles (400 kyr) which ranged from 350-800 ppm. The divergence of the Holocene 905 δ15N records from the atmospheric CH4 records at 3.2 kyr supports the hypothesis of Ruddiman (2003) that anthropogenic activities prior to the industrial revolution altered greenhouse gas production and atmospheric methane concentrations. Nitrous oxide, also an important greenhouse gas, is produced within highly productive oceanic upwelling zones and terrestrial wetland areas as a by-product during both the nitrification and denitrification processes. Having both a marine and terrestrial source causes differences in the behaviour of N2O during rapid climate changes with respect to CH4 (Sowers et al., 2003). The Holocene N2O record shows very small magnitude variations that do not closely resemble either the ice core CH4 records (Flückiger et al., 2002) or the 905 reconstruction of ASSM intensity indicating that Holocene fluctuations in the multiple sources of N2O are small or are in contradiction with one another. Linear and threshold responses to Precessional forcing The Holocene Epoch, the last 10 kyr, spans half of a precessional cycle. The Early Holocene “African Humid Period”, from 10.5-6 kyr BP, has been described extensively in the literature (deMenocal et al., 2000; Gasse, 2000) (and references therein) and is once again confirmed by the 905 δ15N records (Figure 8). This period of intense summer monsoon convection is followed by a general decline in wind intensity that continues until approximately 6 kyr when a plateau or slight recovery occurs and persists until 3 kyr. At that time the hiatus in the Q5 δ18O record and the lowest values in both the 905 δ15N and the G. bulloides upwelling records (Figure 8) suggest a minimum in monsoon wind strength. This progression from maximum monsoon intensity to minimum monsoon intensity over the past 10 kyr corresponds to the precession of the equinox where June occurred at perihelion 10 kyr ago and is occurring at aphelion today. 81 Chapter 4. Holocene Variations Our understanding of how “abrupt” the transition was between the African Humid Period and the late Holocene arid environment depends on the proxy used in the reconstruction. Proxies of monsoon intensity such as the 905 δ15N and the Q5 precipitation records suggest that wind strength, upwelling and precipitation responded linearly to the decrease in insolation (Fleitmann et al., 2003). However a Holocene record of terrestrial input from the African continent to the Northern Equatorial Atlantic Ocean (deMenocal et al., 2000) suggests that an abrupt transition from moist continental conditions to arid continental conditions occurred in less than four centuries. Water level and paleo-chemistry records from Lake Abiyata (Ethiopia) indicate that a stepwise transition from freshwater to saline water occurred at 5.4 kyr (Chalie et al., 2002). The lithogenic records from core 905 confirm a stepwise transition at 5.5 kyr and indicate that the west African continental response to the decrease in the African monsoon seen by deMenocal et al. (2000) is duplicated by the east African continental response to changes in the ASSM. At 5.5 kyr the Zr/Al and % quartz records from core 905 show an increase in the average concentration compared to the Early Holocene. Rather than indicating an increase in wind strength, this mid Holocene transition appears to reflect an increase in continental aridity that allowed the deflation of larger grained sediments to be transported as dust from the Arabian Peninsula and to the Somali margin (Figure 7). The stepwise nature of the terrestrial response is likely enhanced by vegetation changes as rainfall decreased (Gasse, 2000). The contrasting scenarios depicted by the marine and terrestrial proxies highlight the need for multi-proxy reconstructions in order to understand fully how different aspects of this complex environment have responded to changing climatic conditions. Abrupt transitions in terrestrial ecosystem dynamics are likely to have significant and unpredicted impacts on human populations. The collapse of the Akkadian civilisation, living in ancient Mesopotamia (modern Syria and Iraq), occurred approximately 4 kyr before present, concurrently with a period of decreased monsoon activity and increased aridity (Cullen et al., 2000). Present day variations in monsoon activity are still associated with increased rates of human mortality whether because of drought or torrential flooding. As human induced climate change supersedes the natural variation, our understanding of ecosystem thresholds is more important today than ever. 82 Chapter 4. Holocene Variations Sub-orbital variation: Millennial-scale The productivity proxies from core 905 indicate that superimposed over the first order precessional signal (the early Holocene maximum to late Holocene minimum), is a higher frequency variation. Frequency analysis of the 905 productivity proxies indicates power corresponding to a period of 1830 kyr (Figure 5). The Ti/Al record has a period of 1828, but a sharper more dominant peak at 642 (Figure 5). Though Bond et al. (1997) reported a 1500 ± 500 year cycle, frequency analysis of their Holocene North Atlantic record of hematite stained grains indicates a dominant period of 1800 years (Figure 5). Keeling et al., (2000) proposed that variations in the physical relationship between the Earth and Moon produce a cycle of variable tidal mixing with a period of 1823 and calculated that the Earth-Moon distance was at a minimum 525, 2348, 4293, 5921, 7744, and 9640 years before present (Figure 10). At these times, the strength of tidal mixing is thought to have increased (Keeling et al., 2000). Tidal mixing provides more than half the total power for vertical mixing in the surface waters (Keeling et al., 2000). Consequently, increases in vertical mixing would incorporate deeper waters into the mixed layer and cool the surface waters. The common periodicities of 1830 from the core 905 productivity records and 1823 from the tidal cycle suggest a possible relationship between monsoon-induced upwelling and the tidal mixing of the surface ocean. Decreased values of the core 905 productivity proxies occur during the predicted times of maximum tidal mixing (Figure 10) suggesting that mixing induced changes in the Arabian Sea surface water temperature might be affecting the intensity of the ASSM. The intensity of the ASSM would likely be affected by a slight cooling in the surface waters of the Western Equatorial Pacific (WEP), a possible result of increased tidal mixing. When the easterly equatorial trade winds are strong, warm surface waters are concentrated in the WEP and are referred to as the “warm pool”. The presence of the warm pool reinforces the low pressure area over Asia that initiates the ASSM (Joseph et al., 1994; Ju et al., 1995; Krishnamurthy et al., 2003). Cooling of the WEP warm pool though enhanced tidal mixing may have decreased the intensity of the Asian low-pressure reinforcement and therefore diminished the strength of the ASSM. Liu et al. (2003) performed model simulations of the evolution of the six major monsoon systems (Asian, N. African, S. African, Australian, N. American and 83 Chapter 4. Holocene Variations S. American) during the Holocene and found that the Asian monsoon (the East Asian and Arabian Sea monsoon combined) was influenced by ocean dynamics, which complicated the insolation induced monsoon forcing. 12 16 GISP2 20 35 Be 10 24 Zr/Al 30 28 25 20 0.075 P/Al 15 0.065 10 0.055 8 !15 N 7.5 0.045 7 0.035 6.5 6 0 2 4 6 8 10 12 Calendar age (kyr) Figure 10. Tidal (lunar) forcing vs. solar forcing of the Arabian Sea Monsoon. A. The GISP2 10Be record indicating solar activity (Finkel and Nishiizuni, 1997). Note that the scale is inverted. Increased The dashed blue arrows indicate times of maximum tidal mixing as predicted by Keeling and Whorf, 2000. The dashed grey lines highlight the 8.2 kyr event. Stott et al. (2004) presents a reconstruction of Holocene variations in the sea surface temperature (SST) of the WEP from two sites, 6° N and 7° S using Mg/Ca measurements on foraminiferal CaCO3 (Figure 11). The SST decrease of 0.5 °C over the Holocene appears consistent with the decrease in precessional forcing seen in 905 δ15N record (Figure 11). As well, some detail seen in the Northern Hemisphere record 84 Chapter 4. Holocene Variations (Figure 11a) is comparable to sub-orbital variations in the ASSM. The Southern Hemisphere record however shows no obvious coherence with the intensity of the ASSM. During the late Holocene (after 5 kyr), cold SST’s in both sites coincide with periods of maximum tidal mixing. This relationship does not appear to exist in the Early Holocene. It is likely that the influence of tidal mixing is secondary to the precessional influence that dominates the early Holocene. Therefore the coherence between the cold WEP temperatures and maximum tidal mixing may only be evident during periods of reduced precessional forcing and tidal mixing does not explain the sub-orbital variations of the early Holocene. Figure 11. A comparison of the Western Equatorial Pacific Warm Pool sea surface temperatures and the intensity of the Arabian Sea summer Monsoon. A. SST determined from Mg/Ca measurements from a site 7 ºN in the warm pool and the 905 δ15N record (data is from Stott et al, 2004) B. SST determined from Mg/Ca measurements from a site 6 ºS in the warm pool and the 905 δ15N record (data is from Stott et al, 2004). Dashed lines indicate times of maximum tidal mixing. The arrows indicate error associated with the temperature records. Contrary to a lunar mechanism forcing the millennial-scale variation, a solar mechanism is more frequently suggested. Solar activity has also been employed as the mechanism generating both high latitude (Bond et al., 2001; Hu et al., 2003) and low latitude (Fleitmann et al., 2003; Jung et al., 2002b; Jung et al., 2004; Neff et al., 2001) Holocene climatic variability. Bond et al (2001) indicate that variations in solar activity, as expressed in the cosmogenic production of 14 C and 10 Be, is strongly correlated with millennial-scale variation in records of North Atlantic ice rafted debris. Higher production of 14C and 10Be occurs when solar winds decrease and solar radiation is reduced, allowing variations in solar activity to be tracked in ice core records (14C and 10Be) and tree rings (14C). 85 Chapter 4. Holocene Variations A comparison between the core 905 paleoproductivity records and the GISP2 10 Be record shows periods of increased 10 Be production (decreased solar activity) correspond to decreases in productivity identified by the P/Al record (Figure 10). A coherent relationship between monsoon intensity, determined from the core 905 δ18O record, and solar activity has also been reported by Jung et al, 2004. The record of continental aridity, Zr/Al, also decreases with enhanced 10Be production between 8-3 kyr (Figure 10) suggesting a less monsoon related precipitation at these times. As well, though detail is absent in the low-resolution % dolomite and % quartz records, decreases in these mineral concentrations at site 905 generally occur during periods of decreased solar activity. Overall, sub-orbital periods of diminished solar activity correspond with indications of reduced ASSM intensity: a decrease in productivity (P/Al), diminished wind strength (Zr/Al) and less intense seasonal rainfall (Ti/Al). It is not possible here to discern whether the ultimate forcing of millennialscale monsoon variability is lunar or solar in origin. The tropical monsoon climate is very sensitive to changes in sea surface temperature and insolation, for both affect the location and total area of tropical convection zones (Pierrehumbert, 1999). It is therefore understandable that more than one forcing mechanism will influence proxies of monsoon variability. The 905 records of marine paleoproductivity appear to show the distinct 1828 year periodicity of the tidal forcing with low productivity occurring during periods of increased tidal mixing. As well the influence of variable solar activity is evident in the productivity records. The 905 Ti/Al record has a periodicity of 1823 years but a more dominant peak with a period of 642 years and therefore does not correspond as closely with changes in tidal mixing but does resemble the higher frequency (though not regular) variation in solar activity. The differences between the land-derived proxies of continental aridity and marine upwelling and productivity signals highlight the sensitivities in the land-based and sea-based systems and suggest multiple forcings may be influencing the system. There are different implications with respect to future change, between a cyclical mechanism such as a lunar forcing and the more erratic variations in solar activity. For prediction of future monsoon variability the degree of forcing attributed to these two possibilities needs to be determined. 86 Chapter 4. Holocene Variations The 8.2 kyr event A distinct event which lasted from 8.4-8 kyr ago is recorded in the GISP2 ice core indicating a period of reduced ice accumulation, reduced atmospheric methane (Figure 9), increased fire activity, and increased dustiness disrupted the relatively stable Early Holocene period (Alley et al., 1997). This event is believed to be a result of the draining of glacial Lakes Agassi and Ojibway into Hudson Bay as the Laurentide ice sheet retreated (Barber et al., 1999). The nature of the ice core proxies, which record local, regional and global events, suggest that this event had widespread climate impacts. This is becoming more apparent as evidence of the “8.2 kyr” event is now available from North America (Dean et al., 2002; Hu et al., 1999; Schuman et al., 2002), Europe (Tinner et al., 2001) and the tropics (Fleitmann et al., 2003; Gasse, 2000; Haug et al., 2001). A centennial-scale event occurring at approximately 8.2 kyr is characterized in the Q5 δ18O and Cariaco % Ti records as a period of decreased tropical precipitation (Fleitmann et al., 2003; Gasse, 2000; Haug et al., 2001). However, these tropical records indicate that the event terminated around 7.8 kyr, making the duration of the tropical 8.2 kyr event 2 kyr longer than the polar event initiated at approximately the same time (Figure 8). Between 8.4-7.8 kyr, the decreased precipitation recorded from the tropical sites has been interpreted as a southerly shift in the position of the ITCZ (Fleitmann et al., 2003; Gasse, 2000; Haug et al., 2001). Corresponding to this shift in the ITCZ, a stepwise decrease in monsoon intensity is seen in the 905 δ15N record. The first decrease is initiated at 8.4 kyr and the second occurs at 8.2 kyr (Figure 9). The extended duration of this tropical event suggests that either that the tropical hydrological cycle, once perturbed by the fresh water input in the North Atlantic, is relatively slow to recover, or that the 8.2 kyr event identified in the Northern polar region is not directly associated with the change in the tropical hydrological cycle that occurred between 8.4-7.8 kyr before present. The 905 Ba/Al paleoproductivity record indicates a decrease in monsoon intensity and productivity from 8.5-7.8 kyr during which low 905 Ba/Al (Figure 6) values correspond to the drop in % G. bulloides seen in records from the Oman coast (Gupta et al., 2003) (Figure 8). The core 905 P/Al and Si/Al records do not show as distinct a decrease during the 8.2 kyr event. However, the Si/Al record is complicated by changes in the aluminosilicate dust input (see discussion above) and the broad 87 Chapter 4. Holocene Variations local minimum in the % opal record beginning at 8.4 kyr (Figure 3) supports a decrease in productivity during the 8.2 kyr event. A sharp increase in the core 905 Zr/Al record occurs between 8.4-8.0 kyr indicating that large grain sediments are being transported to site 905 even though the ASSM winds diminished. This is followed by a distinct low in the Zr/Al record between 8.0-7.8 kyr. As discussed above, changes in continental moisture appear to determine the 5.5 kyr transition from low to high Zr/Al values (Figure 7). The increase in Zr/Al at 8.2 kyr may also be a result of a decrease in soil moisture indicating a higher rate of sediment deflation from the nearby continent, or it might reflect a change in the wind direction. NW winds “straighten” SW monsoon weakens Figure 12. Changes in atmospheric winds patterns during the 8.2 kyr Event. The diminished summer monsoon winds move offshore from the Arabian Peninsula. The Shamal winds extend eastward, no longer impacting site 905. The southern limb of the northwesterly winds also extends, now directly influencing site 905. The orientation of sand dunes on the Arabian Peninsula suggests that during the last glacial period when the summer monsoon winds were weak and located 88 Chapter 4. Holocene Variations offshore, the Shamal winds were strong and extended beyond the coastline of the Arabian Peninsula out to the sea (Glennie et al., 2002b) (Figure 12). In contrast during the early Holocene period, when the intensity of the summer monsoon increased, the Shamal winds retreated and the Arabian coastline was influenced by the summer monsoon winds (Glennie et al., 2002a). The increase in Zr/Al and decrease in dolomite at site 905 (Figure 7) during the 8.2 kyr event may be reflecting a relative increase in the strength of the southern limb of the northwesterly winds that flow through the Red Sea region. The dolomite-rich Shamal winds, increasing in kind, would have less impact on the sediments of site 905 as they would extend eastward rather than southward (Figure 12). Conclusions Variations in the intensity of the Arabian Sea summer monsoon have occurred throughout the Holocene. These changes are evident on a variety of time scales from precessional (20 kyr) to centennial (100 years). Precessional cycles change seasonality, causing a slow transition from hot summers and cold winters to cool summers and cool winters. The resultant change in the land–sea temperature gradient drives the variations in monsoon strength. Past changes in monsoon wind strength, marine upwelling and upwelling-induced productivity are linearly related to precessional forcing, as are the atmospheric greenhouse gas (CH4, N2O) concentrations. However, the terrestrial response to the linear change in precessional forcing is abrupt, exhibiting threshold behaviour between an arid, dusty, desert environment and a humid environment. A distinct transition in continental moisture occurred at 5.5 kyr indicating the end of the Early Holocene humid period in Eastern Africa and the onset of the arid conditions apparent today. It is evident that superimposed over the precessional mid-Holocene transition out of African Humid Period is a higher frequency variation in the strength of the Arabian Sea monsoon. Changes in the monsoon intensity, as registered by the marine productivity proxies of core 905, occur with a cyclicity of approximately 1830 years, a period also seen in the Holocene sedimentary records of the N. Atlantic (Bond et al., 2001; Bond et al., 1997). This periodicity is similar to the 1823 period of tidal mixing driven by the changes in the earth- moon relationship (Keeling et al., 2000). Changes in solar activity also correlate with the paleo-productivity and lithogenic records from site 905. 89 Chapter 4. Holocene Variations An event occurring between 8.4-7.8 kyr is apparent in the 905 records of Arabian Sea monsoon variability. During this period, the intensity of the Arabian monsoon decreased. Though the onset of this tropical event corresponds to the 8.2 kyr event associated with a fresh water flux into the North Atlantic Ocean (Barber et al., 1999), the tropical event appears to endure 2 kyrs longer than the “8.2 event” identified in the Greenland ice core (GISP2) (Alley et al., 1997). The relationship between these two events is therefore uncertain. Understanding the natural Holocene variation in the strength of the ASSM or at least the variation that has occurred over the last 10 kyr, allows the prediction of future climate change to be better and more informed. As well it furthers our understanding of the mechanism driving millennial-scale changes in climate. It is well documented that a change in the tropical convection patterns are felt globally through changes in the hydrological cycle. Variations in the ASSM intensity on a millennialscale are also likely to have global repercussions, both climatically and economically. References Alley, R.B. et al., Holocene climatic instability: A prominent, widespread event 8200 yr ago. Geology, 25(6): 483-486, 1997. Altabet, M., Nitrogen isotopic evidence for micronutrient control of fractional NO3utilization in the equatorial Pacific. Limnology and Oceanography, 46(2): 368-380, 2001. Altabet, M. et al., The nitrogen isotope biogeochemistry of sinking particles from the margin of the Eastern North Pacific. Deep-Sea Research1, 46(4): 655-679, 1999. Altabet, M.A., Higgins, M.J. and Murray, D.W., The effects of millennial-scale changes in Arabian Sea denitrification on atmospheric CO2. Nature, 415: 159-162, 2002. Archer, D., Lyle, M., Rodgers, K. and Froelich, P., What controls opal preservation in the tropical deep-sea sediments. Paleoceanography, 8(1): 7-21, 1993. Banse, K., Seasonality of phytoplankton chlorophyll in the central and northern Arabian Sea. Deep Sea Research, 34: 713-723, 1987. Barber, D.C. et al., Forcing of the cold event of 8,200 years ago by catastrophic drainage of Laurentide lakes. Nature, 400: 344-348, 1999. Blunier, T., Chappellaz, J.A., Schwander, J., Stauffer, B. and Raynaud, D., Variations in atmospheric methane concentration during the Holocene epoch. Nature, 374: 4649, 1995. 90 Chapter 4. Holocene Variations Bond, G. et al., Persistent solar influence on North Atlantic climate during the Holocene. Science, 294: 2130-2136, 2001. Bond, G. et al., A pervasive millennial-scale cycle in North Atlantic Holocene and glacial climates. Science, 278: 1257-1266, 1997. Brummer, G.J.A., Kloosterhuis, H.T. and Helder, W., Monsoon-driven export fluxes and early diagenesis of particulate nitrogen and its d15N across the Somali margin. In: P.D. Clift, D. Kroon, C. Gaedicke and J. Craig (Editors), The tectonic and Climatic Evolution of the Arabian Sea Region. Special Publications. Geological Society, London, pp. 353-370, 2002. Brumsack, H.J. and Geiskes, J.M., Interstitial water trace element chemistry of laminated sediments from the Gulf of California, Mexico. Marine Chemistry, 14: 89106, 1983. Calvert, S.E. and Fontugne, M.R., On the late Pleistocene-Holocene sapropel record of climatic and oceanographic variability in the eastern Mediterranean. Paleoceanography, 16(1): 78-94, 2001. Calvert, S.E. and Pedersen, T.F., Geochemistry of recent toxic and anoxic marine sediments: Implication for the geological record. Marine Geology, 113: 67-88, 1993. Chalie, F. and Gasse, F., Late Glacial-Holocene diatom record of water chemistry and lake level change from the tropical East African rift lake Abiyata (Ethiopia). Palaeogeography, Palaeoclimatology, Palaeoecology, 187: 259-283, 2002. Chappellaz, J.A., Fung, I.Y. and Thompson, A.M., The atmospheric methane increase since the last glacial maximum (1) Source estimates. Tellus Series B, 45b: 228-241, 1993. Clemens, S., Prell, W., Murray, D., Shimmield, G. and Weedon, G., Forcing mechanisms of the Indian Ocean monsoon. Nature, 353: 720-725, 1991. Clemens, S.C., Dust response to seasonal atmospheric forcing: proxy evaluation and calibration. Paleoceanography, 13(5)1998. Clemens, S.C. and Prell, W.L., Late Pleistocene variability of Arabian Sea summer monsoon winds and continental aridity: eolian records from the lithogenic components of deep sea sediments. Paleoceanography, 5(2): 109-145, 1990. Clemens, S.C. and Prell, W.L., A 350,000 year summer-monsoon multi-proxy stack from the Owens Ridge, northern Arabian Sea. Marine Geology, 201: 35-51, 2003. Cullen, H.M. et al., Climate change and the collapse of the Akkadian empire: Evidence from the deep sea. Geology, 28(4): 379-382, 2000. Dean, W., Gardner, J.V. and Piper, D.Z., Inorganic geochemical indicators of glacial interglacial changes in productivity and anoxia on the California continental margin. Geochimica Cosmochimica Acta, 61(21): 4507-4518, 1997. 91 Chapter 4. Holocene Variations Dean, W.E., Forester, R.M. and Bradbury, J.P., Early Holocene change in atmospheric circulation in the Northern Great Plains: an upstream view of the 8.2 ka cold event. Quaternary Science Reviews, 21: 1763-1775, 2002. Delaney, M.L., Phosphorus accumulation in marine sediments and the oceanic phosphorus cycle. Global Biogeochemical Cycles, 12: 563-572, 1998. deMenocal, P. et al., Abrupt onset and termination of the African Humid period: rapid climate responses to gradual insolation forcing. Quaternary Science Reviews, 19: 347-361, 2000. Dymond, J. and Collier, R., Particulate barium fluxes and their relationships to biological productivity. Deep-Sea Research II, 43(4-6): 1283-1308, 1996. Dymond, J., Suess, E. and Lyle, M., Barium in deep-sea sediment: A geochemical proxy for paleoproductivity. Paleoceanography, 7(2): 163-181, 1992. Finkel, R.C. and K. Nishiizuni, Beryllium 10 concentrations in the Greenland Ice Project 2 ice core from 3-40 ka. Journal of Geophysical Research, 102:26699-26706, 1997. Fleitmann, D. et al., Holocene forcing of the Indian monsoon recorded in a stalagmite from southern Oman. Science, 300: 1737-1739, 2003. Flückiger, J., Monnin, E., Stauffer, B., Schwander, J. and Stocker, T.F., Highresolution Holocene N2O ice core records and its relationship with CH4 and CO2. Global biogeochemical cycles, 16(1, 1010): 10.29/2001GB001417, 2002. Frogley, M.R., Tzedakis, P.C. and Heaton, T.H.E., Climate variability in Northwest Greece during the last interglacial. Science, 285: 1886-1889, 1999. Ganeshram, R.S., Francois, R., Commeau, J. and Brown-Leger, S.L., An experimental investigation of barite formation in seawater. Geochimica et Cosmochimica Acta, 67(14): 2599-2605, 2003. Ganeshram, R.S. and Pedersen, T.F., Glacial-interglacial variability in upwelling and bioproductivity off NW Mexico: Implications for Quaternary paleoclimate. Paleoceanography, 13(6): 634-645, 1998. Ganeshram, R.S., Pedersen, T.F., Calvert, S.E. and Murray, J.W., Large changes in oceanic nutrient inventories from glacial to interglacial periods. Nature, 376: 755-758, 1995. Gasse, F., Hydrological changes in the African tropics since the last glacial maximum. Quaternary Science Reviews, 19: 189-211, 2000. Glennie, K.W. and Singhvi, A.K., Event stratigraphy, paleoenvironment of chronology. Quaternary Science Reviews, 21: 853-869, 2002a. 92 Chapter 4. Holocene Variations Glennie, K.W., Singhvi, A.K., Lancaster, N. and Teller, J.T., Quaternary climatic changes over southern Arabia and the Thar Desert, India. In: P.D. Clift, D. Kroon, C. Gaedicke and J. Craig (Editors), The Tectonic and Climatic Evolution of the Arabian Sea Region. Special Publications. Geological Society, London, pp. 301-316, 2002b. Gupta, A.K., Anderson, D.M. and Overpeck, J.T., Abrupt changes in the Asian southwest monsoon during the Holocene and their links to the north Atlantic Ocean. Nature, 421: 354-356, 2003. Haug, G.H., Hughen, K.A., Sigman, D.M., Petersen, L.C. and Rohl, U., Southward migration of the Intertropical Convergence Zone through the Holocene. Science, 293(5533): 1304-1308, 2001. Honjo, S., Dymond, J., Prell, W. and Ittekot, V., Monsoon-controlled export fluxes to the interior of the Arabian Sea. Deep-Sea Research II, 46: 1859-1902, 1999. Hu, F.S. et al., Cyclic variation and solar forcing of Holocene Climate in the Alaskan Subarctic. Science, 301: 1890-1893, 2003. Hu, F.S. et al., Abrupt changes in North American climate during the early Holocene times. Nature, 400: 437-439, 1999. Ivanochko, T.S. and Pedersen, T.F., Determining the influences of Late Quaternary ventilation and productivity variations on Santa Barbara Basin sedimentary oxygenation: a multi-proxy approach. Quaternary Science Reviews, 23(3-4): 467-480, 2004. Joseph, P.V., Eischeid, J.K. and Pyle, R.J., Interannual variability of the onset of the Indian summer monsoon and its association with atmospheric features, El Niño, and sea surface temperature anomalies. Journal of Climate, 7: 81-105, 1994. Ju, J. and Slingo, J., The Asian monsoon and ENSO. Quarterly Journal of the Royal Meteorological Society, 121: 1133-1168, 1995. Jung, S.J.A., Davies, G.R., Ganssen, G. and Kroon, D., Decadal-centennial scale monsoon variations in the Arabian Sea during the Early Holocene. Geochemistry, Geophysics, Geosystems, 3(10): doi:10.1029/2002GC000348, 2002a. Jung, S.J.A. et al., Centennial-millennial-scale monsoon variations off Somalia over the last 35 ka. In: P. Clift, D. Kroon, C. Gaedicke and J. Craig (Editors), The tectonic and climatic evolution of the Arabian Sea region. The Geological Society London, London, pp. 341-352, 2002b. Kamatani, A. and Oku, O., Measuring biogenic silica in marine sediments. Marine Chemistry, 68(3): 219-229, 2000. Keeling, C.D. and Whorf, T., The 1,800-year oceanic tidal cycle: A possible cause of rapid climate change. Proceedings of the National Academy of Sciences on the United States of America., 97(8): 3824-3819, 2000. 93 Chapter 4. Holocene Variations Koning, E. et al., Selective preservation of upwelling-indicating diatoms in sediments off Somalia, NW Indian Ocean. Deep-Sea Research I, 48: 2473-2495, 2001. Krishnamurthy, V. and Kirtman, B.P., variability of the Indian Ocean: Relation to monsoon and ENSO. Q.J.R. Meteorol. Soc., 129: 1623-1646, 2003. Kutzbach, J.E., Monsoon climate of the early Holocene: Climate experiment with the Earth's orbital parameters for 9000 years ago. Science, 214: 59, 1981. Leuschner, D.C. and Sirocko, F., The low-latitude monsoon climate during Dansgaard-Oeschger cycles and Heinrich events. Quaternary Science Reviews, 19: 243-254, 2000. Leuschner, D.C. and Sirocko, F., Orbital insolation forcing of the Indian monsoon-a motor for global climate change. Palaeogeography, Palaeoclimatology, Palaeoecology, 197: 83-95, 2003. McFarlane, M.J., Laterite and Landscape. Academic Press Inc., London, 151 pp, 1976. McManus, J., Berelson, W.M., Klinkhammer, J.P., Kilgore, T.E. and Hammond, D.E., Remobilization of barium in continental margin sediments. Geochimica et Cosmochimica Acta, 58(22): 4899-4907, 1994. McManus, J. et al., Early diagenesis of biogenic opal: Dissolution rates, kinetics, and paleoceanographic implications. Deep-Sea Research II, 42(2-3): 871-903, 1995. Membery, D.A., Low level wind profiles during the Gulf Shamal. Weather, 38: 18-24, 1983. Nair, R.R. et al., Increased particle flux to the deep ocean related to monsoons. Nature, 338: 749-751, 1989. Neff, U. et al., Strong coherence between solar variability and the monsoon in Oman between 9 and 6 kyr ago. Nature, 411: 290-293, 2001. Noren, A.J., Bierm, P.R., Steig, E.J., Lini, A. and Southon, J., Millennial-scale storminess variability in the northeastern United States during the Holocene epoch. Nature, 419: 821-823, 2002. Petit, J.R. et al., Climate and atmospheric history of the past 420,000 years from the Vostok ice core, Antarctica. Nature, 399(6735): 429-436, 1999. Pierrehumbert, R.T., Subtropical water vapour as a mediator of rapid global climate change. In: P.U. Clark, R.S. Webb and L.D. Keigwin (Editors), Mechanisms of Global Climate Change at Millennial Time Scales1999. Pilskaln, C. and Pike, J., Formation of Holocene sedimentary laminae in the Black sea and the role of the benthic flocculent layer. Paleoceanography, 16(1): 1-19, 2001. 94 Chapter 4. Holocene Variations Porter, S.C. and An, Z.S., Correlation between climate events in the North Atlantic and China during the last glaciation. Nature, 375: 305-308, 1995. Prell, W. and Curry, W.B., Faunal and isotopic indices of monsoonal upwelling: Western Arabian Sea. Oceanologia Acta, 4: 91-98, 1981. Pride, C. et al., Nitrogen isotopic variation in the Gulf of California since the last deglaciation: Response to global climate change. Paleoceanography, 14(3): 397-409, 1999. Pye, K., Processes of fine particle formation, dust source regions, and climatic changes. In: M. Leinen and M. Sarnthein (Editors), Paleoclimatology and Paleometerology: Modern and Past Patterns of Global Atmospheric Transport. Series C: Mathematical and Physical Sciences. Kluwer Academic, Dordrecht, The Netherlands, pp. 909, 1989. Ragueneau, O. et al., A review of the Si cycle in the modern ocean: recent progress and missing gaps in the application of biogenic opal as a paleoproductivity proxy. Global and Planetary Change, 26(4): 317-365, 2000. Rea, D.K., the paleoclimatic record provided by eolian deposition in the deep sea: The geologic history of wind. Reviews of Geophysics, 32(2): 159-195, 1994. Reichart, G.J., den Dulk, M., Visser, H.J., van der Weijden, C.H. and Zachariasse, W., A 225 kyr record of dust supply, paleoproductivity, and the oxygen minimum zone from the Murray Ridge (northern Arabian Sea). Palaeogeography, Paleoclimatology, Palaeoecology, 134: 149-169, 1997. Reichart, G.J., Schenau, S.J., de Lange, G.J. and Zachariasse, W.J., Synchroneity of oxygen minimum zone intensity on the Oman and Pakistan margins at subMilankovitch time scales. Marine Geology, 185: 403-415, 2002. Rohling, E.J. et al., African monsoon variability during the previous interglacial maximum. Earth and Planetary Science Letters, 202: 61-72, 2002. Ruddiman, W.F., The anthropogenic greenhouse era began thousands of years ago. Climate Change, 61: 261-293, 2003. Russell, J.M., Johnson, T.C. and Talbot, M.R., A 725 year cycle in the climate of central Africa during the late Holocene. Geology, 31(8): 677-680, 2003. Sarma, V.V.S.S., An evaluation of the physical and biogeochemical processes regulating the perennial suboxic conditions in the water column. Global Biogeochemical Cycles, 16(4): 1082, doi:10.1029/2001GB001461, 2002. Schulz, H., von Rad, U. and Erlenkeuser, H., Correlation between Arabian Sea and Greenland climate oscillations of the past 110,000 years. Nature, 393(6680): 54-57, 1998. 95 Chapter 4. Holocene Variations Schuman, B., Bartlein, P., Logar, N., Newby, P. and Webb, T.I., Parallel climate and vegetation responses to the early Holocene collapse of the Laurentide Ice sheet. Quaternary Science Reviews, 21(1793-1805): 1793-1805, 2002. Shimmield, G.B. and Mowbray, S.R., The inorganic geochemical record of the northwest Arabian Sea: A history of productivity variation over the last 400 ky from sites 722 and 724. In: W.L. Prell and N. Niitsuma (Editors), Proceesing of the Ocean Drilling Program, Scientific Results. Ocean Drilling Program, College Station, pp. 409-429, 1991. Shimmield, G.B., Mowbray, S.R. and Weedon, G.P., A 350ka history of the Indian southwest monsoon- Evidence from deep-sea cores, northwest Arabian Sea. Transactions of the Royal Society of Edinburgh: Earth Sciences., 81: 289-299, 1990. Sirocko, F., Garbe-Schönberg, D. and Devey, C., Processes controlling trace element geochemistry of Arabian Sea sediments during the last 25,000 years. Global and Planetary Change, 26: 217-303, 2000. Sirocko, F. and Lange, H., Clay-mineral accumulation rates in the Arabian Sea during the Late Quaternary. Marine Geology, 97: 105-119, 1991. Sirocko, F. and Sarnthein, M., Wind-borne deposits in the northwestern Indian Ocean: records of Holocene sediments versus modern satellite data. In: M. Leinen and M. Sarnthein (Editors), Paleoclimatology and Paleometerology: Modern and Past Patterns of Global Atmospheric Transport. Series C: Mathematical and Physical Sciences. Kluwer Academic, Dordrecht, The Netherlands, pp. 909, 1989. Sirocko, F. et al., Century-scale events in monsoonal climate over the past 24,000 years. Nature, 364: 322-324, 1993. Sowers, T., Alley, R.B. and Jubenville, J., Ice core records of atmospheric N2O covering the last 106,000 years. Science, 301: 945-948, 2003. Stott, L. et al., Decline of surface temperature and salinity in the western tropical Pacific Ocean in the Holocene epoch. Nature, 431: 56-59, 2004. Tinner, W. and Lotter, A.F., Central European vegetation response to abrupt climate change at 8.2 ka. Geological Society of America, 29(6): 551-554, 2001. Van Weering, T.C.E. and Helder, W., The Netherland Indian Ocean Expedition199201993, first results and an introduction. Deep Sea Research II, 44(67): 1177-1193, 1997. Wedepohl, K.H., Environmental influences on chemical composition of shales and clays. Physics and Chemistry of the Earth, 8. Pergamon, Oxford, 307-331 pp, 1971. Wuebbles, D.J. and Hayhoe, K., Atmospheric methane and global change. EarthScience Reviews, 57: 177-210, 2002. 96 Chapter 4. Holocene Variations Xiao, J. et al., Holocene vegetation variation in the Daihai Lake region of northcentral China: a direct indication of the Asian Monsoon climatic history. Quaternary Science Reviews, 23: 1669-1679, 2004. 97