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Symposium no. 21 Paper no. 2215 Presentation: poster Parent material and world soil distribution GRAY Jonathan and MURPHY Brian NSW Department of Land and Water Conservation, 10 Valentine St, Parramatta, NSW 2150, Australia Abstract This paper examines the role of parent material in soil distribution. Parent material is divided into ten categories based on chemical composition, chiefly silica and calciumferromagnesium content. The influence of parent material on various key soil properties is discussed, including chemical fertility, texture, sodicity, salinity level, acidity, structure, shrink/swell potential, erodibility and profile thickness. The modelling of world soil types (using the World Reference Base scheme) under various parent material, climate and drainage regimes is attempted. The model aids in the prediction of likely soil types occurring in most world environments. Keywords: parent material, soil properties, soil distribution, modelling Introduction It has long been recognised that parent material has a major influence on the physical and chemical properties of soils. It is one of the five traditionally recognised factors of soil formation, the others being climate, topography, organic material and time. Broadly speaking, parent material is considered to provide the primary raw material upon which the other influencing factors will serve to modify. This paper examines how and why parent material influences soil properties and soil distribution. It attempts to model soil distribution under different parent material and environmental regimes. Parent material was taken as including primary bedrock and also secondary material such as alluvial, aeolian and colluvial deposits. Materials and Methods The study extensively utilised existing published material. This included material dealing specifically with the influence of parent material on soil properties, such as Jenny (1941 , 1980), Whiteside (1953), Brewer (1954), Bear (1969), Chesworth (1973), FitzPatrick (1980), and Paton et al. (1995). Also important were general publications on soil distribution such as Stace et al. (1968), Isbell et al. (1997), ISSS Working Group (1998, 1998b) and Charman and Murphy (2000) and published chemical analyses of major rock types, particularly Joplin (1965), Krauskopf (1979) and Best (1982). Another important source of data was the NSW Department of Land and Water Conservation's Soil and Land Information System (SALIS) soils database, from which data from over 8,000 soil profiles were analysed to derive statistical correlations between soil types, parent material, climate and drainage. These correlations (based on the Australian Soil Classification system) were presented in a series of over 50 charts in Gray and Murphy (1999). 2215-1 GRAY & MURPHY 17th WCSS, 14-21 August 2002, Thailand In addition to these sources, the authors also considered whether the relationships formulated were consistent with theoretical first principles of chemistry and soil science. Results and Discussion Classification of parent material for pedologic purposes For most pedologic purposes, including the modelling of soil properties and soil distribution, the most important feature of the parent material is considered its chemical composition. Physical properties such as grainsize or the presence of layering are considered only of secondary importance. The most useful criteria are silica content (SiO2) and calcium-ferromagnesium (Ca-Fe-Mg) oxide content. These criteria allow parent material to be categorised in terms of their siliceous (ie, high in silica, low in calcium-ferromagnesium) or mafic (low in silica, high in calcium-ferromagnesium) character. The more siliceous the parent material the greater the level of free quartz, the lower the clay forming potential and the lower will be the calcium-ferromagnesium content and cation exchange capacity (or "activity") of the clays. These properties have a major influence on any derivative soils. Ten categories of parent material are identified, as shown in Table 1. The first six categories are defined by silica and calcium-ferromagnesium content while the last four categories are defined by other properties. The average chemical composition of a range of igneous, sedimentary and metamorphic rocks, corresponding to these different parent material categories is given in Table 2. Average trace element contents for a range of these materials is given in Table 3. Influence of parent material on specific soil properties From a consideration of the chemical and physical properties of different parent materials, principles of soil science and the correlations derived from the SALIS database, it is possible to draw conclusions on how parent material will influence various specific soil properties. Chemical fertility Parent material is a major source of most nutrients necessary for plant growth, with the notable exceptions of oxygen, hydrogen, nitrogen and carbon, which are primarily derived from the atmosphere and organic material. From an examination of Tables 2 and 3 it is apparent that most of these nutrients increase as the parent material becomes more mafic. For example, the table shows CaO concentrations increasing from 0.1% in average granite, to 6.8% in average andesite, to 9.5% in average basalt, and then dropping to 5.1% in average peridotite. Also the ability of the soil to absorb and retain nutrients, as indicated by its cation exchange capacity (CEC), increases with increasing mafic character of the parent material. Clays produced from mafic parent materials, such as montmorillonite and vermiculite, have higher CEC (or activity) than those produced from siliceous parent materials such as illite and kaolin. Ultramafic parent materials frequently contain concentrations of elements that are toxic to many plants particularly Ni, Cr, Co, Zn, Hg, and Pb, as can be seen from Table 3. 17th WCSS, 14-21 August 2002, Thailand GRAY & MURPHY Table 1 Broad classification of parent material for pedologic purposes. 1 CalciumFerromagnesium Content (Ca, Mg & Fe oxides) Parent Material Category Silica Content (SiO2) 1. Extremely siliceous >90% extremely low (generally <3%) 2. Highly siliceous 72-90% Low (generally 3-7%) 3.Transitional siliceous/ intermediate 62-72% moderately low (generally 7-14%) 4. Intermediate 52-62% Moderate (generally 14-20%) 5. Mafic 45-52% High (generally 20-30%) very high (generally >30%) 6. Ultramafic <45% 7. Calcareous low1 8. Alluvial 9. Organic variable1 low1 10. Sesquioxide variable1 CaCO3 dominant, other bases variable variable organic matter dominant, bases variable variable, dominated by sesquioxides such as iron and aluminium oxides Examples quartz sands (beach, alluvial or aeolian), chert, quartzite, quartz reefs and silicified rocks granite, rhyolite, adamellite, dellenite, quartz sandstone, quartz siltstone and siliceous tuff granodiorite, dacite, trachyte, syenite, most greywacke, most lithic sandstone, siliceous/intermediate tuff and most argillaceous rocks (mudstone, claystone, shale, slate, phyllite and schist) monzonite, trachy-andesite, diorite, andesite, intermediate tuff and some greywacke, lithic sandstone and argillaceous rocks. gabbro, dolerite, basalt and mafic tuff (uncommon) serpentinite, dunite, peridotite, amphibolite and tremolitechlorite-talc schists limestone, dolomite, calcareous shale and calcareous sands alluvium peat, coal and humified vegetative matter laterite, bauxite, ferruginous sandstone and ironstone category not defined by silica content Texture The parent material largely controls the potential quantity of clay, the potential quantity of resistant minerals such as quartz and their grainsize, and the activity of the clay produced. Most minerals apart from quartz eventually weather to form clay minerals. Thus, the more mafic the parent material, the higher will be the clay content and lower the quartz grain content. Argillaceous rocks such as shales are predominantly composed of clay particles, thus they will give rise to soils with high amounts of clay. 2215-3 17th WCSS, 14-21 August 2002, Thailand 100.27 Total 99.88 78.33 0.25 4.77 1.07 0.3 1.16 5.5 0.45 1.31 1.63 5.03 0.08 Quartz sandstone (s) 100.07 71.30 0.31 14.32 1.21 1.64 0.05 0.71 1.84 3.68 4.07 0.77 0.05 0.12 Granite (p) 99.96 72.82 0.28 13.27 1.48 1.11 0.06 0.39 1.14 3.55 4.30 1.41 0.08 0.07 Rhyolite (v) 100.70 66.06 0.62 15.34 1.01 4.58 0.04 2.85 2.38 3.21 4.00 0.52 0.09 Greywacke2 (s) 99.90 66.09 0.54 15.73 1.38 2.73 0.08 1.74 3.83 3.75 2.73 1.04 0.08 0.18 Granodiorite (p) 99.78 65.01 0.58 15.91 2.43 2.30 0.09 1.78 4.32 3.79 2.17 1.19 0.06 0.15 Dacite (v) Source: Average analysis: Best (1982); Australian sample analysis: Joplin (1965). p: plutonic igneous (coarse grained); v: volcanic igneous (fine grained); s: sedimentary; 1 Cronulla, NSW, 2 Mt Nebo, Brisbane Qld, 3 Prospect, NSW. 97.62 1.32 0.4 0.13 0.28 0.52 - SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2O H2O CO2 P 2O 5 Dune sand 1 (s) 100.14 60.28 1.12 17.78 4.45 2.6 1.17 0.56 0.34 2.36 0.26 0.22 Shale3 (s) 99.98 57.48 0.95 16.67 2.50 4.92 0.12 3.71 6.58 3.54 1.76 1.36 0.10 0.29 Diorite (p) 99.93 57.94 0.87 17.02 3.27 4.04 0.14 3.33 6.79 3.48 1.62 1.17 0.05 0.21 Andesite (v) 99.95 49.2 1.84 15.74 3.79 7.13 0.2 6.73 9.47 2.91 1.1 1.38 0.11 0.35 Basalt (v) Table 2 Average chemical composition of some common igneous and sedimentary rocks. (expressed as % oxides). GRAY & MURPHY 99.46 42.26 0.63 4.23 3.61 6.58 0.41 31.24 5.05 0.49 0.34 4.22 0.3 0.1 Peridotite (p) 99.79 5.19 0.06 0.81 0.54 7.89 42.57 0.05 0.33 0.77 41.54 0.04 Limestone (s) 17th WCSS, 14-21 August 2002, Thailand GRAY & MURPHY Table 3 Average content of trace elements in main rock types and ionic radii of common elements. (content in ppm). Ultramafic Igneous P Ga Cr Li Ni C V Ti Zr Mn Sc Cu Sr Pb Ba Rb Zn As Mo B 170 2 2000 <1 2000 200 40 300 30 1500 5 20 10 <1 1 2 Mafic Igneous 1400 18 200 15 160 45 200 9000 100 2000 24 100 440 8 300 45 100 2 1 5 Intermediate Igneous 1600 20 50 20 55 10 100 8000 260 1200 3 35 800 15 650 100 Shale Highly Siliceous Igneous 750 25 100 60 80 20 130 4600 180 850 15 50 400 20 600 140 90 10 2 100 700 20 25 40 8 5 40 2300 200 600 3 20 300 20 830 200 50 1.5 1.5 15 Sandstones 170 12 35 15 2 0.3 20 1500 220 50 1 5 20 7 50 60 16 1 0.2 35 Carbonates 400 4 11 5 4 0.1 20 400 19 1100 1 4 610 9 10 3 20 1 0.4 20 Source: various tables in Krauskopf (1979). The activity of the clay present will also influence the soil texture, with high activity clays such as smectites and vermiculite giving heavier texture than low activity clays such as kaolin and illite. Generally the more mafic the parent material, the higher the activity of the clays produced. The coarser the grain size of the parent material, and in particular that of the resistant quartz grains, the coarser will be the particle size of the soil, especially of the surface soil. Sodicity Sodic problems develop where there is a high ratio of sodium relative to other exchangeable bases. This ratio generally increases with increasing siliceous character of the parent material. This is demonstrated by Table 2 which reveals a Na2O/CaO ratio of 0.3 for average basalt, 0.5 for average diorite, 1.0 for average granodiorite and 2.0 for average granite. Highly siliceous parent materials such as quartz sandstones or granites give rise to soils that are very susceptible to external sources of sodium (such as leached solutions from upslope, windlblown dust or rising groundwaters) because of their inherently low (non-sodium) base content (see Hallsworth and Waring, 1964). 2215-5 GRAY & MURPHY 17th WCSS, 14-21 August 2002, Thailand Salinity level It is difficult to make generalisations about the potential salinity levels in soils arising from different parent materials. Much of the salt present in soils may be derived from external sources (see Isbell et al., 1983). Salt content may be high in marine clay rich sediments (i.e. claystones, shales, etc) as the salt and/or component ions may be bound up with the clays during the deposition process. Note that not all marine sediments are high in salt content as the saline water is generally not retained during the lithification process. Gunn and Richardson (1979), studying the Cretaceous rocks of southern Queensland, reported significant quantities of sodium, chloride and other salt forming ions in marine argillaceous sediments, but low quantities in marine quartzose sediments. These authors show that most rocks, with the probable exception of quartzose sandstones and siltstones, have sufficient sodium, chloride and other ions to give rise to salty conditions without the need for atmospheric accession of salt. As is the case for sodicity effects noted above, soils derived from highly siliceous parent materials are inherently more susceptible to the presence of salt than those derived from mafic soils, due to their lower exchangeable base content, thus lower buffering potential. Soil acidity Soil acidity tends to decrease with increasing mafic character of the parent material. This is due to the greater abundance of exchangeable bases and higher CEC in soils derived from mafic materials which have a buffering effect to increases in the H+ ion ions (e.g. from plant growth, removal of basic cations in farm produce, or nitrate leaching). Where carbonate is present in the soil, as is common over calcareous parent materials (e.g., limestone or dolomite), they will usually be slightly or even strongly alkaline in character. Thus soils derived from highly siliceous sandstones and granites will generally be more acidic than those derived from andesites and basalts, other factors being equal. Soil structure The most highly structured soils are generally formed where there are clays with high calcium levels and low sodium levels; high levels of sesquioxides (as indicated by the presence of free iron and aluminium oxides); and/or high organic matter and soil fauna activity (particularly critical for lighter-textured soils). Generally speaking, these attributes become more common in soils as the parent material becomes increasingly mafic in character (but not ultramafic). Thus, soils with good structure, at least in surface units, are commonly formed from parent materials of mafic to intermediate composition, e.g. basalts and andesites. Shrink/swell potential This phenomena occurs where high levels of smectite clays such as montmorillonite are present. Generally the more mafic the parent material the higher the amount of smectite present. Illite, vermiculite and interstratified clays (i.e. material composed of interlayers of various clay types) can be prone to a degree of shrink/swelling activities. Kaolin and chlorite have low potential for these activities. Thus, basalt-derived soils have a typically high potential for shrink/swell and related phenomena, soils from more intermediate rocks such as andesites, shales and GRAY & MURPHY 17th WCSS, 14-21 August 2002, Thailand granodiorites have a moderate potential, while siliceous rocks such as granites and sandstones give rise to soils with a typically low potential. Erodibility Soils with high levels of fine sand and silt and low clay levels are likely to be highly erodible. The finer the sand/silt particles the more prone to erosion the soil is likely to be. Thus, fine-grained siliceous parent materials such as siltstones and rhyolites will be the most likely to give rise to erodible soils, at least in surface units. High clay forming parent materials such as basalts and shales are generally the least likely, other factors being equal. Where the clays present are dispersible they are highly prone to erosion, where they are flocculating they are less prone to erosion. Clays with dispersible behaviour are frequently associated with the more siliceous parent materials, as they are more susceptible to sodium problems. Note that "self mulching" clay soils derived from mafic parent materials may be subject to high erosion because of their tendency to seal under rainfall, thus leading to high runoff and water erosivity. Soil thickness and rock outcrop In the zone of soil depletion (i.e. middle and upper hillslopes), soil thickness is determined by the rate of parent material weathering as opposed to the rate of soil erosion from the site. Where the former is greater than the latter a relatively thick profile will develop; where the reverse applies the profile will be relatively thin with extensive rock outcrop. From a consideration of these weathering and erodibility factors, it is possible to develop a sequence of parent materials giving rise to deeper soils and decreasing rock outcrop. The following general sequence is suggested for zones of depletion under equivalent environmental conditions: carbonate parent material fine-grained siliceous parent material coarse-grained siliceous parent material fine-grained intermediate parent material coarse-grained intermediate parent material fine-grained mafic parent material coarse-grained mafic parent material. shallowest soil deepest soil In the zone of soil accumulation (i.e., footslopes and valley floors) soils are typically thick with rare outcrop. It is more difficult to determine trends as attempted above for this zone. Modelling of soil distribution based on parent material, climate and drainage The modelling of potential soil types under various parent material, climate and drainage regimes is attempted. This is based on an understanding of the influence that these factors have on soil properties, an analysis of correlations derived from approximately 8,000 soil profiles stored in the SALIS soil database, and an examination of published soil relationships. The model aids in the prediction of likely soil types in most world locations, using the World Reference Base for Soil Resources scheme (FAO 1998 and ISSS Working Group 1998a, 1998b). The model is presented in the form of two x-y plots in Figures 1 and 2, showing the typical distribution ranges of most World Reference Base soil types. Figure 1 deals with Well Drained (Upland) Locations, characterised by good water drainage and a net 2215-7 GRAY & MURPHY 17th WCSS, 14-21 August 2002, Thailand removal of soil materials. Figure 2 deals with Imperfectly Drained (Lowland) Locations, characterised by restricted drainage and a net accumulation of soil materials. On the y axis of each of these plots is parent material category (based on silica content) ranging from extremely siliceous at the top to ultramafic at the base. On the x axis is annual rainfall, ranging from dry on the left to very humid on the right. Although the maximum rainfall indicated is only 2,000 mm pa, the plot is in fact open ended. Typical temperature conditions, be it cool, temperate or warm are indicated by superscripts attached to each of the major soil groups in the body of the plot. The plots comprise a series of "soil distribution stars". The centroid of the star indicates the most common conditions under which the soil will occur while the arms of the star indicate the ranges of conditions over which the soil may occur. For example, Figure 1 reveals that in well drained (upland) locations, Calcisols range from highly siliceous to mafic parent materials and from approximately 0 to 500 mm annual rainfall. Note that several different soils are usually theoretically possible under any given set of conditions. The figures do not cover the soil types that do not have clear parent material - climate - drainage correlations, and thus cannot be easily presented on these plots, eg, Anthrosols (human modified soils) and Cryosols (perenially frozen soils). These plots represent the best fit model for World Reference Base soil distribution that could be generated with the information available. They are, however, still only approximations and need to be applied with caution. The precise positioning and ranges of the soil distribution stars will very likely be modified as further data and user feedback is gained. Figure 1 Soil distribution in well drained (upland) locations. GRAY & MURPHY 17th WCSS, 14-21 August 2002, Thailand Figure 2 Soil distribution in imperfectly drained (lowland) locations. A summary of the main diagnostic and land management features of the main World Reference Base soils as identified in Figures 1 and 2 (together with their Soil Taxonomy equivalents) are presented in Table 4. Conclusion Parent material has a major influence on the properties of soil. It provides the basic starting material upon which other factors such as topography and climate serve to modify. This paper has presented a model identifying the relationship of World Reference Base soils to parent material, climate and topographic regimes. It is recognised that considerable uncertainties exist in the model, and that it must be applied with caution. Any resulting predictions should be treated as first approximations only. The authors would welcome any feedback to help refine the model. 2215-9 17th WCSS, 14-21 August 2002, Thailand Aqualts, Humults and Udults Andisols Human influence at sub-order level Psamments or Psammaquents Pale- great groups of Alfisols & Aridisols, & calcic subgoups Inceptisols (Dystro- & Eutrochrepts) Borrol ?? Gelisol order Alfisols & Inceptisols, in Durorthid or Durargid great groups Oxisols ALBELUVISOLS ALISOLS ANDOSOLS ANTHROSOLS CALCISOLS CHERNOZEMS CRYOSOLS DURISOLS FERRALSOLS CAMBISOLS ARENOSOLS Latosols, oxic Alfisols and Ultisols multiple ACRISOLS World Reference Soil Taxonomy Equivalent Base Soil Deep and strongly weathered, physically stable but chemically poor subsoil Accumulation of secondary silica Subsoil with low activity clay and low base saturation Acidic, bleached horizon penetrating into clay rich horizon High activity clay subsoil, rich in exchangeable aluminium Young age, within recent volcanic deposits Formation conditioned by human influences Sandy, very weak or no pedologic development Accumulation of secondary calcium carbonates Only weak to moderate pedologic development Thick, blackish, organic rich topsoil, calcareous subsoil Permafrost within 1 m depth Main Characteristics Land Management Features High agricultural potential - high available water capacity, nutrients and organic matter; neutral pH Very low agricultural potential - prone to high erosion and melting and ponding of permafrost Very low agricultural potential - duripan restricts plant root and water penetration Low to moderate agricultural potential - good physical properties but low nutrients and pH Low agricultural potential - low nutrients, CEC and waterholding capacity Moderate agricultural potential (but dry conditions are limiting), prone to erosion and salinisation Variable but generally moderate agricultural potential Low agricultural potential - acid and nutrient poor, rapidly degrade, prone to erosion Low to moderate agricultural potential - acid, nutrient poor and drainage and tillage problems Low to moderate agricultural potential - low nutrients, aluminium toxicity, high erodibility Moderate agricultural potential - low water retention and CEC, acid, aluminium toxicity Variable agricultural potential Table 4 Main characteristics and land management features of world reference base soils. GRAY & MURPHY Aquents, Aquepts and Aquolls Aridisols (Gypsiorthid) Histosols Ustolls and Borolls Entisols (lithic subgroups), Rendolls Latosols and Alfisols (oxic subgroup) Alfisols Alfisols and Ultisols (kandic group) Aquolls GLEYSOLS GYPSISOLS HISTOSOLS KASTANOZEMS LEPTOSOLS NITISOLS Albaqualfs, Albaqualts, Argialbolls Plinthaquox PLANOSOLS PLINTHOSOLS PHAEOZEMS LUVISOLS LIXISOLS Fluvents FLUVISOLS 2215-11 Wet, hard layer of iron, clay and quartz in subsoil Deep and clay rich, shiny, nut shaped structure Thick, dark, organic rich topsoil, carbonates removed Bleached, temporarily water saturated topsoil on a slowly permeable subsoil Composed of organic materials Thick, dark brown, organic rich topsoil, calcareous or gypsum rich subsoil Very shallow depth over hard rock, or very gravelly Subsoil with low activity clay and high base saturation Subsoil with high activity clays Permanent or temporary wetness near the surface Accumulation of secondary gypsum Young soils in alluvial deposits Main Characteristics Land Management Features Low agricultural potential - shallow depth, low water holding capacity and typical steep slopes Moderate agricultural potential - generally moderate nutrient levels, low CEC, prone to erosion High agricultural potential - good fertility, CEC and waterholding capacity. Restricted drainage can be problem High agricultural potential - good fertility (despite low available phosphorous), structure and physical properties High agricultural potential - high nutrient levels, organic matter, and available water capacity and good structure Low to moderate agricultural potential - dense subsoil inhibits root growth, generally low in organic matter and nutrients Very low agricultural potential - plinthite layer means poor plant rooting conditions but often useful as construction material Moderate to high agricultural potential - fertile and flat land; acid sulfate problems in marine areas Low to moderate agricultural potential - wet and poorly drained, extensively cultivated for rice Low to moderate agricultural potential - dissolution of gypsum causes subsidence, gypsic pan may be restriction Low agricultural potential - may be improved by drainage Moderate to high agricultural potential - good physical and chemical properties, but irrigation usually required 17th WCSS, 14-21 August 2002, Thailand World Reference Soil Taxonomy Equivalent Base Soil Table 4 (Cont.) GRAY & MURPHY Entisols Salorthids Natr-ustalfs, -ustolls, -xeralfs, argids and Nadurargids Umbrepts and Humitropepts Vertisols REGOSOLS SOLONCHAKS SOLONETZ UMBRISOLS VERTISOLS Subsurface clay accumulation, rich in sodium Acidic, medium textured, topsoil being thick, dark and organic rich Dark-coloured cracking and swelling clays Acidic, with illuvial iron-aluminiumorganic compounds Very little soil development, in unconsolidated material Strongly saline Information source: ISSS Working Group RB (1998a, 1998b) Spodosols PODZOLS Main Characteristics Land Management Features Very low agricultural potential - sandy texture, low nutrient levels, acidic and frequent aluminium toxicity Low to moderate agricultural potential - variable properties, generally low water holding capacity Very low agricultural potential - salt limits growth to salt tolerant plants. Salt also causes problems with construction Low agricultural potential - sodic conditions impede plant growth and mean high erodibility Low agricultural potential - acidic soil and wet, cold climatic conditions, potential will improve with liming High agricultural potential - very high fertility, but physical problems eg, heavy, shrink-swell clays with low infiltration 17th WCSS, 14-21 August 2002, Thailand World Reference Soil Taxonomy Equivalent Base Soil Table 4 (Cont.) GRAY & MURPHY GRAY & MURPHY 17th WCSS, 14-21 August 2002, Thailand References Bear, F.E. 1969. Chemistry of the Soil. 2nd ed. Van Nostrand Renhold Company, New York, Melbourne. Best, M.G. 1982. Igneous and Metamorphic Petrology. Freeman and Co, New York. Brewer, R. 1954. Soil Parent Material. The Australian Journal of Sciences 16:134-138. Charman, P.E.V. and B.W. Murphy. 2000. Soils-Their Properties and Management. 2nd ed. Oxford University Press, Melbourne. Chesworth, W. 1973. The Parent Rock Effect in the Genesis of Soil. Geoderma 10:215225. FAO. 1998. World Reference Base for Soil Resources. World Soil Resources Report 84, FAO-ISRIC-ISSS. FitzPatrick, E.A. 1980. Soils-Their Formation, Classification and Distribution. Longman Group Ltd, London. Gray, J.M. and B.W. Murphy. 1999. Parent Material and Soils-A Guide to the Influence of Parent Material on Soil Distribution in Eastern Australia. NSW Dep't of Land and Water Conservation Tech. Rep. 45, Sydney. Gunn, R.H. and D.P. Richardson. 1979. The nature and possible origins of soluble salts in deeply weathered landscapes of south eastern Australia. Australian Journal of Soil Research 17:197-215. Hallsworth, E.G. and H.D. Waring. 1964. An alternative hypothesis for the formation of the solidized-solonetz of the Pilliga District. Journal of Soil Science 15:158-177. Isbell, R.F., R. Reeve and J.T. Hutton. 1983. Salt and Sodicity in Soils-An Australian Viewpoint. CSIRO Melbourne, Academic Press, London. Isbell, R.F., W.S. McDonald and L.J. Ashton. 1997. Concepts and Rationale of the Australian Soil Classification. ACLEP, CSIRO, Canberra. ISSS Working Group RB. 1998a. World Reference Base for Soil Resources: Introduction. In J.A. Deckers, F.O. Nachtergaele and O.C. Spaargaren (eds.). First Edition. ISSS, ISRIC and FAO, Acco, Leuven. ISSS Working Group RB. 1998b. World Reference Base for Soil Resources: Atlas. In E.M. Bridges, N.H. Batjes and F.O. Nachtergaele (eds.). ISRIC-FAO-ISSS-Acco, Leuven. Jenny, H. 1941. Factors of Soil Formation. McGraw-Hill Book Company Inc., New York. Jenny, H. 1980. The Soil Resource-Origin and Behaviour. Springer-Verlag, New York. Joplin, G.A. 1965. Chemical Analysis of Australian Rocks. Part II: Sedimentary Rocks. Bureau of Mineral Resources, Bulletin No. 78. Krauskopf, K.B. 1967. Introduction to Geochemistry. 2nd ed. McGraw-Hill Book Company, USA. Paton, T.R., G.S. Humphreys and P.B. Mitchell. 1995. Soils-A New Global View. UCL, Press Ltd, London. 2215-13 GRAY & MURPHY 17th WCSS, 14-21 August 2002, Thailand Stace, H.C.T., G.D. Hubble, R. Brewer, K.H. Northcote, J.R. Sleeman, M.J. Mulcahy and E.G. Hallsworth. 1968. A Handbook of Australian Soils. CSIRO and ISSS, Rellim Technical Publications, South Australia. Whiteside, E.P. 1953. Some Relationships between the Classification of Rocks by Geologists and the Classification of Soils by Soil Scientists. Soil Science Society of America, Proceedings 17:138-142.