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Transcript
Review: Inside the Atom
­atoms consist of sub­atomic particles
protons­positively charged electrons­negatively charged
neutrons­neutral
­the number of protons is significant since it is this that determines what the element actually is
atomic number = number of protons
number of protons = number of electrons
number of neutrons = mass number ­ number of protons
­a charged atom is called an ion
­electrons are very small and can be stripped off easily
­since each proton balances each electron, the ion has a charge equal o the number of electrons it has lost
+1
Example: Na has lost one electron
Standard Atomic Notation
mass #
35
17
Cl
Hint mass #
Na
atomic #
Hint
atomic #
1
Developing Models of Matter
What does an atom look like? How do the
'pieces' fit together? First some history...
About 450 BC
• Greek Philosopher Empedocles
• Earth, Air, Wind, Fire
About 400 BC
• Democritus
• matter made of tiny particles
• called them atoms
About 350 BC
• Aristotle
• very influential because he was educated
• Empedocles model accepted for nearly
2000 years
AD 500­1600
• Alchemists­part philosopher, mystic,
magicion and chemist
• developed many of our current procedures
and tools but still accepted the 4 element
model
• attempted to make gold of cheap
materials­did not succeed!
2
About 1650
• Robert Boyle
• developed a new definition for "element"
• " a pure substance that cannot be broken
down into simpler substances"
About late 1700's
• Priestly, Lavoisier and Cavendish
• isolated oxygen and later hydrogen and
recognised them as elements
• Priestly­isolated oxygen
• Lavoiser­recognized Oxygen was an
element and air is a mixture
• Cavendish found that
acid+metal=Hydrogen
1808
• John Dalton ­ Particle Theory
­ All matter is made of tiny particles
­ Each element has its own kind of atom
and mass
­ Compounds are created when elements
combine
­ atoms cannot be created or destroyed
3
1800's
• 1831­Michael Faraday
­ matter must contain positive and
negative charges
­ opposite charges attract, like charges
repel
­ atoms combine to form compounds
because of electrical attractions
• Found electric current causes chemical
changes to some compounds
1904
• JJ Thomson
• "raison bun" model
­ atoms contain particles called electrons
­ electrons are very small and negative
­ remainder is a sphere with a positive
charge
­ electrons are "embedded" in this sphere,
resulting in an uncharged atom
• Discovered electron
• Experimented with protons
Draw diagram!!
4
1911
• Ernest Rutherford
• gold foil experiment
­ a tiny dense positive core called the
nucleus
­ surrounded by mostly empty space
containing the rapidly moving negative
electrons
A Planetary Model of the Atom
Niels Bohr, suggested the following:
­electrons can move around the nucleus in
nearly circular orbits
­each electron has a specific amount of
energy
­the farther away from the nucleus the greater
the amount of energy
­electrons cannot exist 'between' these orbits,
butcan move up and down from one orbit to
another
­the order of filling these orbits is 2, 8, 8 for the
the first three orbits
­electrons are more stable at lower energy,
closer to the nucleus
5
Bohr Diagrams
the element symbol is written in the center and the electrons are 'filled' into the orbits around this nucleus
Electron
Example:
Hydrogen has 1 proton, so 1 electron
H
Nitrogen has 7 protons and so has 7 electrons
(Hint: remember 2,8,8)
N
6
Try these!
determine the # of protons and electrons Dont forget the 2, 8, 8
Electron
P
Cl
Mg
F
Bohr­Rutherford diagrams
­
combination of Rutherford’s
nuclear model & Bohr’s planetary
model
­
circle in middle to represent
nucleus of the atom ­ number of
protons & neutrons are written here
­
electrons shown in circular orbits
Ex. Carbon
7
You Try!
Helium
Nitrogen
Sulfur
Sodium
8