* Your assessment is very important for improving the workof artificial intelligence, which forms the content of this project
Download 10th CBSE {SA - 1} Revision Pack Booklet - 3
History of electrochemistry wikipedia , lookup
Chemical equilibrium wikipedia , lookup
Sodium hydroxide wikipedia , lookup
Biochemistry wikipedia , lookup
Chemical thermodynamics wikipedia , lookup
Hydrogen-bond catalysis wikipedia , lookup
Transition state theory wikipedia , lookup
Water pollution wikipedia , lookup
Acid dissociation constant wikipedia , lookup
Artificial photosynthesis wikipedia , lookup
Sodium hypochlorite wikipedia , lookup
Chemical reaction wikipedia , lookup
Photosynthetic reaction centre wikipedia , lookup
Nucleophilic acyl substitution wikipedia , lookup
Sodium bicarbonate wikipedia , lookup
Freshwater environmental quality parameters wikipedia , lookup
Electrochemistry wikipedia , lookup
Bioorthogonal chemistry wikipedia , lookup
Click chemistry wikipedia , lookup
Stoichiometry wikipedia , lookup
Evolution of metal ions in biological systems wikipedia , lookup
Water splitting wikipedia , lookup
Metalloprotein wikipedia , lookup
Acid–base reaction wikipedia , lookup
Lewis acid catalysis wikipedia , lookup
Pioneer Education {The Best Way To Success} IIT – JEE /AIPMT/NTSE/Olympiads Classes Revision Question Bank Chemical Reactions and Equations 1. Give the reaction taking place during respiration in the body cells. Sol: The reaction taking place during respiration is as follows C6H12O6 aq 6 O2 aq Glucose Oxygen 6 CO2 aq 6H2O l Energy Carbon dioxide 2. water Name the reaction in which one of the reacting species loses, while the other gains electrons. Sol: Redox reaction is that reaction, in which one of the reacting species loses, while the other gains electrons. 3. Why is decomposition reaction called opposite of combination reaction? Write equations for these reactions. Sol: In a combination reaction, two or more substances combine together to form a single new substance whereas, in a decomposition reaction, a single substance is broken into two or more new substances, e.g. Combination reaction Burn 2H2 g O2 g 2H2 O g Hydrogen Oxygen water Decomposition reaction Electricity 2H2 O l 2H2 O g water Hydrogen Oxygen It is clear that decomposition reaction is the reverse of combination reaction. 4. Write balanced chemical equation for each of the following. www.pioneermathematics.com S.C.O. - 326, Sector 40–D, CHD. Phone: 9815527721, 4617721 14 Pioneer Education {The Best Way To Success} IIT – JEE /AIPMT/NTSE/Olympiads Classes (a) Methane burns in air to give carbon dioxide, water and heat. (b) Ferric oxide reacts with sulphuric acid to give ferric sulphate and water. Sol: (a) CH4 g 2O2 g CO2 g 2H2O g Heat Methane Oxygen Carbon dioxide water (b) Fe2O3 s 3H2SO4 aq Fe2 SO4 3 Iron(III) oxide 5. Sulphuric acid aq 3H2O l Iron(III) sulphate hydrate water All single displacement reactions are irreversible reactions. Explain. Sol: Single displacement reactions involve the displacement of a less reactive element by a more reactive element and the less reactive element precipitates out. But the reverse of this is not possible because the less reactive element cannot displace back the more reactive element. For example, Fe s CuSO4 aq FeSO4 aq Cu Iron 6. Blue Green copper Write equations for each decomposition reactions where energy is supplied in the form of heat, light or electricity. Sol: (i) The decomposition reaction, when energy is supplied in the form of heat, Heat CaCO3 s CaO3 CO2 g Calcium carbonate calcium oxide carbon dioxide (ii) The decomposition reaction, when energy is supplied in the form of electricity Electricity 2H2O l 2H2 g O2 g water Hydrogen Oxygen (iii) The decomposition reaction, when energy is supplied in the form of sun-light. sunlight 2AgBr s 2Ag Br2 silver bromide 7. silver bromine In what way are chemical equations useful for us? Sol: www.pioneermathematics.com S.C.O. - 326, Sector 40–D, CHD. Phone: 9815527721, 4617721 15 Pioneer Education {The Best Way To Success} IIT – JEE /AIPMT/NTSE/Olympiads Classes A chemical equation is useful for us because it gives us the following informations (i) Names of the reactants, which take part in the chemical reaction, (ii) Names of the products formed, (iii) Number of moles of each reactant and product, (iv) Mass of each substance involved in the reaction. (v) Physical state of all reactants and products, (vi) Physical conditions of a reaction. 8. Lime water turns milky when carbon dioxide gas is passed through it and further turns colourless when excess of carbon dioxide is bubbled through it. Explain. Sol: Lime water is Ca (OH)2 solution. When CO2 is passed through lime water, it turns milky due to the formation of insoluble CaCO3 precipitate. But when excess of CO2 is passed through the solution, calcium bicarbonate is formed, which is soluble in water and so the solution again turns colourless. Ca OH 2 CO2 Calcium hydroxide CaCO carbon dioxide 3 Calcium carbonate CaCO 3 calcium carbonate Milky suspension H2O water H2O CO2 Ca HCO3 2 aq water carbon dioxide Excess Soluble www.pioneermathematics.com S.C.O. - 326, Sector 40–D, CHD. Phone: 9815527721, 4617721 16 Pioneer Education {The Best Way To Success} IIT – JEE /AIPMT/NTSE/Olympiads Classes Chemical Reaction {Chapter Test} M:M: 30 1. M: Time: 40Mins. Why do iron railings on roadside get rusted if not painted? [1] Solution: If it is not painted, the iron surface will remain in contact with air and moisture. So, oxide layer called the rust, will deposit on its surface. 2. When the powder of a common metal is heated in an open China dish, its colour turns black. However, when hydrogen is passed over the hot black substance so formed, it regains its original colour. Based on the given information, answer the following questions (a) Name the metal initially taken in the powder form. (b) What type of chemical reaction takes place in each of the two given steps? Write balanced chemical equations for both reactions. [2] Solution: (a) Copper metal is taken initially in the powder form. (b) In step I combination reaction/oxidation reaction takes place. Heat 2Cu s O2 g 2CuO s Oxidation Copper (brown) Oxygen Copper oxide (Black) In step n, reduction reaction takes place. Reduction CuO s H2 g Cu s Copper oxide 3. Hydrogen H2O g Copper (Brown) Water Draw the apparatus for electrolysis of water. Why is the amount of hydrogen produced, double the amount of oxygen? [3] Solution: The apparatus for electrolysis of water is shown below www.pioneermathematics.com S.C.O. - 326, Sector 40–D, CHD. Phone: 9815527721, 4617721 17 Pioneer Education {The Best Way To Success} IIT – JEE /AIPMT/NTSE/Olympiads Classes Number of molecules of hydrogen produced are double the molecules of oxygen produced, according to the reaction. Electrolysis 2H2O l 2H2 g O2 g water 4. Hydrogen Oxygen A piece of sodium is dropped in water. What happens in this process? Which gas is evolved in the process? How is it detected? [4] Solution: When sodium is dropped in water, it reacts violently with water. During this exothermic reaction, hydrogen gas is evolved. To detect this gas, it is passed through soap solution. The bubbles formed rise up and burn with a popping sound if a burning matchstick is brought near it. 5. Balance the following chemical equations [3] (a) HNO3 + Ca(OH)2 Ca(NO3)2 + H2O Fe2O3 + SO2 + SO3 (b) FeSO4 CO2 + H2O + Heat (c) C6H12O6 + O2 Ca NO3 2 2H2O Solution: (a) 2HNO3 Ca OH 2 Nitric acid (b) Calcium hydroxide Calciumnitrate Water 2FeSO4 Fe2O3 SO2 SO3 Iron(II)sulphate Iron(III)Oxide Sulphur dioxide Sulphur tioxide (c) C6H12O6 6O2 6CO2 6H2O Heat Glucose 6. Oxygen Carbondioxide Water A solution of sodium sulphate is added to barium chloride solution. Write a balanced chemical equation for the reaction and the type of reaction. www.pioneermathematics.com S.C.O. - 326, Sector 40–D, CHD. Phone: 9815527721, 4617721 [2] 18 Pioneer Education {The Best Way To Success} IIT – JEE /AIPMT/NTSE/Olympiads Classes Solution: Na2SO4 aq BaCl2 aq BaSO4 s 2NaCl sodium sulphate Barium chloride Barium suphate sodium chloride It is a double displacement reaction because in this reaction, two different ions in the reactant molecules are displaced by each other. 7. Write balanced equations for the following, mentioning the type of reaction involved. (a) Aluminium + Bromine Aluminium bromide (b) Calcium carbonate Calcium oxide +Carbon dioxide (c) Silver chloride Silver + Chlorine [3] Solution: (a) 2Al(s) + 3Br2 (l) 2AlBr3 (s) It is combination reaction because in this reaction, two reactants, Aland Br2 react together to form a single product (AlBr3) (b) CaCO3 (s) CaO(S)+CO2(g) It is thermal decomposition reaction because this reaction involves the use of energy in the form of heat for decomposition of the reactant (CaCO3). Sunlight (c) 2AgCl(s) 2Ag(S)+Cl2(g) It is photochemical decomposition or photolysis because this reaction involves the use of light energy for the purpose of decomposition of the reactant (AgCl). 8. What is rancidity? How is it prevented? Why do we fill chips packets with nitrogen gas? How does it help? [4] Solution: Rancidity is the change in smell and taste of oil or fat product due to oxidation. It is prevented by using antioxidants or cutting the supply of oxygen. Chips packets are flushed with nitrogen gas to shield the chips from oxygen supply. Nitrogen does not cause rancidity of food. This helps in preserving the taste and smell of food. Manufacturers and shopkeepers are helped as shelf life for the chips is prolonged. 9. Define rusting. How does it occur? Write the reaction involved. What are its effects? Suggest two ways of preventing rusting. [4] Solution: Rusting is corrosion of iron due to the action of oxygen and moisture on its surface. www.pioneermathematics.com S.C.O. - 326, Sector 40–D, CHD. Phone: 9815527721, 4617721 19 Pioneer Education {The Best Way To Success} IIT – JEE /AIPMT/NTSE/Olympiads Classes It occurs in the presence of moist air due to the following reaction 2Fe s H2O O2 g Fe2O3 s H2 Iron water Oxygen Iron III oxide Hydrogen g Rusting weakens iron and damages structures such as doors, bridges, cars, etc. Rusting can be prevented by painting the iron surface or galvanising it (with zinc). 9. Why CuSO4 solution can't be stored in iron container? Give chemical equation also. [2] Solution: CuSO4 solution can't be stored in iron container because, copper is less reactive than iron. The more reactive metal (iron) displaces the less reactive metal (copper) from its solution (copper sulphate solution). Fe s CuSO4 aq Cu s Iron Copper sulphate Blue Copper FeSO 4 Ferrous sulphate Light green colour 10. Complete the reactions and state their types. [2] (a) 2KClO3 (s) (b)N2(g) + 3H2(g) How are the two reactions different? Solution: (a) 2KClO3 s 2KCl s 3O2 g Potassium chloride (b) N2 g 3H2 g Potassium chloride Oxygen 2NH3 g CaO s H2 O l Ca OH 2 aq calcium chloride water Calcium hydroxide It is combination reaction. The decomposition reaction involves breaking down of a compound into two or more substances. In combination reaction, two or more substances combine with each other to form one compound. www.pioneermathematics.com S.C.O. - 326, Sector 40–D, CHD. Phone: 9815527721, 4617721 20 Pioneer Education {The Best Way To Success} IIT – JEE /AIPMT/NTSE/Olympiads Classes Acids, Bases and Salts 1. How is plaster of Paris chemically different from gypsum? How can they be inter converted? Write one use of plaster of Paris. Sol: Plaster of Paris is chemically different from gypsum, in terms of water of crystallisation. Gypsum has two moles of water per mole of calcium sulphate (CaSO4.2H2O). Plaster of Paris has half a mole of water per mole of calcium sulphate (or two moles of calcium sulphate share one water molecule, i.e., 1 CaSO4. H2O or 2CaSO4.H2O 2 Gypsum, on heating at around 120oC, gets converted to Plaster of Paris (POP) and POP, upon hydration, gets converted to gypsum. 1 1 120o C CaSO4 .2H2O CaSO4 . H2O 1 H2O 2 2 Gypsum Plaster of paris 1 1 CaSO4 . H2O 1 H2O CaSO4 .2H2O 2 2 Gypsum POP Use of Plaster of Paris It is used as plaster for supporting fractured bones in the right position. 2. Given below are the pH values of four different liquids 7.0,14.0,4.0,2.0 Which of these could be that of (a) lemon juice (b) distilled water (c) 1 M, sodium hydroxide (NaOH) solution (d) tomato juice Sol: (i) The pH value of lemon juice = 2.0 (ii) The pH value of distilled water = 7 (iii) The pH value of 1 M, sodium hydroxide (NaOH) solution =14.0 www.pioneermathematics.com S.C.O. - 326, Sector 40–D, CHD. Phone: 9815527721, 4617721 21 Pioneer Education {The Best Way To Success} IIT – JEE /AIPMT/NTSE/Olympiads Classes (iv) The pH value of tomato juice = 4.0 3. State Arrhenius concept of acids and bases. Select a strong acid and a weak base from amongst the following substances H2CO3, HNO3, NaOH, NH4OH. Sol: According to Arrhenius theory, acids are substances which provide H+ ions when dissolved in water, whereas bases are substances which when dissolved in water give OH– ions, (hydroxide ions). Among the given substances, HNO3 is a strong acid and NH4 OH is a weak base. i.e., Strong acid = HNO3 Weak base = NH4 OH 4. A solution turns red litmus blue, its pH is likely to be (a) 1 (b) 4 (c) 5 (d) 10 Sol: (d) Its pH is likely to be 10 [Bases turn red litmus blue]. pH range of bases is from 8 to 14. 5. What effect does the concentration of H+(aq) have on the acidic nature of the solution? Sol: Acidity of a solution increases with increase in the concentration of hydronium ion (H3 O+). 6. Given two test-tubes 'A' and 'B'. Test-tube 'A' contains blue litmus solution and test-tube 'B' contains red litmus solution. A solution with pH 2 is added in both the test-tubes, in which of the two would you observe a colour change? Sol: The colour of solution in test-tube 'A' will change, i.e., blue litmus solution will turn to red. [The substance with pH 2 is acidic in nature and acids turn blue litmus red]. In test-tube 'B', no colour change is observed. 7. Write the chemical reaction involved when zinc is added to warm dilute sodium www.pioneermathematics.com S.C.O. - 326, Sector 40–D, CHD. Phone: 9815527721, 4617721 22 Pioneer Education {The Best Way To Success} IIT – JEE /AIPMT/NTSE/Olympiads Classes hydroxide solution. Can all metals react with caustic soda solution? Sol: When zinc is added to warm dilute sodium hydroxide solution, the following reaction takes place 2NaOH Sodium hydroxide Zn Na2ZnO2 H2 Zinc Sodium zincale Hydrogen No, all metals do not react with caustic soda. 8. To an aqueous solution of sodium hydroxide, a few drops of phenolphthalein were added. What do you observe? To this solution small amount of dilute HCl was added. What do you observe now? Explain your answer. Sol: On adding phenolphthalein to sodium hydroxide solution, the solution turns pink but when acid is added to it, the solution again turns colourless. This is because phenolphthalein gives pink colour in alkaline medium. When acid is added to the pink solution, the acid neutralises the base and the solution ultimately turns colourless. www.pioneermathematics.com S.C.O. - 326, Sector 40–D, CHD. Phone: 9815527721, 4617721 23 Pioneer Education {The Best Way To Success} IIT – JEE /AIPMT/NTSE/Olympiads Classes Acids , Bases and salts {Chapter Test} M:M: 30 M: Time: 40Mins. 1. What is the chemical name for baking soda? How is it produced? Why is it used in baking? Write the reactions involved. [4] Solution: Baking soda is sodium hydrogen carbonate (NaHCO3). Production method It is obtained when ammonia is passed over brine solution in an environment of CO2. NaCl H2O CO2 NH3 NH4Cl NaHCO3 sodium chloride water carbon dixide ammonia ammonium chloride sodium bicarbonate On heating, it decomposes to give CO2. It is thus used for baking as it makes the cake light and spongy. 2NaHCO3 Na2CO3 H2O CO2 sodium bicarbonate 2. sodium carbonate water carbon dioxide (a) Out of HCl and CH3COOH which solution has higher value of pH? (b) A student tests a sample of drinking water and reports its pH as 6 at room temperature, which compound do you think may have been added to water? [2] Solution: (a) CH3COOH is a weak acid. It ionises partially and therefore it has a higher pH value. (b) The compound added to water may be bleaching powder. In water bleaching powder liberates chlorine which makes its pH6 (i.e., the solution becomes acidic). 3. Give reasons for the following (a) Iron develops brown layer on its surface in air. (b) Copper develops green colour appearance in air. (c) Iron articles are galvanised. [3] Solution: (a) A layer of oxide (Fe2O3) develops on iron surface due to its reaction with www.pioneermathematics.com S.C.O. - 326, Sector 40–D, CHD. Phone: 9815527721, 4617721 24 Pioneer Education {The Best Way To Success} IIT – JEE /AIPMT/NTSE/Olympiads Classes oxygen and moisture in air. This is called rusting. (b) In air, a layer of green coloured basic copper carbonate is formed on the surface of copper. (c) To prevent the iron articles from corrosion (rusting), they are galvanised. 4. What is water of crystallisation? Describe an activity to demonstrate that crystals contain water of crystallisation. [3] Solution: Fixed number of water molecules present in one formula unit of a salt is called water of crystallisation. It is responsible for the shape and colour of the crystal. Aim To show that crystals contain water of crystallisation. Materials Required Copper sulphate crystals, burner, boiling tube and holder. Procedure (i) Take a few crystals of CuSO4 and heat them in a boiling tube. (ii) The blue colour of crystals vanishes. Small water droplets appear on the walls of boiling tube on the upper sides. (iii) Stop heating and add 4-5 drops of water in the test tube. (iv) Crystals again turn blue. Thus, hydrated copper sulphate crystals are blue in colour and have formula CuSO4 .5H2 O www.pioneermathematics.com S.C.O. - 326, Sector 40–D, CHD. Phone: 9815527721, 4617721 25 Pioneer Education {The Best Way To Success} 5. IIT – JEE /AIPMT/NTSE/Olympiads Classes Define chlor-alkali process. What are the uses of its products? [3] The process of decomposing the aqueous solution of common salt to form NaOH by passing electricity is called chlor-alkali process. Electric 2NaCl aq 2H2O l 2NaOH aq Cl2 g H2 g Current sodium hydroxide Chlorine At anode Hydrogen At cathode Chlorine is used for the treatment of water in wells and pools, in making pesticides, CFCs and PVC manufacture. Hydrogen is used in fuels, manufacture of ammonia and margarine. Sodium hydroxide is used for de-greasing metals in paper making, for soap, detergents and artificial fibres making. 6. Write the chemical equations for the reaction of (a) potassium (b) calcium, with air and water. (c) Give two examples of metals which don't react with air and water. [3] Solution: (a) Potassium Reaction with air 4K+O2 2K2O Reaction with water 2K+2H2O 2KOH+H2 (b) Calcium Reaction with air 2Ca + O2 2CaO Reaction with water Ca(OH)2 +H2 Ca+ 2H2O Silver and gold do not react with water. 7. Distinguish between strong acid and weak acid with examples. www.pioneermathematics.com S.C.O. - 326, Sector 40–D, CHD. Phone: 9815527721, 4617721 [2] 26 Pioneer Education {The Best Way To Success} Solution: 8. IIT – JEE /AIPMT/NTSE/Olympiads Classes Differences between strong acid and weak acid are as follows S. No. Strong Acid Weak Acid (i) Ionise almost completely in Ionise only partially or to lesser extent in water. water. (ii) Give more number H+ ions in Give less number of H+ ions in water. water. (iii) pH value is less pH value is more. (iv) e.g., cone sulphuric e.g., Acetic acid(CH3COOH) acid (H2SO4). What is aqua regia? How is it obtained? State its properties. [2] Solution: Aqua regia is a reagent, which can dissolve inactive metals like gold, platinum, etc. Aqua regia is obtained by adding cone. HCl (3 parts) and cone. HNO3 (1 part). Properties It has highly corrosive and fuming nature. 9. (a) For making cake, baking powder is taken. If at home your mother uses baking soda instead of baking powder in cake, (i) How will it affect the taste of the cake and why? (ii) How can baking soda be converted into baking powder? (iii) What is the role of tartaric acid added to baking soda? (b) Name the acid present in ant sting and give its chemical formula. Also give the common method to get relief from the discomfort caused by the ant sting. Solution: [4] (a) (i) Baking powder has tasty tartaric acid which reacts with Na2 CO3 produced during decomposition of NaHCO3 and neutralises it, so if tartaric acid is not present, the cake will taste bitter due to the presence of sodium carbonate (Na2 CO3). (ii) By adding tartaric acid to baking soda we can form baking powder. (iii) Tartaric acid neutralises the sodium carbonate formed during decomposition of NaHCO3 hence, it makes the cake tasty and not bitter in taste. (b) The acid is formic acid (HCOOH). If baking soda (a base) is applied on the sting www.pioneermathematics.com S.C.O. - 326, Sector 40–D, CHD. Phone: 9815527721, 4617721 27 Pioneer Education {The Best Way To Success} IIT – JEE /AIPMT/NTSE/Olympiads Classes (biting area), it gives relief. 10. (a) A metal carbonate X on reacting with an acid gives a gas which when passed through a solution Y gives the carbonate back. On the other hand, a gas G that is obtained at anode during electrolysis of brine is passed on dry Y, it gives a compound Z, used for disinfecting drinking water. Identify XXG and Z. (b) What happens when nitric acid is added to egg shell? [4] Solution: (a) X is calcium carbonate. CaCO3 + dil. 2HCl CaCl2 + H2O + CO2 X Solution Y is lime water Ca(OH)2. Ca(OH)2 + CO2 CaCO3 +H2O Y During electrolysis of brine, Cl2 gas is released at anode. So, gas G is Cl2 gas (chlorine gas). Ca(OH)2 +Cl2 CaOCl2 + H2O Y G Z Hence, Z is calcium oxychloride (bleaching powder). (ii) Egg shells are made up of calcium carbonate, CaCO3. So, brisk effervescence due to the liberation of CO2 gas is observed. The reaction is CaCO3 +2HNO3 Ca(NO3)2 + H2O + CO2 www.pioneermathematics.com S.C.O. - 326, Sector 40–D, CHD. Phone: 9815527721, 4617721 28