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Atomic Structure Do you know your atomic structure? Basic Unit of Matter •ATOM • Sodium Atom Animation What is the charge of each subatomic particle? • Proton neutron •+ O • positive none electron negative Where are they found in the atom? Neutron and proton – in the nucleus Electron – outside the nucleus Helium atom animation Chemical Element • A pure substance that consists on only one type of atom Pure Substance: Iodine Atom • EX: every atom in a gold block looks like all the other gold atoms Periodic Table of the Elements Mendeleev Element Song(link) “The Elements” by Tom Lehrer • • • There’s antimony, arsenic, aluminum, • selenium, And hydrogen and oxygen and nitrogen and rhenium And nickel, neodymium, neptunium, germanium, And iron, americium, ruthenium, uranium, Europium, zirconium, lutetium, vanadium And lanthanum and osmium and astatine and radium And gold, protactinium and indium and gallium And iodine and thorium and thulium and thallium. • There’s yttrium, ytterbium, actinium, rubidium And boron, gadolinium, niobium, iridium And strontium and silicon and silver and samarium, And bismuth, bromine, lithium, beryllium and barium. There’s holmium and helium and hafnium and erbium • And phosphorous and francium and fluorine and terbium And manganese and mercury, molybdinum, magnesium, Dysprosium and scandium and cerium and cesium And lead, praseodymium, platinum, plutonium, Palladium, promethium, potassium, polonium, Tantalum, technetium, titanium, tellurium, And cadmium and calcium and chromium and curium. There’s sulfur, californium and fermium, berkelium And also mendelevium, einsteinium and nobelium And argon, krypton, neon, radon, xenon, zinc and rhodium And chlorine, cobalt, carbon, copper, Tungsten, tin and sodium. These are the only ones of which the news has come to Harvard, And there may be many others but they haven’t been discovered. Symbols of Elements • 1. First letter is capitalized • 2. Second letter (if there is one) is always lower case • EXAMPLES: • C F Al • Cl B Mn • Ca H Mg • Cr O Mo Which are symbols? Abbreviations for elements •C CO Why? Mn CO2 Ni •C Mn Ni • Only one capital letter Trace Elements Needed by some organisms but only in very small amounts Like iodine, we need only 0.15 mg per day A deficiency will cause a goiter What are trace elements? • Needed in the body in only small amounts • Like mg (milligrams) • WHY IMPORTANT IF WE DON’T NEED SO MUCH? • Minerals act as catalysts (speed up reactions) for many biological reactions EACH ELEMENT: All the same atoms • Photographic Periodic Table (link) Which are elements? • • • • • • • • Cu C CO Co N NO WHY? Cu C N only one kind of matter Atomic Number • Number of protons of an element Mass Number • • • • Protons plus neutrons Decimal number Will round off the number Average of masses of many atoms Mass Number • Mass of nucleus What about that decimal for mass number? = Average of all isotopes of carbon • Mass Number What is the mass number of Na? • Atomic Number Atomic Number? Mass Number? HOW TO FIND • Number of Protons = Atomic Number • Number of Electrons = Number of Protons = Atomic Number • Number of Neutrons = Mass Number Atomic Number How many? • Protons • Carbon 6 electrons 6 neutrons 6 • Chlorine • 17 17 18 What’s a neutral atom? • Number of protons = number of electrons • Example: carbon has 6 eand 6 p+ Is this a neutral atom? =p = e- Same Number of electrons as protons • WHY? • So the atom will be neutral (no excess charge) What is the mass number of…? • Carbon • WHY? • • • • nitrogen hydrogen 12 14 1 Decimal number on periodic table Not other number in succession Number of p + n What is the atomic number of? • Silicon WHY? fluorine sodium • 14 9 11 • Number in succession (not a decimal) • Number of protons How do you find the number of…? • Protons electrons • Atomic Number atomic mass no. number minus (if neutral) At. No. neutrons YOU NEED TO KNOW • The Names (spelled correctly) and the Symbols (written correctly) • “Naturally Occurring Elements in the Human Body” Radioisotopes • All elements with atomic numbers greater than 83 are radioisotopes meaning that these elements have unstable nuclei and are radioactive and some under 83 have isotope forms. Isotope: form of an element with a different number of neutrons What makes atoms radioactive? Their nuclei are unstable and they break down at a constant rate over time…and they have uneven numbers of protons and neutrons. Radioactive Decay of Uranium Some Radioactive Elements Radioactive Particles Given Off • Radioactive Decay of Uranium Isotopes • Are atoms of the same element that differ in the number of neutrons! Number of neutrons? Isotopes? Which is the neutral form? Which has more uneven number of protons and neutrons? Number of Protons Positive Uses of Radioisotopes Iodine-131 treat thyroid cancer Sr 89 treat bone and prostate cancer PET SCAN Uses of Radioisotopes • Positron Emission Tomography tracers Radioactive dating Sterillizing food and medical equipment Cancer treatment Technetium-99m has become the most widely used (80%) radioisotope for diagnosing diseased organs (especially brain, heart, and bone) Which are isotopes? • 20 F 9 16 O 8 WHY? 38 K 19 20 F 9 128 I 53 38 K 19 128 I 53 12 C 6 different # neutrons Formula • Abbreviation for a compound • A COMPOUND is two or more elements chemically bound: Which are formulas? Abbreviation for a compound • H2SO4 Why? Cl2 H20 Al H2SO4 H20 abbreviations for compounds (2 or more different kinds of elements) What is a compound? • 2 or more different elements chemically joined (2+ diff. capital letters) • HCl • H2SO4 H2O NOT O2 Which are atoms? •C N Why? N2 H20 • C and N only one in number Using The Correct Term (get handout) • Element • 1 kind of Atom, Na, H • Compound • 2 or more different kinds of elements chemically joined, NaCl • Abbreviation of an element, H, Cl • Symbol • Abbreviation of a compound • Formula Na2S • 1 unit of matter H Na Cl • Atom • Molecule • 2 or more atoms chemically joined H2, NaCl Which are compounds? • Na N Why? H2 NO2 H2O • NO2 • H 2O • 2 or more different elements chemically joined (2+ diff. capital letters) What’s the difference? • Co • Symbol CO co formula nuttin Which are molecules? • Co CO Why? CO2 O2 • CO CO2 O2 two or more atoms (alike or not alike, it doesn’t matter) bonded together What are the four… • Most abundant elements in living matter? C H O N What is the relative size? • Proton neutron electron • 1 amu • 1 amu ~1/2000 amu • AMU=atomic mass unit= 1/12 CARBON ATOM How do electrons arrange? • In the outer shells? • 2, 8, 8 • Fill inner shell first, then go to next shell out Get kinda complicated beyond 2,8,8…so that’s all we’ll do for now! Atoms that have the same number of electrons have the same chemical properties. How many electrons in each shell? •C O F Na • 2,4 2,6 2,7 2,8,1 What are ions? • Charged atoms • Have lost or gained an electron Lost or Gained How Many e-? • H+ Li+ Na+ K+ • Lost one e- • Be+2 Mg+2 Ca+2 • Lost 2 e- • Al+3 • Lost 3 e- • F- Cl- Br- I- • Gained one e- • • Gained 2 e- S-2 Note Ions and Formulas • Na+ Cl+1 -1 • Mg2+ Cl+2 -1 • Na+ S 2+1 -2 • Mg2+ S 2+2 -2 NaCl 1:1 MgCl2 1:2 Na2S 2:1 MgS 1:1 Which are ions? • Cl O-2 Why? Na+1 N2 • O-2 Na+1 • Charged atoms (lost or gained electrons) • show charges as superscripts Which electrons determine… • The chemical properties of the atom? • Outermost shell Periodic Table Hint: • You can tell how many electrons are in an atom’s outermost shell by just looking at its position on the periodic table!!!!! e- in outer shells 1 2 3 4 5 6 7 8 Which atoms combine… • with other atoms? • Ones that do not have filled outer electron shells What is the driving force to make atoms join with other atoms to form compounds? • TO HAVE FILLED OUTER ELECTRON SHELLS!!!!!!!!!!!!!!!!!!!!!!!! How does an atom… • Get a filled outer electron shell? • Gaining, losing, or sharing electrons If one electron is… • Lost what charge will the ion have? •+1 If one electron is gained… • What charge will the ion have? •-1 If 2 electrons are lost… • What charge will the ion have? •+2 If two electrons are gained… • What charge will the ion have? •-2 Making Correct Formulas: • Note how the ion charge becomes the subscript of the other ion • • • • Na+ ClMg2+ ClNa+ S-2 Mg2+ S-2 NaCl MgCl2 Na2S MgS What do we call the forces that… • Hold atoms together in a molecule? • Chemical bonds…not to be confused with James Bond IONIC BOND • What makes up ionic bonds? • IONS • WHY? • Opposite charged ions attract Covalent Bond • What makes up covalent bonds? • Atoms that are sharing electrons Comparing Bonds IONIC BOND (gain or lose e-) COVALENT BOND (sharing e-) How can covalent bonds be written? • Single bond • • C-C C:C double bond C=C C::C triple bond C=C C:::C