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Transcript
Physics 43 Ch 42 HW# Key
Serway 7th edition Problems: 16, 18, 19, 20, 50, 54, 62
16.
Plot the wave function 1s(r) (see Eq. 42.22) and the radial probability density
function P1s(r) (see Eq. 42.25) for hydrogen. Let r range from 0 to 1.5a0, where a0 is the
Bohr radius.
P42.16
is the ground state
hydrogen wave function.
is the ground state radial
probability distribution function.
18. The wave function for an electron in the 2p state of hydrogen is
What is the most likely distance from the nucleus to find an electron in the 2p state?
P42.18
so
Set
Solving for r, this is a maximum at
.
19. For a spherically symmetric state of a hydrogen atom, the Schrödinger equation in
spherical coordinates is
Show that the 1s wave function for an electron in hydrogen,
satisfies the Schrödinger equation.
P42.19
Substitution into the Schrödinger equation to test the validity of the solution yields
But
so
or
This is true, so the Schrödinger equation is satisfied.
20. In an experiment, electrons are fired at a sample of neutral hydrogen atoms and
observations are made of how the incident particles scatter. A large set of trials can be
thought of as containing 1 000 observations of the electron in the ground state of a
hydrogen atom being momentarily at a distance a0/2 from the nucleus. How many
times is the atomic electron observed at a distance 2a0 from the nucleus in this set of
trials?
P42.20 The hydrogen ground-state radial probability density is
The number of observations at
is, by proportion
50. As the Earth moves around the Sun, its orbits are quantized. (a) Follow the steps of
Bohr’s analysis of the hydrogen atom to show that the allowed radii of the Earth’s orbit
are given by
where MS is the mass of the Sun, ME is the mass of the Earth, and n is an integer
quantum number. (b) Calculate the numerical value of n. (c) Find the distance between
the orbit for quantum number n and the next orbit out from the Sun corresponding to
the quantum number n + 1. Discuss the significance of your results.
P42.50
(a) Using the same procedure that was used in the Bohr model of the hydrogen atom, we apply Newton’s
second law to the Earth. We simply replace the Coulomb force by the gravitational force exerted by the
Sun on the Earth and find
(1)
where v is the orbital speed of the Earth. Next, we apply the postulate that angular momentum of the
Earth is quantized in multiples of :
Solving for v gives
(2)
Substituting (2) into (1), we find
(3)
(b) Solving (3) for n gives
Taking
and
(4)
, and
,
,
,
, we find
(c) We can use (3) to determine the radii for the orbits corresponding to the quantum numbers n
and
:
and
Hence, the separation between these two orbits is
Since n is very large, we can neglect the number 1 in the parentheses and express the separation as
This number is much smaller than the radius of an atomic nucleus
quantized orbits of the Earth is too small to observe.
, so the distance between
54. Review problem. (a) How much energy is required to cause an electron in hydrogen
to move from the n = 1 state to the n = 2 state? (b) Suppose the electron gains this energy
through collisions among hydrogen atoms at a high temperature. At what temperature
would the average atomic kinetic energy 3kBT/2, where kB is the Boltzmann constant, be
great enough to excite the electron?
P42.54
(a)
The energy difference between these two states is equal to the energy that is absorbed.
Thus,
(b)
or
62.
The force on a magnetic moment z in a nonuniform magnetic field Bz is given by
Fz = z(dBz/dz). If a beam of silver atoms travels a horizontal distance of 1.00 m through
such a field and each atom has a speed of 100 m/s, how strong must be the field
gradient dBz/dz in order to deflect the beam 1.00 mm?
P42.62
and