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Chemical Reactions and Equations Chemical Reactions • when a substance changes identity – reactants- original – products- resulting • law of conservation of mass – total mass of reactants = total mass of products Chemical Reactions • chemical equation – represents identities and relative amounts of reactants and products in the chemical reaction – uses symbols and formulas Signs of Chemical Reaction • heat or light – can also happen with physical changes • gas bubbles – means a gas is being created as product • precipitate – solid is being created • color change Equations cannot tell us: • if the reaction will actually occur – depends on many factors affecting energy • the speed of the reaction – depends on chemical kinetics – can be very slow, almost unnoticeably • how the bonding actually changes – formula may not clearly show bonding Word Equations • uses names instead of formulas • helps you to write formula equation Symbols Used in Equations yields reversible above arrow: or heat heated MnO2 or Pt catalyst 25°C specific T requirement 2 atm specific P requirement after a formula: (s) solid (l) liquid (aq) aqueous: dissolved in water (g) gas Example • Description: Solid sodium oxide is added to water at room temperature and forms sodium hydroxide. • Word Equation: sodium oxide + water sodium hydroxide • Formula Equation: Na2O + H2O NaOH Writing Chemical Equations • most pure elements – written as elemental symbol • diatomic molecules – molecule containing only 2 atoms – some elements normally exist this way – H2, O2, N2, F2, Cl2, Br2, I2, At2 • other exceptions – sulfur: S8 – phosphorus: P4 Writing Equations • • • • Write Word equations to show reactants and products. Be sure to include symbols showing states of each reactant and product Be sure to write the correct formula for each (crossing over for ionic compounds!) Balancing the equation when you are finished. Coefficients • whole numbers in front of formula • distributes to numbers of atoms in formula • specifies the relative number of moles and molecules involved in the reaction • used to balance the equation Balancing Equations • 1. 2. 3. 4. 5. 6. ONLY add/change coefficients- NEVER subscripts!!! balance one type of atom at a time balance polyatomic ions first balance atoms that appear only once second balance H and O last simplify if you can Check at end! Example 1 • Description: Zinc metal is added to hydrochloric acid to create zinc chloride and hydrogen gas. • Word Equation: zinc + hydrochloric acid zinc chloride + hydrogen Example 2 • Solid calcium metal reacts with water to form aqueous calcium hydroxide and hydrogen gas. • calcium + water calcium hydroxide + hydrogen • Ca(s) + H2O(l) Ca(OH)2(aq) + H2(g) • Ca(s) + 2H2O(l) Ca(OH)2(aq) + H2(g) Example 3 • solid zinc metal reacts with aqueous copper (II) sulfate to produce solid copper metal and aqueous zinc sulfate • zinc + copper (II) sulfate copper + zinc sulfate • Zn(s) + CuSO4(aq) Cu(s) + ZnSO4(aq) • Zn(s) + CuSO4(aq) Cu(s) + ZnSO4(aq) Example 4 • Hydrogen peroxide in an aqueous solution decomposes to produce oxygen and water • hydrogen peroxide oxygen + water • H2O2(aq) O2(g) + H2O(l) • 2H2O2(aq) O2(g) + 2H2O(l) Example 5 • Solid copper metal reacts with aqueous silver nitrate to produce solid silver metal and aqueous copper (II) nitrate • copper + silver nitrate silver + copper (II) nitrate • Cu(s) + AgNO3(aq) Ag(s) + Cu(NO3)2(aq) • Cu(s) + 2AgNO3(aq) 2Ag(s) + Cu(NO3)2(aq) Example 6 • Carbon dioxide gas is bubbled through water containing solid barium carbonate, creating aqueous barium bicarbonate • carbon dioxide + water + barium carbonate barium bicarbonate • CO2(g) + H2O(l) + BaCO3(s) Ba(HCO3)2(aq) • CO2(g) + H2O(l) + BaCO3(s) Ba(HCO3)2(aq)