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Transcript
Magnetism and electron configuration
• Electrons in atoms are moving charges.
• produce magnetic field (consider as an example the electric
current). Electrons act as tiny magnets.
• Magnetic field mainly produced by spin motion.
• Paired electrons have a total spin of zero, have thus no total
magnetic field.
paired
unpaired
II/
• diamagnetism
- slightly repelled by magnetic field
- no unpaired electrons
• paramagnetism
- attracted to magnetic field
- one or more unpaired electrons
• ferromagentism
- case of paramagnetism where the substance retains its
magnetism
- Very strongly attracted to magnetic field
II/
Paramagnetism
II/
• Exercise:
• Which of the following species do you expect to exhibit
paramagnetism:
K
F-
Hg
Ba2+
Ti2+
Cu2+
N
K: [Ar] 4s1
Ba: [Xe] 6s2
Ba2+: [Xe]
Cu: [Ar] 4s1 3d10
Cu2+: [Ar] 3d9
II/