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PV Cells Technologies • Characterization criterion: • Thickness: • Conventional – thick cells (200 - 500 μm) • Thin film (1 – 10 μm). Tend to be less costly than conventional (think) cells but they also tend to be less reliable and efficient. • Crystalline configuration: • Single crystal • Multicrystalline: cell formed by 1mm to 10cm single crystal areas. • Polycrystalline: cell formed by 1μm to 1mm single crystal areas. • Microcrystalline: cell formed by areas of less than 1μm across. • Amorphous: No single crystal areas. • p and n region materials: • Same material: homojunction (Si) • Different material: heterojunction (CdS and CuInSe2) 1 © Alexis Kwasinski, 2012 PV Cells Technologies Uni-Solar solar shingle BP SX170B Polycrystalline BP SX170B Monocrystalline Uni-Solar Laminate PVL-136 Amorphous Mitsubishi PV-TD 190MF5 Multicrystalline PV Modules at ENS 2 © Alexis Kwasinski, 2012 PV Cells Technologies • Thick film fabrication techniques: • Czochraski’s (CZ): for single-crystal silicon. Costly. • Float zone process (FZ): also for single-crystal silicon. Costly • Ribbon silicon • Cast silicon: for multicrystalline cells. Less costly. • Thin film • Can be used embedded in semitransparent windows. • Techniques: • Amorphous Silicon: can achieve higher efficiencies (in the order of 42% thanks to the multijunction (different multiple layers) in which each layer absorb photons with different energy. • Gallium Arsenide (GaAs): relatively high theoretical efficiency (29 %) which is not significantly affected by temperature. Less sensitive to radiation. Gallium makes this solution relatively expensive. • Gallium Indium Phosphide (GaInP): similar to GaAs. • Cadmium Telluride (CdTe): Issue: Cd is a health hazard (it is very toxic). • Copper Indium Diselenide (CIS or CuInSe2): relatively good efficiency) • Silicon Nitrade (N4Si3) 3 © Alexis Kwasinski, 2012 The p-n junction diode n-type substrate Bias voltage p-type substrate Id • Vd is the diode voltage • I0 is the reverse saturation current caused by thermally generated carriers • At 25 C: Vd 0.026 Id I0 e 1 4 Ideal diode Real diode I0 © Alexis Kwasinski, 2012 d qV kT I d I 0 e 1 PV Cells physics The current source shifts the reversed diode curve upwards ISC VOC Same curve The bias source (voltage source) is replaced by a current source powered by the photons 5 ISC p-n junction is equivalent to a diode © Alexis Kwasinski, 2012 Reverse v-i curve for the diode PV Cell steady state characteristic • From Kirchoff’s current law: I PV I SC I d I SC qVkTd I 0 e 1 • The open circuit voltage is VOC V ( I PV kT I SC 0) ln 1 q I0 Maximum power point Power P I PVVPV Pmax 0.7 • Voc • Isc Current 6 © Alexis Kwasinski, 2012 PV Cell steady state characteristic • Dependence on temperature and insolation: 7 © Alexis Kwasinski, 2012 PV Cell steady state characteristic • More on the dependence on temperature and insolation: 8 © Alexis Kwasinski, 2012 More complex steady-state models • For a more realistic representation we can consider the following (equivalent to a diode’s model): • 1) Effect current leakage slope ISC Rp I PV ( I SC I d ) V Rp • 2) Effect of internal ohmic resistance + Vd ISC 9 RS qVkTd I 0 e 1 + I PV I SC V where Vd = V+IRS This is a transcendental equation - © Alexis Kwasinski, 2012 V IRS 1 Rp PV more complex steady-state model • Both effects can be combined to obtain the more realistic (and complex) steady state model: + ISC Rp RS Vd - I PV I SC + V - qVkTd Vd I 0 e 1 Rp where Vd = V+IRS This is a transcendental equation 10 © Alexis Kwasinski, 2012 Dynamic effects Capacitive effect • As with any diode, there is an associated capacitance. However, this capacitance is relatively small, so the effects on the output can often be neglected. Therefore, PV modules can follow a rapidly changing load very well. •One undesirable effect of the capacitance is that it makes PV cells more susceptible to indirect atmospheric discharges. 11 © Alexis Kwasinski, 2012 Modules combination • PV cells are combined to form modules (panels). Modules may be combined to form arrays. More modules (or cells) in series More modules (or cells) in parallel • When modules are connected in parallel, the array voltage is that of the module with the lowest voltage. •When several modules are connected in series to achieve a higher array voltage, the array’s current equals that of the module delivering the lowest current. 12 © Alexis Kwasinski, 2012 Shading (Rp+Rs)(n-1)Imodule • A shadowed module degrades the performance of the entire array + + One module with 50% shadow One module with 100% shadow (n-1)Vmodule Two modules with 100% shadow 13 © Alexis Kwasinski, 2012 Bypass diode for shadowing mitigation • Bypass diodes can mitigate the effects of shadows but they don’t solve the issue completely. • A better solution will be presented when discussing power electronics interfaces. No shade Shaded without bypass diode 14 © Alexis Kwasinski, 2012 Shaded with bypass diode