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CHEMISTRY 30 / UNIT C CHEMICAL CHANGES OF ORGANIC COMPOUNDS [A] CONCEPTS DEVELOPED FOR THIS UNIT – ORGANIC COMPOUNDS NAMING COMPOUNDS STRUCTURAL ISOMERS MONOMERS ALIPHATIC AND AROMATICS SATURATED/UNSATURATED STRUCTURAL FORMULAS POLYMERS ESTRIFICATION IDENTIFY FUNCTIONAL GROUPS – ALCOHOLS , CARBOXYLIC ACIDS – ESTERS HOLOGENATED HYDROCARBONS 1) COMBUSTION REACTIONS 2) POLYMERIZATION 4) SUBSTITUTION REACTION 5) ELIMINATION REACTION 3) ADDITION REACTION GENERAL OUTCOME 1 - EXPLORE ORGANIC COMPOUNDS AS A COMMON FORM OF MATTER [1] SPECIFIC OUTCOMES FOR KNOWLEDGE - students will K.1 Define organic compounds containing carbon, recognizing inorganic exceptions such as ( carbonates,cyanides, carbides, and oxides of carbon ) K.2 Identify and describe significant organic compounds in daily life: demonstrating generalized knowledge of their origins and applications(eg. methane,methanol,ethane,ethanol,ethanioic acid,propane,benzene,octane glucose, polyethylene . K.3 Name and draw structural, condensed structural and line diagrams and formulas, using IUPAC nomenclature guidelines for saturated and unsaturated aliphatic(including cyclic) and aromatic compounds a) a) - containing up to 10 carbons in parent chain (eg: pentane : 3-ethyl-2,4-dimethylpentane and cyclic structures like cyclopentane ) b) - containing only one type of functional group (with multiple bonds categorized as a functional group) eg: pent - 2- ene / and including simple halogenated hydrocarbons eg: 2 - chloropentane alchols – eg: pentan -2-ol / carboxylic acids – eg: pentanoic acid / and esters – eg : methylpropanoate c) - and with multiple occurrences of the functional group limited to halogens – eg: 2-bromo-2-chloropentane and alcohols – eg: pentane-2,3-diol K.4 Identify types of compounds from the hydroxyl,carboxyl,ester linkage and halogen functional groups when given the structural formula K.5 Define structural isomerism as compounds having the same empirical formulas, but with different structural fomulas, and relate the structures to the variations in the properties of the isomers K.6 Compare,both with hologous series and among compounds with different functional groups, the boiling points and solubility of examples of aliphatics,aromatics,alcohols and carboxylic acids. K.7 Describe, in general terms, the physical,chemical and technological processes ( fractional distillation and solvent extraction ) used to separate organic compounds from natural mixtures of solutions ; eg : petroleum refining , bitumen recovery GENERAL OUTCOME 2 - STUDENTS WILL DESCRIBE CHEMICAL REACTIONS OF ORGANIC COMPOUNDS [2] SPECIFIC OUTCOMES FOR KNOWLEDGE - Students will K.1 Define , illustrate and provide examples of simple addition, substitution, elimination, estrification and combustion reactions K.2 Predict products and write and interpret balanced equations for the above reactions K.3 Define, illustrated and provide examples of monomers( eg: ethylene) polymers (eg: polyethylene) and polymerization in living systems (eg: carbohydrates,proteins) and nonliving systems (eg: nylon ,polyester and plastics) K.4 Relate the reactions described above to major reactions that produce thermal energy and economically important compounds from fossil fuels Specific Outcomes for Skills S.1 formulate questions about observed relationships and plan investigations of questions, ideas problems and issues. - predict ester formed from an alcohol and an organic acid - describe procedures for the safe handling, storage and disposal of materials used in the lab ( WHMIS) - consumer product labeling - design a procedure to prepare a polymer S.2 Conduct investigations into relationships among observable variables and use a broad range of tools and techniques to gather and record information in the reaction of organic compounds. - synthesize a polymer, such as nylon or slime - produce an ester / investigate the making of soap - Research bitumen grading / octane ratings of fuels – how they are determined - Investigate issues related to green house gases / methane, carbon dioxide, water, nitrogen dioxide - analyze the contribution of green house gases to climate change - use models to illustrate polymers - analyze a process for producing polymers - analyze negative by-products related to chemical processes in organic chemistry SPECIFIC OUTCOMES FOR SCIENCE TECHNOLOGY AND SOCIETY (STS) (1) (The social and environmental contexts emphasis) STUDENTS WILL: 1) Explain how science and technology are developed to meet the societal needs and expand human capability - describe where organic compounds are used in processes and common products, such as in hydrogenation to produce margarine and esters used in flavoring agents for foods - describe Aboriginal use of organic substances for waterproofing, tanning dyeing, medicine,salves, and insect repellents 2) Explain that science and technology have influenced, and been influenced by, historical development and societal needs. - explain how, as a result of chemistry and chemical technology, synthetic compounds of great benefit to society, such as plastics, medicines, hydrocarbon fuels, and pesticides, have been produced. SPECIFIC OUTCOMES FOR SCIENCE TECHNOLOGY AND SOCIETY (STS) (2) - describe processes for obtaining economically important compounds from fossil fuels ( eg : hydrocracking and catalytic reforming) (eg: describe bitumen upgrading) - describe major reactions used in the petrochemical industry in Alberta – such as in the production of methanol , ethylene glycol , polyethylene, polyvinyl chloride (PVC) and urea formaldehyde - investigate nanoscience and nanotechnology in the petrochemical industry and the medical sciences - describe processes involved in producing fuels: ( eg: adjusting octane/octane rating / reducing sulfur content / adding compounds such as additives –ethanol) - assessing the positive and negative affects of various reactions involving organic compounds Quality of life issues / environmental impact (examples) burning of fossil fuels and climate change production of pharmaceuticals and foods by-products (CO2 , dioxins ) of common reactions recycling of plastics impact of CFC’s and Hydrochlorofluorocarbons (HCFC’s) on the ozone layer transfats in the diet ( unsaturated/polyunsaturated vs saturated fats )