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Chapter 9 2pt each 1. The number of valence electrons in the element Nitrogen is a. 2 b. 3 c. 5 d. 7 2. As bond length _________ the bond strength is __________. a. lengthens/weaker c. shortens/stronger b.shortens/weaker d. lengthens/stronger 3. In which molecule is the carbon/oxygen bond the strongest? (CO, CO2,CO3-2, H2CO3) a. CO c. CO3-2 b. CO2 d. H2CO3 4. The formula for sulfurous acid is. a. SF2 b. H2SO4 c. HSO3 d. HSF 5. Which of the following bonds is most negatively charged? a. C-H b. C-S c.C-N d. C-O 6. Based on symmetry which one of these molecules is non-polar? a. H3O+ b. PCl5 c. H2O d. NH3 7. The molecular shape of PH3 would be. a. Trigonal bipyramidal b. Bent c. Linear d. Trigonal pyramidal 8. As I move from left to right the electronegativity ____________and as I move from top to bottom it ___________. a. Increases/Decreases b. Decreases/Increases c. stays the same/Increases c. Decreases/stays the same 9. What is the correct name for this compound? NO a. Nitrous oxide b. Nitric acid c. Nitrogen monoxide d. Mononitrogen monoxide 10. Draw the Lewis structures for each of the following molecules or ions. 2pt each a. H2S b. SO2 c. PO3-3 Final Exam Ch 10, 11, 12, 22, 16 Chapter 10 2pts each 1. The products of a combustion reaction are always: a. carbon dioxide and water b. oxygen and water c. carbon dioxide and oxygen d. none of these 2. The solvent in an aqueous solution is always a. Oxygen b. an acid c. a base d. water 3. A solid produced during a chemical reaction is called a (an) a. solute b. precipitate c. spectator ion d. solvent 4. Balance the following equation. Fe(s) + H2O(l) Fe2O3(s) + H2(g) 5. Balance the following equation NH3(aq) + O2(g) NO(g) + H2O(l) 6. The equation in #14 is an example of a. Decomposition rxn b. Single replacement rxn c. Double replacement d. Combustion rxn 7. In a double replacement reaction the ______reacts with the (an) ______ to form______________. a. Anion/Cation/ single product b. Cation/Anion/Two different compounds b. Metal/Oxygen/Two different compounds d. Element/Element/Water 8. What is the difference between the net ionic equation and the ionic equation? 2pts 9. Please write the word equation for the following reaction. CaCO3(s) + 2HCl(aq) CaCl2(aq) + H2O(l) + CO2(g) Chapter 11 10. Determine the number of moles of 84.6 L of tetrahydrogen nonoxide.2pt 11. Find the mass in grams of 5.00 x 1023 molecules of fluorine gas.2pt 12. How many representative particles are in each of these substances? 6pts a. Cl2 b. AlCl3 c. Kr 13. How many nitrogen atoms are in 10 moles of nitrogen dioxide? 2pt 14. How many kilograms of calcium can be recovered from 550 Kg of the compound calcium carbonate? 3pt 15. The Percent composition of a compound is 24%C and 76% F. What is the empirical formula? If the molecular mass is 150 grams, what is the molecular formula? 6pt 16. What is the formula and name of a hydrate that is 85.3% Barium and 14.7% water? 4pt 27. Why is the difference between the atomic mass and the molar mass? 2pts 17. Extra credit: the number 6.02 x 1023 is also called ____________ number. Chapter 12: Multiple Choice: Write the letter of the best answer in the blank to the left of the question. 2pts each ____28. The substance that limits or determines the amount of product that can be formed in a reaction is called __________________. a. limiting reagent b. excess reagent c. actual yield d. theoretical yield ____29. The amount of product that forms when a reaction is carried out in the laboratory is called a ___________________. a. limiting reagent b. excess reagent c. actual yield d. theoretical yield ____30. In a chemical reaction a. mass is conserved c. moles are conserved conserved b. atoms are conserved d. both mass and atoms are Perform these calculations showing ALL you work for extra credit! 31. Ammonia, NH3 is a typical ingredient in household cleaners. It is produced through a combination reaction involving nitrogen gas and hydrogen gas. If 10 moles of hydrogen gas reacts with an excess of nitrogen gas, how many moles of ammonia are produced? 2pts N2(g) + 3H2(g) 2NH3(g) 32. How many grams of CO are needed to react with an excess of Fe2O3 to produce 558 g of Fe? The equation for the reaction is: (2pts) Fe2O3(s) + 3CO(g) CO2(g) + 2Fe(s) 33. What is the limiting reagent when 50 g of nitrogen reacts with 10.7 g of hydrogen according to this balanced equation? (4pts) N2(g) + 3H2(g) 2 NH3(g) 34. (a) if 4 g of hydrogen gas are made to react with excess carbon monoxide, how many grams of CH3OH can theoretically be produced according to the following equation? (2pts) CO(g) + 2H2(g) CH3OH(l) (b) If 28 g of CH3OH are actually produced, what is the percent yield? (2pts) Chapter 16 35. The specific heat of ethanol is 2.44 J/gxC. How many kilojoules of energy are required to heat 50g of ethanol from -20.0 degrees C to 68.0 degrees C? 3pts a. 10.7 kJ b. 2.44 kJ c. 8.30 kJ d. 1.22 kJ 36. 3.00 g of aluminum foil is placed in an oven and heated from 20.0 degrees C to 662.0 degrees C. If it absorbs 1728 J of heat, what is the specific heat of aluminum? 3pts a. 0.131 J/gxC b. 0.897 J/gxC c. 0.870 J/gxC d. 2.61 J/gxC 37. A 15.6g sample of ethanol absorbs 868 J as it is heated. If the initial temperature of ethanol was 21.5 degrees C and the specific heat of ethanol is 2.44 J/gxC, then what is the final temperature of the ethanol? 3pts a. 44.3 C b. – 44.3 C c. 22.15 C d. 88.6 C 38. Determine the delta H for the reaction of aluminum and sulfur dioxide. 4Al(s) + 3SO2(g) 2Al2O3(s) + 3S(s) Use the following equations. 4Al(s) + 3O2(g) 2Al2O3(s) Delta H = -3352 kJ/mole S(s) + O2(g) SO2(g) Delta H = -297 kJ/mole a. -4243 kJ c. -3649 kJ b. -3055 kJ d. -2461 kJ 39. In describing a chemical reaction, what is meant by the system? The surroundings? 3pts 40. Describe the differences between enthalpy, entropy, and free energy and give the correct symbols for each concept. 6pts Chapter 22 41. Write the structural formulas for each of the following.4pts a. 2-methyhexane b. 2,3-dimethypentane 42. Name the compound represented by each of the following structural formulas. 4pts a. CH3CH2CH2CH2CH3 c. CH3CH2CHCH2CH3 | CH2 | CH3 43. Write the name and draw the structure of the alkyl group that corresponds with the following alkanes. 6pts a. methane b. butane c. octane 44. Explain the difference between a saturated hydrocarbon and an unsaturated hydrocarbon chain. 2pts 45. Extra Credit: Name one thing you liked or enjoyed learning about and one thing you did not like learning about this class. 2pts