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The Institute of Physical Chemistry of the Polish Academy of Sciencies
The Institute of Physical Chemistry of the Polish Academy of Sciencies

The rotation of a homonuclear linear molecule
The rotation of a homonuclear linear molecule

... Since it has just been argued that the ortho and para spin isomers can be distinguished by their thermodynamics, it might be possible to devise a way to separate them using these properties. One obvious way is to use their differing freezing and boiling points. Another is to use their different rete ...
Lecture 2 Hamiltonian operators for molecules CHEM6085: Density
Lecture 2 Hamiltonian operators for molecules CHEM6085: Density

... Please note that in all of the questions below and for the rest of the course, whenever we mention “electronic molecular Hamiltonian” we assume the molecular Hamiltonian operator after the application of the BO approximation ...
Problems
Problems

Photosynthesis
Photosynthesis

... 2. Sugar formation (reduction): 6 ATP and 6 NADPH are used to convert 6 PGA into 6 PGAL (3 C, also called G3P) through a series of reactions 1 PGAL is released to the cell; 5 continue on in the cycle PGAL is the actual product of photosynthesis; can be used as a building block for carbohydrates or o ...
Chemistry Learning Goals Chap 14 Solutions Minniear
Chemistry Learning Goals Chap 14 Solutions Minniear

... Given a common substance, SWBAT determine whether it is a solution or a mixture. SWBAT define miscible and immiscible and given examples of each. SWBAT define solvent and solute and in a given solution, identify the solute and solvent. SWBAT explain saturated, unsaturated and supersaturated solution ...
File
File

... 1s2  The large number "1" refers to the principle quantum number "n" which stands for the energy level. It tells us that the electrons of helium occupy the first energy level of the atom.  The letter "s" stands for the angular momentum quantum number "l". It tells us that the two electrons of the ...
Slides - Jung Y. Huang
Slides - Jung Y. Huang

... STED Principle: an initial excitation pulse is focused on a spot. The spot is narrowed by a second, donut-shaped pulse that prompts all excited fluorophores to STED. This leaves only the hole of the donut in an excited state, and only this narrow hole is detected as an emitted fluorescence. The ligh ...
Chapter 8 The quantum theory of motion
Chapter 8 The quantum theory of motion

1 - PLK Vicwood KT Chong Sixth Form College
1 - PLK Vicwood KT Chong Sixth Form College

Quantum Chemical Simulations and Descriptors
Quantum Chemical Simulations and Descriptors

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(2 hours) This paper con - University of Southampton

... numbers n, l and m which are used to describe the electronic states of hydrogen? State the inequalities which limit the possible combinations of n, ...
lect19-20
lect19-20

The Lippmann-Schwinger equation reads ψk(x) = φk(x) + ∫ dx G0(x
The Lippmann-Schwinger equation reads ψk(x) = φk(x) + ∫ dx G0(x

energy
energy

... an electron in an atom is called its ground state. Electrons must absorb a specific “quantum of energy” to be excited to a higher energy level. This is said to be it’s “excited state” When the excited electron drops back down to its “ground state” it emits a photon of light with the same energy as t ...
Ch 6 notes 6.1 to 6.4
Ch 6 notes 6.1 to 6.4

Modeling excess heat and related issues Peter Hagelstein Research Laboratory of Electronics
Modeling excess heat and related issues Peter Hagelstein Research Laboratory of Electronics

A Little Coherence in Photosynthetic Light Harvesting
A Little Coherence in Photosynthetic Light Harvesting

... To demonstrate how 2DES has been important in providing these new insights, we first describe how this information is manifested in a 2-D spectrum for a model system. The 2DES experiment uses femtosecond laser pulses to excite electronic absorption bands of the system being studied (e.g., a protein ...
Electronic Structure - Chemistry Teaching Resources
Electronic Structure - Chemistry Teaching Resources

Rotational−Vibrational Levels of Diatomic Molecules Represented
Rotational−Vibrational Levels of Diatomic Molecules Represented

Atomic Term Symbols and Energy Splitting
Atomic Term Symbols and Energy Splitting

肖连团 - 山西大学
肖连团 - 山西大学

... 4.1 EFFICIENT DETECTION OF A SINGLE EMITTER IN TRANSMISSION • In the weak excitation regime, the effect of a molecule on an incident plane wave can be formulated as ...
Dissociation energy of the C-H bond in chloroform Cl3C
Dissociation energy of the C-H bond in chloroform Cl3C

... limit, following the Birge-Sponer method. The experimental procedure follows that published by Myrick, et al.4 Quantum-chemical calculations will be done with density functional theory (DFT), an electronic-structure theory that includes correlation energy. The "hybrid" functional B3LYP will be used. ...
docx - Pdx
docx - Pdx

... energy levels of an atom. Increase the intensity of the lamp using the Lamp Control slide button. Vary the light wavelength to a color that has a low energy and then to a color with a high energy. ...
Midterm exams I
Midterm exams I

... 18. Write an expression for Fourier transform of the step function ...
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Franck–Condon principle



The Franck–Condon principle is a rule in spectroscopy and quantum chemistry that explains the intensity of vibronic transitions. Vibronic transitions are the simultaneous changes in electronic and vibrational energy levels of a molecule due to the absorption or emission of a photon of the appropriate energy. The principle states that during an electronic transition, a change from one vibrational energy level to another will be more likely to happen if the two vibrational wave functions overlap more significantly.
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