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Organic Families: Summary Chart
Organic Families: Summary Chart

... The more C atoms present, the harder it is to break the bonds. The more C atoms, the higher the boiling point. Alkenes and alkynes are more reactive than alkanes due to their double/triple bonds (unsaturated). Presence of OH group makes alcohol more polar than hydrocarbons. Therefore, boiling point ...
Group 2 - UC Davis Canvas
Group 2 - UC Davis Canvas

A2 LEVEL CHEMISTRY 4.1.1 ARENES TEST Answer all questions
A2 LEVEL CHEMISTRY 4.1.1 ARENES TEST Answer all questions

... The chemist found that when benzene reacts with bromine, a halogen carrier is required as a catalyst. Write an equation for this reaction. You do not need to show the halogen carrier in your equation. ...
organic revision nots
organic revision nots

chem 217 intermediate chemistry ii assignment #5 3/9/00 due: 3/23/00
chem 217 intermediate chemistry ii assignment #5 3/9/00 due: 3/23/00

... R = H (aldehyde), CH3 (ketone) and OEt (ester) The decreasing order of electron-withdrawing ability is CHO > COR > CO2R hence the order of pKa values given. Resonance structures best illustrate this: ...
Diphenylsilene - American Chemical Society
Diphenylsilene - American Chemical Society

... least squares analyses of the expression k d m y = ko + kq[Q]. b2,3Dimethyl-l,3-butadiene. Not determined. well as several other products which have not yet been rigorously identified. At least one of these is the product of addition of the solvent to 2, according to G C / M S analysis of the crude ...
chirality - KS5Chemistry
chirality - KS5Chemistry

... NaOH needed (1) for first two marks acidify with /add excess HNO3 (1) [If HCl is added here, only the NaOH mark can score] Accept neutralise with nitric acid ...
Part 1
Part 1

... a) thing you’re naming the compound after (double bond if alkene; -OH group if alcohol, etc) note: for multiple double bonds -diene, -triene, -tetraene b) first branch/substituent group c) If both ends have the same first branching number, then number chain to minimize position of second branch (an ...
Principles of Biochemistry 4/e
Principles of Biochemistry 4/e

... Other Furanose Conformations • Envelope – one of the five ring atoms is out-of-plane & others are coplanar • Twist – two of the five ring atoms are out-of-plane, one on either side of the plane formed by the other 3 ...
chemistry ch4 - The Student Room
chemistry ch4 - The Student Room

... 2-Aminobenzenecarboxylic acid, unusually for an aromatic compound, is very soluble in water. One reason for this solubility is its ability to hydrogen bond with water molecules. Describe how this compound forms hydrogen bonds with water, illustrating your answer with a diagram. ...
Molecular Models of Functional Groups
Molecular Models of Functional Groups

... carbon. Add a carboxyl group (-COOH) to this carbon. You have just constructed glycine, the simplest of the amino acids. Now construct glycine as it would appear when dissolved in water. a) ...
Isomers
Isomers

Group 13 Compounds - University of Ottawa
Group 13 Compounds - University of Ottawa

Enzyme Activity
Enzyme Activity

... Therefore, in the presence of a competitive inhibitor, more substrate is needed to achieve Vmax: Competitive inhibitors do not alter Vmax. The effect of a competitive inhibitor is reversed by increasing ...
Oxidation of alcohols
Oxidation of alcohols

... Oxidation of alcohols ...
esters - wellswaysciences
esters - wellswaysciences

Chem 150 Unit 9 - Biological Molecules II
Chem 150 Unit 9 - Biological Molecules II

labPhuc NguyenLab
labPhuc NguyenLab

... the presents of alkene. The precipitation turns into a brownish red color. This process was an E1, because it showed first order kinetics as the breaking of the C-H bond occurred after the rate limiting step. The primary reactant, 4-methylcyclohexanol is a secondary alcohol, and was therefore requir ...
Carboxylic Acid Derivatives and Nitriles
Carboxylic Acid Derivatives and Nitriles

... The mechanism for all of the above reactions (except the last [Friedel-Crafts]) is pretty much the same – a nucleophile adds to the electrophilic carbonyl group, creating a tetrahedral intermediate. The electrons on oxygen then pop down, expelling the good leaving group (Cl-). This type of reaction ...
Heat of reaction
Heat of reaction

2014
2014

... Use the information below to answer questions 7-10. PCl5 (g) ⇆ PCl3 (g) + Cl2 (g) PCl5 (g) decomposes into PCl3 (g) and Cl2 (g) according to the equation above. A sample of PCl5 (g) is placed into a rigid, evacuated 1.00 L container. The initial pressure of the PCl5 (g) is 1.00 atm. The temperature ...
STRUCTURE, INTERMOLECULAR FORCES AND SOLUBILITY
STRUCTURE, INTERMOLECULAR FORCES AND SOLUBILITY

كيمياء عضويةc - جامعة دمنهور
كيمياء عضويةc - جامعة دمنهور

... Deduce chemical and structural formulas of organic compounds. Describe differences between and similarities of reactions of alkyl and aryl halides, alcohols and phenols, aldehydes and ketones. Differentiate the carbonyl group in aldehydes and ketones, and hydroxyl group in alcohols and phenols. Corr ...
08 PowerPoint
08 PowerPoint

... Balanced Equations – use coefficients  H2 + Cl2  2 HCl ...
Demonstrate understanding of the properties of organic compounds
Demonstrate understanding of the properties of organic compounds

... • Water can be removed using heat and a catalyst to produce an alkene Conc H2SO4 or Al2O3 at 1700C ...
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Asymmetric induction



Asymmetric induction (also enantioinduction) in stereochemistry describes the preferential formation in a chemical reaction of one enantiomer or diastereoisomer over the other as a result of the influence of a chiral feature present in the substrate, reagent, catalyst or environment. Asymmetric induction is a key element in asymmetric synthesis.Asymmetric induction was introduced by Hermann Emil Fischer based on his work on carbohydrates. Several types of induction exist.Internal asymmetric induction makes use of a chiral center bound to the reactive center through a covalent bond and remains so during the reaction. The starting material is often derived from chiral pool synthesis. In relayed asymmetric induction the chiral information is introduced in a separate step and removed again in a separate chemical reaction. Special synthons are called chiral auxiliaries. In external asymmetric induction chiral information is introduced in the transition state through a catalyst of chiral ligand. This method of asymmetric synthesis is economically most desirable.
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