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Topic 8 Assessed Homework Task - A
Topic 8 Assessed Homework Task - A

... Ethanol is an important fuel. A dilute aqueous solution of ethanol can be produced by the fermentation of an aqueous solution of glucose. It is claimed that the ethanol obtained from this solution is a carbon-neutral biofuel. Write an equation for this fermentation reaction. Give two other essential ...
6-organic - fixurscore
6-organic - fixurscore

... tertiary carbocation is made stabilised by the electron releasing methyl groups around it. (see alkenes topic for another example of this). Also the bulky methyl groups prevent the hydroxide ion from attacking the halogenoalkane in the same way as the mechanism above ...
Chemistry 250A -- Exam #3 Answer Key -
Chemistry 250A -- Exam #3 Answer Key -

... formation of the products. Then clearly explain why only one product is obtained under the first set of conditions, and why a mixture favoring the other product is obtained under the second set of conditions. CH3CH2O H ...
Carboxylates/esters vs ketones/aldehydes
Carboxylates/esters vs ketones/aldehydes

... BH3 becomes B(OC2H5)3 by reacting with ethanol, then, when heated with water, becomes B(OH)3. The mechanism of the NaBH4 reduction in a protic solvent such as ethanol, methanol, and water is known to be quite complex since NaBH4 reacts with the solvent, e.g., NaBH4 + C2H5OH → NaBH3(OC2H5) + H2 Becau ...
synthesis reaction
synthesis reaction

... during a chemical reaction is called an oxidation.  Oxygen is not necessary for an element to go through oxidation. This is a broad term for losing electrons.  Sodium (Na) atoms go through oxidation to become ions: Na  Na+ + 1e-. Everything in groups 1-13 can go through oxidation.  In a chemical ...
Chapter 26 Functional Groups and Organic Reactions
Chapter 26 Functional Groups and Organic Reactions

... compounds with an -OH group – The -OH functional group in alcohols is called a “hydroxyl” group; thus ROH can represent the formula, where “R” is an alkyl group  How is this different from the hydroxide ion? (covalently bonded to the carbonnot ionically as in hydroxides) ...
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Topic 16 Test - A

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Presentation - Chem Rxns - stpats-sch3u-sem1-2013
Presentation - Chem Rxns - stpats-sch3u-sem1-2013

... A reaction doesn’t occur unless the particles collide with a certain minimum energy called the activation energy of the reaction Activation energy is the minimum energy required before a reaction can occur.You can show this on an energy profile for the reaction. For a simple over-all exothermic reac ...
Elimination Reactions
Elimination Reactions

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Chapter 4: Carbon and the Molecular Diversity of Life
Chapter 4: Carbon and the Molecular Diversity of Life

... Concept 4.3 A small number of chemical groups are key to the functioning of biological molecules 9. Here is an idea that will recur throughout your study of the function of molecules: Change the structure, change the function. You see this in enantiomers, you will see it in proteins and enzymes, and ...
Alkenes - MsReenChemistry
Alkenes - MsReenChemistry

... If the halogen used is an aqueous solution of bromine (bromine water), the orange-brown colour of bromine solution is decolourised. ...
Chapter 16. Biological Reagents
Chapter 16. Biological Reagents

CHM412 June 2013 paper
CHM412 June 2013 paper

... Within the H-bonding species, Carboxylic acids form dimers (as part d) mentions), that is, two sets of Hbonding to one other molecule, so their H-bonds are stronger than the hydrogen bonding in water. Withing the LDF categories, the species with the more open / straight chain structure and the more ...
Chem 30B Spring 2004 QUIZ #1 KEY Weds April 14th / 30
Chem 30B Spring 2004 QUIZ #1 KEY Weds April 14th / 30

... BONUS QUESTION: What is the product of the Pinacol rearrangement shown below? Write your answer (just the structure) clearly in the box provided on the cover sheet to this quiz. There will be NO partial credit – either your structure is right or wrong. The next blank page can be used for working thr ...
Study guide - cloudfront.net
Study guide - cloudfront.net

... 4.1 Identify the structural isomers, geometric isomers, and enantiomers from the following compounds. Which of the geometric isomers is the cis isomer? Ethanol and dimethyl ether, structural isomers, have the same number and kinds of atoms but a different boding sequence and very different propertie ...
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... Acid & base combine to form salt & water, double replacement reaction Explain a combustion reaction. A reaction in which a substance reacts rapidly with oxygen, often produces heat & light, *Products are always carbon ...
Examples of Reactions with Grignard Reagents
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... Examples of Reactions with Grignard Reagents ...
Chapter 11
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Organic Chemistry
Organic Chemistry

Naming Organic Compounds
Naming Organic Compounds

... 2. If the alkyl substituent is large and/or complex, the ring may be named as a substituent group on an alkane. 3. If two different substituents are present on the ring, they are listed in alphabetical order, and the first cited substituent is assigned to carbon #1. The numbering of ring carbons the ...
organic chemistry i
organic chemistry i

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Asymmetric catalytic routes to chiral building blocks of
Asymmetric catalytic routes to chiral building blocks of

... large number of novel amino acids. In terms of efficiency, however, our asymmetric hydrogenation process requires that individual enamides must be prepared for each new a-amino acid desired. In the design and optimization of peptide and peptidomimetic therapeutics, countless variations of a particul ...
Chemical Reactions
Chemical Reactions

... There are many kinds of chemical reactions and several ways to classify them. One useful method of classifies reactions into four major types. These are: 1.) synthesis; 2.) decomposition; 3.) single replacement; and 4.) double replacement reactions. Not all reactions can be put into one of these cat ...
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Asymmetric induction



Asymmetric induction (also enantioinduction) in stereochemistry describes the preferential formation in a chemical reaction of one enantiomer or diastereoisomer over the other as a result of the influence of a chiral feature present in the substrate, reagent, catalyst or environment. Asymmetric induction is a key element in asymmetric synthesis.Asymmetric induction was introduced by Hermann Emil Fischer based on his work on carbohydrates. Several types of induction exist.Internal asymmetric induction makes use of a chiral center bound to the reactive center through a covalent bond and remains so during the reaction. The starting material is often derived from chiral pool synthesis. In relayed asymmetric induction the chiral information is introduced in a separate step and removed again in a separate chemical reaction. Special synthons are called chiral auxiliaries. In external asymmetric induction chiral information is introduced in the transition state through a catalyst of chiral ligand. This method of asymmetric synthesis is economically most desirable.
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