Powerpoint: Reaction pathways
... It may be surprising that water needs such vigorous conditions to react with ethene. It is a highly polar molecule and you would expect it to be a good electrophile. ...
... It may be surprising that water needs such vigorous conditions to react with ethene. It is a highly polar molecule and you would expect it to be a good electrophile. ...
File
... Know which elements are transition metals and therefore require the charge in parenthesis when being named. [ex. Sn (II) or Co (III) ] Know the charges of Ag+1, Zn+2, Cd+2, Al+3, and Ga+3 (exceptions to the transition area) Know how to use the Activity Series of Metals and Halogens for single replac ...
... Know which elements are transition metals and therefore require the charge in parenthesis when being named. [ex. Sn (II) or Co (III) ] Know the charges of Ag+1, Zn+2, Cd+2, Al+3, and Ga+3 (exceptions to the transition area) Know how to use the Activity Series of Metals and Halogens for single replac ...
Stereochemistry and Stereoisomers Revisited
... two nonidentical substituents, the resulting molecule is symmetrical (Figure D.1). In other words, a plane of symmetry can be drawn through this molecule. Furthermore, this molecule is superimposable on its mirror image. (Prove this to yourself by building the molecules with molecular models or toot ...
... two nonidentical substituents, the resulting molecule is symmetrical (Figure D.1). In other words, a plane of symmetry can be drawn through this molecule. Furthermore, this molecule is superimposable on its mirror image. (Prove this to yourself by building the molecules with molecular models or toot ...
Organic Reactions
... deficit of electrons b/c atom is attached to very electronegative atom carbon of carbonyl group acids ...
... deficit of electrons b/c atom is attached to very electronegative atom carbon of carbonyl group acids ...
Example - cloudfront.net
... a) Balance elements that appear in more than one compound __________ (NH4)2CO3 NH3 + CO2 + H2O b) Balance __________________ as though they are one item as long as the ion stays together as a group on each side of the arrow. Al + CuSO4 Al2(SO4)3 + Cu c) If you can’t seem to get it balanced, ____ ...
... a) Balance elements that appear in more than one compound __________ (NH4)2CO3 NH3 + CO2 + H2O b) Balance __________________ as though they are one item as long as the ion stays together as a group on each side of the arrow. Al + CuSO4 Al2(SO4)3 + Cu c) If you can’t seem to get it balanced, ____ ...
isomerism
... Synthesis of 2-hydroxypropanoic acid (lactic acid) LACTIC ACID can be formed from ethanal in a two stage process. 1. Nucleophilic addition of hydrogen cyanide to ethanal 2 Hydrolysis of the nitrile group ...
... Synthesis of 2-hydroxypropanoic acid (lactic acid) LACTIC ACID can be formed from ethanal in a two stage process. 1. Nucleophilic addition of hydrogen cyanide to ethanal 2 Hydrolysis of the nitrile group ...
General properties of urea : It is water
... Urea is identified by the test known as biuret test. The biuret residue is dissolved in water and made alkaline with a few drops of NaOH. When a part of copper sulphate solution is added to the alkaline solution of biuret, a violet colouration is ...
... Urea is identified by the test known as biuret test. The biuret residue is dissolved in water and made alkaline with a few drops of NaOH. When a part of copper sulphate solution is added to the alkaline solution of biuret, a violet colouration is ...
Novel amine-catalysed hydroalkoxylation reactions of
... DMAP12 gave smooth conversion to acetal 24, which was isolated in high yield after chromatography (Scheme 3). To our knowledge this is the first example of a nucleophile-promoted dihydroalkoxylation reaction to be reported.13 In summary, it has been found that tertiary nucleophilic amines such as DB ...
... DMAP12 gave smooth conversion to acetal 24, which was isolated in high yield after chromatography (Scheme 3). To our knowledge this is the first example of a nucleophile-promoted dihydroalkoxylation reaction to be reported.13 In summary, it has been found that tertiary nucleophilic amines such as DB ...
Review of Thermodynamics
... ingredients that when combined create a menu that we observe as molecular recognition properties of molecules. Bringing two or more molecules together results in preferences for particular orientations that can lead to particular reactivity or expressed properties. These resultant structures are hig ...
... ingredients that when combined create a menu that we observe as molecular recognition properties of molecules. Bringing two or more molecules together results in preferences for particular orientations that can lead to particular reactivity or expressed properties. These resultant structures are hig ...
Example - Request a Spot account
... 1. Catalysts are substances that speed up chemical reactions a. Allow reactions to occur that might not otherwise take place (due to low temperature for example) b. Lower activation energy for a chemical reaction 2. Participation of catalysts in a chemical reaction a. They may undergo a chemical cha ...
... 1. Catalysts are substances that speed up chemical reactions a. Allow reactions to occur that might not otherwise take place (due to low temperature for example) b. Lower activation energy for a chemical reaction 2. Participation of catalysts in a chemical reaction a. They may undergo a chemical cha ...
IR Lecture
... n = wavenumbers. Larger n = higher energy Excitation depends on atomic mass and how tightly they are bound a) Hooke’s Law for 2 masses connected by a spring ...
... n = wavenumbers. Larger n = higher energy Excitation depends on atomic mass and how tightly they are bound a) Hooke’s Law for 2 masses connected by a spring ...
Organic and Biological Molecules
... compounds, but, since the silicon oxygen bond is much stronger than that between two silicon atoms, the chains typically contain –O-Si-O-Sitype links, rather than -Si-Si- bonds. Silicon also has empty low-lying d orbitals which make its compounds more reactive. ...
... compounds, but, since the silicon oxygen bond is much stronger than that between two silicon atoms, the chains typically contain –O-Si-O-Sitype links, rather than -Si-Si- bonds. Silicon also has empty low-lying d orbitals which make its compounds more reactive. ...
Name Class Date 23.4 Polymers Organic compounds can bond
... Addition Polymers An addition polymer forms when unsaturated monomers covalently bond to form a long chain. The physical properties of polymers change with the length of the carbon chain. Polymers of ethylene, propylene, styrene, and others have many industrial uses. Addition polymers are widely use ...
... Addition Polymers An addition polymer forms when unsaturated monomers covalently bond to form a long chain. The physical properties of polymers change with the length of the carbon chain. Polymers of ethylene, propylene, styrene, and others have many industrial uses. Addition polymers are widely use ...
Ch17-2 Driving Forces of Reactions
... Increase in entropy + S …..more crazy random (favored) delta ...
... Increase in entropy + S …..more crazy random (favored) delta ...
Week # 6 Homework doc
... 1. The alcohol oxygen becomes bonded to the carbonyl carbon to form the ether. 2. The carbon double bond oxygen electrons are used to bond the alcohol hydrogen to the carbonyl oxygen 3. The alcohol oxygen-hydrogen bond is broken The whole process can be remembered by saying: The aldehyde or ketone o ...
... 1. The alcohol oxygen becomes bonded to the carbonyl carbon to form the ether. 2. The carbon double bond oxygen electrons are used to bond the alcohol hydrogen to the carbonyl oxygen 3. The alcohol oxygen-hydrogen bond is broken The whole process can be remembered by saying: The aldehyde or ketone o ...
Name
... a. Theoretical yield b. Percentage yield c. Mole ratio d. Actual yield 14. For the reaction Cl2 + 2KBr → 2KCl +Br2, calculate the percentage yield if 200g of chlorine react with excess potassium bromide to produce 410g of bromine. a. 73.4% b. 82.1% c. 91.0% d. 98.9% 15. For the reaction Mg + 2HCl → ...
... a. Theoretical yield b. Percentage yield c. Mole ratio d. Actual yield 14. For the reaction Cl2 + 2KBr → 2KCl +Br2, calculate the percentage yield if 200g of chlorine react with excess potassium bromide to produce 410g of bromine. a. 73.4% b. 82.1% c. 91.0% d. 98.9% 15. For the reaction Mg + 2HCl → ...
ch 1: organic chemistry
... both undergo a characteristic reaction called an addition reaction, where atoms are added to the molecule with no loss of H atoms addition reactions can involve halogens, H, hydrogen halides,and water, given the right conditions Examples: ...
... both undergo a characteristic reaction called an addition reaction, where atoms are added to the molecule with no loss of H atoms addition reactions can involve halogens, H, hydrogen halides,and water, given the right conditions Examples: ...
Test 2
... 11. Write a molecular equation (balanced, phases) for the reaction described: Lead(II) nitrate solution and sodium sulfate solution are mixed. A precipitate of lead(II) sulfate ...
... 11. Write a molecular equation (balanced, phases) for the reaction described: Lead(II) nitrate solution and sodium sulfate solution are mixed. A precipitate of lead(II) sulfate ...
Asymmetric induction
Asymmetric induction (also enantioinduction) in stereochemistry describes the preferential formation in a chemical reaction of one enantiomer or diastereoisomer over the other as a result of the influence of a chiral feature present in the substrate, reagent, catalyst or environment. Asymmetric induction is a key element in asymmetric synthesis.Asymmetric induction was introduced by Hermann Emil Fischer based on his work on carbohydrates. Several types of induction exist.Internal asymmetric induction makes use of a chiral center bound to the reactive center through a covalent bond and remains so during the reaction. The starting material is often derived from chiral pool synthesis. In relayed asymmetric induction the chiral information is introduced in a separate step and removed again in a separate chemical reaction. Special synthons are called chiral auxiliaries. In external asymmetric induction chiral information is introduced in the transition state through a catalyst of chiral ligand. This method of asymmetric synthesis is economically most desirable.