Outline_CH13_Klein
... inversion of configuration incomplete iii. SN2 reaction With phosphorus trihalides PBr3 or PCl3 or PCl5 or P° and I2 to form alkyl halides o Mechanism/ no rearrangement/ inversion of configuration e. Alkyl tosylates (sulfonate esters) by reaction of ROH with sulfonyl chlorides i. Mechanism/ retentio ...
... inversion of configuration incomplete iii. SN2 reaction With phosphorus trihalides PBr3 or PCl3 or PCl5 or P° and I2 to form alkyl halides o Mechanism/ no rearrangement/ inversion of configuration e. Alkyl tosylates (sulfonate esters) by reaction of ROH with sulfonyl chlorides i. Mechanism/ retentio ...
Chapter 11 - Alcohols and Ethers1
... 11.1 - Structure and Nomenclature - The common naming calls alcohols as alkyl alcohols (eg: methyl alcohol) - The common names of ethers have the groups attached to the oxygen atom listed in alphabetical order followed by the word ether (eg: Ethly methyl ether) - The ...
... 11.1 - Structure and Nomenclature - The common naming calls alcohols as alkyl alcohols (eg: methyl alcohol) - The common names of ethers have the groups attached to the oxygen atom listed in alphabetical order followed by the word ether (eg: Ethly methyl ether) - The ...
Naming Hydrocarbons and Substituted Hydrocarbons
... 3. Which is an isomer of 2,2-dimethylpropane? (1) ethane (3) n-pentane (2) propane (4) n-butane ...
... 3. Which is an isomer of 2,2-dimethylpropane? (1) ethane (3) n-pentane (2) propane (4) n-butane ...
10.4 Alcohols 10.4 Alcohols
... 10.4.3 Determine the products formed by the oxidation of primary and secondary alcohols. ...
... 10.4.3 Determine the products formed by the oxidation of primary and secondary alcohols. ...
Glossary of Key Terms in Chapter Two
... disulfide (12.9) an organic compound that contains the disulfide group (-S-S-). elimination reaction (12.5) a reaction in which a molecule loses atoms or ions from its structure. ether (12.8) an organic compound that contains two alkyl and/or aryl groups attached to an oxygen atom; R-O-R, Ar-O-R, an ...
... disulfide (12.9) an organic compound that contains the disulfide group (-S-S-). elimination reaction (12.5) a reaction in which a molecule loses atoms or ions from its structure. ether (12.8) an organic compound that contains two alkyl and/or aryl groups attached to an oxygen atom; R-O-R, Ar-O-R, an ...
Enantiodivergent conversion of chiral secondary alcohols into
... •Summary (comparison to other methods) ...
... •Summary (comparison to other methods) ...
Zumd22
... – This class is called “aromatic” (by virtue of their aroma). – The structure is often preserved in their chemical reactions; they don’t add, they substitute instead. ...
... – This class is called “aromatic” (by virtue of their aroma). – The structure is often preserved in their chemical reactions; they don’t add, they substitute instead. ...
alcohol
... Nomenclature of Alcohols In the IUPAC system, the hydroxyl group in alcohols is indicated by the ending –ol. In common names, the separate word alcohol is placed after the name of the alkyl group. ...
... Nomenclature of Alcohols In the IUPAC system, the hydroxyl group in alcohols is indicated by the ending –ol. In common names, the separate word alcohol is placed after the name of the alkyl group. ...
Lect 9 Alcohols
... • Take the name of the corresponding alkyl group and add the word "alcohol", e.g. methyl alcohol, ethyl alcohol or tert-butyl alcohol. • Propyl alcohol may be n-propyl alcohol or isopropyl alcohol depending on whether the hydroxyl group is bonded to the 1st or 2nd carbon on the propane chain. • Isop ...
... • Take the name of the corresponding alkyl group and add the word "alcohol", e.g. methyl alcohol, ethyl alcohol or tert-butyl alcohol. • Propyl alcohol may be n-propyl alcohol or isopropyl alcohol depending on whether the hydroxyl group is bonded to the 1st or 2nd carbon on the propane chain. • Isop ...
Document
... 15.4: Preparation of Alcohols From Epoxides - the threemembered ring of an epoxide is strained. Epoxides undergo ringopening reaction with nucleophiles (Grignard reagents, organolithium reagents, and cuprates). ...
... 15.4: Preparation of Alcohols From Epoxides - the threemembered ring of an epoxide is strained. Epoxides undergo ringopening reaction with nucleophiles (Grignard reagents, organolithium reagents, and cuprates). ...
Alcohols
... attached to the same carbon as -OH • Distinguished by Lucas reagent (ZnCl2 in conc HCl) – no visible reaction: primary alcohol – solution turns cloudy in 3-5 minutes: secondary alcohol – solution turns cloudy immediately, and/or phases separate: tertiary or benzyl alcohol ...
... attached to the same carbon as -OH • Distinguished by Lucas reagent (ZnCl2 in conc HCl) – no visible reaction: primary alcohol – solution turns cloudy in 3-5 minutes: secondary alcohol – solution turns cloudy immediately, and/or phases separate: tertiary or benzyl alcohol ...
L2 - Alcohols and Phenols
... Naming Alcohols, cont. Alkyl Nomenclature: Short chained alcohols are commonly named as alkyl substituents on a hydroxyl parent chain. •To name alcohols according to alkyl nomenclature, treat the –OH group as the parent chain and name the alkyl substituent followed by the word alcohol. OH ...
... Naming Alcohols, cont. Alkyl Nomenclature: Short chained alcohols are commonly named as alkyl substituents on a hydroxyl parent chain. •To name alcohols according to alkyl nomenclature, treat the –OH group as the parent chain and name the alkyl substituent followed by the word alcohol. OH ...
Chapter 13 Alcohols, Phenols, and Ethers
... • Step 1: Name the longest chain to which the –OH group is attached. Use the hydrocarbon name of the chain, drop the final –e, and replace it with –ol. • Step 2: Number the longest chain to give the lowest number to the carbon with the attached –OH. • Step 3: Locate the –OH position. ...
... • Step 1: Name the longest chain to which the –OH group is attached. Use the hydrocarbon name of the chain, drop the final –e, and replace it with –ol. • Step 2: Number the longest chain to give the lowest number to the carbon with the attached –OH. • Step 3: Locate the –OH position. ...
aldehyde ketone
... CH3-CH2-OH CH3-CHO + 2H+ + 2e CH3-CHO + H2O CH3COOH + 2H+ + 2e reduction; Cr2O72-(aq) + 14H+(aq) + 6e- 2Cr3+ (aq) +7H2O orange ...
... CH3-CH2-OH CH3-CHO + 2H+ + 2e CH3-CHO + H2O CH3COOH + 2H+ + 2e reduction; Cr2O72-(aq) + 14H+(aq) + 6e- 2Cr3+ (aq) +7H2O orange ...
Ethanol as a solvent
... the carbon the –OH group is attached to joins one other carbon (i.e. on the end of a carbon chain) the carbon the –OH group is attached to joins two other carbons (i.e. in the middle of a carbon chain) the carbon the –OH group is attached to joins three other carbons (i.e. in the middle of a carbon ...
... the carbon the –OH group is attached to joins one other carbon (i.e. on the end of a carbon chain) the carbon the –OH group is attached to joins two other carbons (i.e. in the middle of a carbon chain) the carbon the –OH group is attached to joins three other carbons (i.e. in the middle of a carbon ...
Colorful Oxidation of Alcohol
... Source: Summerlin, L. R., Borgford, C. L., and Ealy, J. B. (1987) Chemical Demonstrations: A Source Book for Teachers Volume 2. p. 210. Description: When a yellow solution, K2CrO7, is added to three different alcohols, the solution turns blue in two of the alcohols and remains yellow in one. Concept ...
... Source: Summerlin, L. R., Borgford, C. L., and Ealy, J. B. (1987) Chemical Demonstrations: A Source Book for Teachers Volume 2. p. 210. Description: When a yellow solution, K2CrO7, is added to three different alcohols, the solution turns blue in two of the alcohols and remains yellow in one. Concept ...
Test 12
... Functional Groups (identify, name and draw) Halides Alcohols Mono, di, tri-hydroxy alcohols Primary, Secondary and Tertiary Alcohols Identify glycerol and ethylene glycol Organic Acids – (electrolyte!) Esters Aldehydes Ketones Ethers Amines and Amides Identify an Amino Acid (has amine group and acid ...
... Functional Groups (identify, name and draw) Halides Alcohols Mono, di, tri-hydroxy alcohols Primary, Secondary and Tertiary Alcohols Identify glycerol and ethylene glycol Organic Acids – (electrolyte!) Esters Aldehydes Ketones Ethers Amines and Amides Identify an Amino Acid (has amine group and acid ...
Ch.14
... RX RSH • All of these compounds contain a carbon atom that is singly bonded to a heteroatom (other than H or C)! • Alcohols & ethers can be considered organic derivatives of water • Replacing H(s) with one or two alkyl groups • HOH; ROH; ROR ...
... RX RSH • All of these compounds contain a carbon atom that is singly bonded to a heteroatom (other than H or C)! • Alcohols & ethers can be considered organic derivatives of water • Replacing H(s) with one or two alkyl groups • HOH; ROH; ROR ...
15_01_05.html
... end uses: solvent, antifreeze, fuel principal use: preparation of formaldehyde prepared by hydrogenation of carbon monoxide CO + 2H2 CH3OH ...
... end uses: solvent, antifreeze, fuel principal use: preparation of formaldehyde prepared by hydrogenation of carbon monoxide CO + 2H2 CH3OH ...
Alcohol
In chemistry, an alcohol is any organic compound in which the hydroxyl functional group (–OH) is bound to a saturated carbon atom. The term alcohol originally referred to the primary alcohol ethyl alcohol (ethanol), the predominant alcohol in alcoholic beverages.The suffix -ol appears in the IUPAC chemical name of all substances where the hydroxyl group is the functional group with the highest priority; in substances where a higher priority group is present the prefix hydroxy- will appear in the IUPAC name. The suffix -ol in non-systematic names (such as paracetamol or cholesterol) also typically indicates that the substance includes a hydroxyl functional group and, so, can be termed an alcohol. But many substances, particularly sugars (examples glucose and sucrose) contain hydroxyl functional groups without using the suffix. An important class of alcohols, of which methanol and ethanol are the simplest members is the saturated straight chain alcohols, the general formula for which is CnH2n+1OH.