AP Chemistry: Chapter 13 Gaseous Equilibrium Section 1: Multiple
... of the gases at equilibrium without the catalyst? Justify your answer. (Assume that the volume of the solid catalyst is negligible.) In another experiment involving the same reaction, a rigid 2.00 L container initially contains 10.0 g of C(s), plus CO(g) and CO2(g), each at a partial pressure of 2.0 ...
... of the gases at equilibrium without the catalyst? Justify your answer. (Assume that the volume of the solid catalyst is negligible.) In another experiment involving the same reaction, a rigid 2.00 L container initially contains 10.0 g of C(s), plus CO(g) and CO2(g), each at a partial pressure of 2.0 ...
ALCOHOLS AND ETHERS
... and benzylic halides (Sections 14-3B and 14-3C), addition of Grignard reagents to carbonyl compounds (Section 14-12), and the reduction of carbonyl compounds (Sections 16-4E and 16-5). These methods are summarized in Table 15-2. Some of the reactions we have mentioned are used for large-scale indust ...
... and benzylic halides (Sections 14-3B and 14-3C), addition of Grignard reagents to carbonyl compounds (Section 14-12), and the reduction of carbonyl compounds (Sections 16-4E and 16-5). These methods are summarized in Table 15-2. Some of the reactions we have mentioned are used for large-scale indust ...
INTERPRETATION OF INFRARED SPECTRA Hydrocarbons
... It should be pointed out that the C=O absorption ranges for the various carbonylcontaining functional groups overlap significantly, so it is difficult to make a definitive identification of the functional group based solely on the position of the carbonyl peak. However, most of these functional grou ...
... It should be pointed out that the C=O absorption ranges for the various carbonylcontaining functional groups overlap significantly, so it is difficult to make a definitive identification of the functional group based solely on the position of the carbonyl peak. However, most of these functional grou ...
Chapter 23 Metals and Metallurgy
... metal cation. • Electrons on the ligands repel electrons in the unhybridized d orbitals of the metal ion. • The result is the energies of the d orbitals are split. • The difference in energy depends on the complex formed and the kinds of ligands. ...
... metal cation. • Electrons on the ligands repel electrons in the unhybridized d orbitals of the metal ion. • The result is the energies of the d orbitals are split. • The difference in energy depends on the complex formed and the kinds of ligands. ...
Drawing Organic Structures Functional Groups
... Naming Alcohols • Multiple hydroxyl groups • Two –OH groups is a diol; 3 is a triol • Two adjacent –OH groups is a glycol • Name as acyclic alcohols, except keep the “-e” suffix and add “-diol” • Indicate numbers for all –OH groups • Unsaturated alcohols (enol or ynol) 1. Parent chain contains carb ...
... Naming Alcohols • Multiple hydroxyl groups • Two –OH groups is a diol; 3 is a triol • Two adjacent –OH groups is a glycol • Name as acyclic alcohols, except keep the “-e” suffix and add “-diol” • Indicate numbers for all –OH groups • Unsaturated alcohols (enol or ynol) 1. Parent chain contains carb ...
The alcohols
... selected topics at AS and A2 level Chemistry. It is based on the requirements of the AQA and OCR specifications but is suitable for other examination boards. Individual students may use the material at home for revision purposes or it may be used for classroom teaching if an interactive white board ...
... selected topics at AS and A2 level Chemistry. It is based on the requirements of the AQA and OCR specifications but is suitable for other examination boards. Individual students may use the material at home for revision purposes or it may be used for classroom teaching if an interactive white board ...
Final Study Guide (Semester 2) Answer Key
... Which compounds above are strong electrolytes? CuSO4 , KOH , K2SO4 a. Which chemical above is not soluble in water? Cu(OH)2 c. Which chemical above is the precipitate? Cu(OH)2 2. Solutions of Barium nitrate and potassium sulfate are mixed. ***The first thing you should do when solving this is look a ...
... Which compounds above are strong electrolytes? CuSO4 , KOH , K2SO4 a. Which chemical above is not soluble in water? Cu(OH)2 c. Which chemical above is the precipitate? Cu(OH)2 2. Solutions of Barium nitrate and potassium sulfate are mixed. ***The first thing you should do when solving this is look a ...
No Slide Title
... selected topics at AS and A2 level Chemistry. It is based on the requirements of the AQA and OCR specifications but is suitable for other examination boards. Individual students may use the material at home for revision purposes or it may be used for classroom teaching if an interactive white board ...
... selected topics at AS and A2 level Chemistry. It is based on the requirements of the AQA and OCR specifications but is suitable for other examination boards. Individual students may use the material at home for revision purposes or it may be used for classroom teaching if an interactive white board ...
ORGANIC CONVERSION---(2 to 3 marks)
... (b) Hydration of propene in the presence of dilute sulphuric acid. (c) Reaction of propanone with methylmagnesium bromide followed by hydrolysis. # Give equations of the following reactions: (i) Oxidation of propan-1-ol with alkaline KMnO4 solution. (ii) Bromine in CS2 with phenol. (iii) Dilute HNO ...
... (b) Hydration of propene in the presence of dilute sulphuric acid. (c) Reaction of propanone with methylmagnesium bromide followed by hydrolysis. # Give equations of the following reactions: (i) Oxidation of propan-1-ol with alkaline KMnO4 solution. (ii) Bromine in CS2 with phenol. (iii) Dilute HNO ...
Coordination Chemistry
... [Co(NH3)6]Cl3 [Co(NH3)5Cl]Cl2 [Co(NH3)4Cl2]Cl [Co(NH3)4Cl2]Cl primary valence (formal oxidation state) ...
... [Co(NH3)6]Cl3 [Co(NH3)5Cl]Cl2 [Co(NH3)4Cl2]Cl [Co(NH3)4Cl2]Cl primary valence (formal oxidation state) ...
Stoichiometry - HCC Learning Web
... Since the moles of FeCl3 based on moles of Cl2 is the smaller answer, Cl2 is the limiting reactant. Iron metal is therefore in excess amount, so there will be some Fe left over unreacted. Note that we might have reasonably assumed that iron metal was the limiting reactant since it was present in les ...
... Since the moles of FeCl3 based on moles of Cl2 is the smaller answer, Cl2 is the limiting reactant. Iron metal is therefore in excess amount, so there will be some Fe left over unreacted. Note that we might have reasonably assumed that iron metal was the limiting reactant since it was present in les ...
Document
... LESS THAN FOUR attachments. – Alkenes and alkynes are unsaturated. – They contain at least one double or triple bond, respectively. – They have fewer hydrogen atoms per carbon atom than alkanes. © 2013 Pearson Education, Inc. ...
... LESS THAN FOUR attachments. – Alkenes and alkynes are unsaturated. – They contain at least one double or triple bond, respectively. – They have fewer hydrogen atoms per carbon atom than alkanes. © 2013 Pearson Education, Inc. ...
What Are the Mechanisms of Catalysis?
... (left) HIV-1 protease complexed with the inhibitor Crixivan (red) made by Merck. The flaps (residues 46-55 from each subunit) covering the active site are shown in green and the active site aspartate residues involved in catalysis are shown in white. (right) The close-up of the active site shows the ...
... (left) HIV-1 protease complexed with the inhibitor Crixivan (red) made by Merck. The flaps (residues 46-55 from each subunit) covering the active site are shown in green and the active site aspartate residues involved in catalysis are shown in white. (right) The close-up of the active site shows the ...
Development of New Synthetic Routes to Organoboronates by Catalytic Allylic Substitution and
... on allylboronic acid derivatives. Thus, palladium pincer-complex catalysis has been applied for extending the scope of palladiumcatalyzed borylation reactions in the synthesis of regio- and stereodefined functionalized allylboronic acid derivatives. These novel allylboronic acids were also employed ...
... on allylboronic acid derivatives. Thus, palladium pincer-complex catalysis has been applied for extending the scope of palladiumcatalyzed borylation reactions in the synthesis of regio- and stereodefined functionalized allylboronic acid derivatives. These novel allylboronic acids were also employed ...
Document
... • PCC is soluble in CH2Cl2 (dichloromethane) and can be used without strong acid present, making it a more selective, milder oxidant. ...
... • PCC is soluble in CH2Cl2 (dichloromethane) and can be used without strong acid present, making it a more selective, milder oxidant. ...
Substitution in Square Planar Metal Complexes
... Metal effects on square planar substitution: • almost all examples of square planar geometry are d8 electron counts so electron counts are not a factor • however, ∆CFSE going from SqP to TBP geometry is still unfavourable by -0.242∆oct so this adds to the barrier for square planar substitution and ...
... Metal effects on square planar substitution: • almost all examples of square planar geometry are d8 electron counts so electron counts are not a factor • however, ∆CFSE going from SqP to TBP geometry is still unfavourable by -0.242∆oct so this adds to the barrier for square planar substitution and ...
Journal of Molecular Catalysis A: Chemical Enhancing
... of disubstituted product. Immiscibility of ionic liquid with different organic solvents, and their tendency to form biphasic media, could offer an excellent solution for this specific task. Keeping in mind good yields of monotetrahydropyranyl ethers obtained in our previous work [9], we decided to pe ...
... of disubstituted product. Immiscibility of ionic liquid with different organic solvents, and their tendency to form biphasic media, could offer an excellent solution for this specific task. Keeping in mind good yields of monotetrahydropyranyl ethers obtained in our previous work [9], we decided to pe ...
Substitution Reactions
... the chloride ion Cl-. It has four electron pairs, but only one of these will form a coordinate bond with a metal. The usual reagent used as a source of chloride ions is concentrated hydrochloric acid; because of its great solubility (conc. HCl is approximately 11M) it produces a much higher concentr ...
... the chloride ion Cl-. It has four electron pairs, but only one of these will form a coordinate bond with a metal. The usual reagent used as a source of chloride ions is concentrated hydrochloric acid; because of its great solubility (conc. HCl is approximately 11M) it produces a much higher concentr ...
Hydroformylation
Hydroformylation, also known as oxo synthesis or oxo process, is an important homogeneously catalyzed industrial process for the production of aldehydes from alkenes. This chemical reaction entails the addition of a formyl group (CHO) and a hydrogen atom to a carbon-carbon double bond. This process has undergone continuous growth since its invention in 1938: Production capacity reached 6.6×106 tons in 1995. It is important because the resulting aldehydes are easily converted into many secondary products. For example, the resulting aldehydes are hydrogenated to alcohols that are converted to plasticizers or detergents. Hydroformylation is also used in specialty chemicals, relevant to the organic synthesis of fragrances and natural products. The development of hydroformylation, which originated within the German coal-based industry, is considered one of the premier achievements of 20th-century industrial chemistry.The process typically entails treatment of an alkene with high pressures (between 10 to 100 atmospheres) of carbon monoxide and hydrogen at temperatures between 40 and 200 °C. Transition metal catalysts are required.