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File - Pedersen Science
File - Pedersen Science

... 1. Explain how carbon’s electron configuration explains its ability to form large, complex, diverse organic molecules 2. Describe how carbon skeletons may vary and explain how this variation contributes to the diversity and complexity of organic molecules 3. Distinguish among the three types of isom ...
Chapter 4
Chapter 4

... 1. Explain how carbon’s electron configuration explains its ability to form large, complex, diverse organic molecules 2. Describe how carbon skeletons may vary and explain how this variation contributes to the diversity and complexity of organic molecules 3. Distinguish among the three types of isom ...
Functional Groups
Functional Groups

... formula C3H6O2 • Solution: the only way the carbon atoms can be written is three in a chain; the -COOH group must be on an end carbon of the chain O CH3 CH2 COH or CH3 CH2 COOH ...
Lecture_Syllabus_Gillies - Kingsborough Community College
Lecture_Syllabus_Gillies - Kingsborough Community College

... The danger of electrocution is related to the electric current flow, not voltage. Even a relatively low current 0.01- 0.2 amps can result in ventricular fibrillation. ...
CH - cloudfront.net
CH - cloudfront.net

...  Plastics are probably the best known of this group of synthetic polymers.  They can be molded and hardened for many different purposes. ...
cleavage of methyl ethers with iodotrimethylsilane
cleavage of methyl ethers with iodotrimethylsilane

... septum. With oven-dried syringes, 4 ml. of chloroform (Note 8), 0.5 g. (0.5 ml., 0.006 mole) of pyridine (Note 8) and (Note 9), and 4.8 g. (3.5 ml., 0.024 mole) of freshly prepared iodotrimethylsilane are injected into the flask in the order specified. When the iodotrimethylsilane is added, the solu ...
Formic acid oxidation reaction on a PdxNiy bimetallic nanoparticle
Formic acid oxidation reaction on a PdxNiy bimetallic nanoparticle

... unique ability to catalyze the oxidation of formic acid in fuel cells in 1987 [5]. Recently, many methods to synthesize Pd NPs have been reported. For example, Wang et al. [6] reported a facile method to synthesize Pd NPs supported on graphene ribbon (GR), in which Na2PdCl4 was employed as the precu ...
Molecules with Nitrogen and Their Reactions
Molecules with Nitrogen and Their Reactions

... 3. tertiary amides: name the two carbon chain on the N atom as branches, and use N- to identify the location for each branch branch = N-methyl ...
here - Department of Chemistry, UWI, Mona
here - Department of Chemistry, UWI, Mona

... Rate = (k1 + k2[Y])[ML3X] Indicate two parallel reaction paths. In the presence of a large excess of the entering ligand [Y] remains constant throughout the reaction Rate = -d[ML3X]/dt = kobs.[ML3X] where kobs. =k1 +k2[Y] A plot of kobs. versus [Y], Straight line with k1 = intercept and k2 is the nu ...
Organics – Naming the Molecules
Organics – Naming the Molecules

... Naming and alcohol is very similar to naming alkenes and alkynes. This is because the location of the –OH group on the chain is very important In this case we number the carbon (from the closest end) and locate which carbon the –OH is on. For example, ‘propan-1-ol’ means that the –OH is on the first ...
Role of Chemical Reaction Engineering in Sustainable
Role of Chemical Reaction Engineering in Sustainable

... In this way, n-butane and oxygen are not in direct contact and this leads to minimizing side reactions and higher maleic anhydride selectivity (up to 90 %) is therefore obtained4,6. Figure 4 shows the circulating fluid bed reactor configuration. Again, to enable the use of CFB extensive catalyst dev ...
Computational Docking Experiments to Find a Ligand that Will Bind
Computational Docking Experiments to Find a Ligand that Will Bind

... This project was to seek a uric acid derivative compound that will be able to bind XOD with high affinity, which could possibly be used as an inhibitor to the XOD activity. A computer was used to design several compounds and the program Autodock Vina was used to perform docking of those compounds to ...
Nickel(II)-induced activation of a carbon–nitrogen
Nickel(II)-induced activation of a carbon–nitrogen

IJCA 49A(2) 171-175
IJCA 49A(2) 171-175

... RC6H4NH2 ligand illustrate a simple molecular fabrication technique, which can be suitably integrated into a system, to have some control on the behavior of metal complexes. A modified ferromagnetic character due to charge build up on the metal centre by ligating nitrogen atom, which in turn makes t ...
Alcohols and phenols - Home - KSU Faculty Member websites
Alcohols and phenols - Home - KSU Faculty Member websites

... The boiling points increase with increase in molecular weights. OH ...
π bonded ligands (# 2)
π bonded ligands (# 2)

... The extent of orbital overlap between 2 and the dxy orbital on the metal is  improved if the allyl group moves in this way. ...
materials required/recommended for this paper
materials required/recommended for this paper

... The phosphoric acid fuel cell (PAFC) uses gaseous oxygen and hydrogen to produce electricity. The cell is named so, because the electrolyte is an extremely concentrated solution of phosphoric acid. Both electrodes are made from porous carbon, which is coated with a platinum catalyst. The cell operat ...
Pseudoasymmetry as a Means for Distinguishing Meso
Pseudoasymmetry as a Means for Distinguishing Meso

Green Polymer Chemistry: Enzyme Catalysis for Polymer
Green Polymer Chemistry: Enzyme Catalysis for Polymer

Influence of the benzyl-substitution in porphyrin macrocycles on its
Influence of the benzyl-substitution in porphyrin macrocycles on its

Grignard-syn-12-ques
Grignard-syn-12-ques

... A Grignard reagent, RMgX, is a very strong base and a good nucleophile; water/moisture MUST be avoided in its reaction. ...
In the bachelor thesis of Esther Schippers, research is
In the bachelor thesis of Esther Schippers, research is

... To mimic discontinuous active sites, the peptides are coupled to scaffold. Binding these two scaffolds should result in an active site mimic. These scaffolds should meet a few requirements. 1. The peptides are set onto scaffolds via CLIPS-chemistry. To be able to do a CLIPS-reaction, a part of the m ...
Week 1 - School of Chemical Sciences
Week 1 - School of Chemical Sciences

Nomenclature of Carboxylic Acids 1. Parent alkane + the suffix
Nomenclature of Carboxylic Acids 1. Parent alkane + the suffix

Lecture 14 – Square Planar Complexes
Lecture 14 – Square Planar Complexes

< 1 ... 109 110 111 112 113 114 115 116 117 ... 359 >

Hydroformylation



Hydroformylation, also known as oxo synthesis or oxo process, is an important homogeneously catalyzed industrial process for the production of aldehydes from alkenes. This chemical reaction entails the addition of a formyl group (CHO) and a hydrogen atom to a carbon-carbon double bond. This process has undergone continuous growth since its invention in 1938: Production capacity reached 6.6×106 tons in 1995. It is important because the resulting aldehydes are easily converted into many secondary products. For example, the resulting aldehydes are hydrogenated to alcohols that are converted to plasticizers or detergents. Hydroformylation is also used in specialty chemicals, relevant to the organic synthesis of fragrances and natural products. The development of hydroformylation, which originated within the German coal-based industry, is considered one of the premier achievements of 20th-century industrial chemistry.The process typically entails treatment of an alkene with high pressures (between 10 to 100 atmospheres) of carbon monoxide and hydrogen at temperatures between 40 and 200 °C. Transition metal catalysts are required.
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