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Chapter 4 REVIEW
Chapter 4 REVIEW

... 28. Chlorine is a very reactive element that forms stable compounds with most other elements. For each of the following chlorine compounds, draw Lewis and structural diagrams, and then predict the polarity of the molecules: (a) NCl3 (c) PCl5 (b) SiCl4 (d) SCl6 ...
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Investigating Chemistry - Chemistry at Winthrop University
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... a Bunsen burner. Using any combination of these substances and common lab equipment, suggest a procedure below which will produce at least one new compound. Write a reaction to show how the new compound(s) form(s). Also, identify the formula for the new compound. NOTE: There are several acceptable p ...
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Homoaromaticity



Homoaromaticity in organic chemistry refers to a special case of aromaticity in which conjugation is interrupted by a single sp3 hybridized carbon atom. Although this sp3 center disrupts the continuous overlap of p-orbitals, traditionally thought to be a requirement for aromaticity, considerable thermodynamic stability and many of the spectroscopic, magnetic, and chemical properties associated with aromatic compounds are still observed for such compounds. This formal discontinuity is apparently bridged by p-orbital overlap, maintaining a contiguous cycle of π electrons that is responsible for this preserved chemical stability.The concept of homoaromaticity was pioneered by Saul Winstein in 1959, prompted by his studies of the “tris-homocyclopropenyl” cation. Since the publication of Winstein's paper, much research has been devoted to understanding and classifying these molecules, which represent an additional “class” of aromatic molecules included under the continuously broadening definition of aromaticity. To date, homoaromatic compounds are known to exist as cationic and anionic species, and some studies support the existence of neutral homoaromatic molecules, though these are less common. The 'homotropylium' cation (C8H9+) is perhaps the best studied example of a homoaromatic compound.
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