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physics/0010052 PDF
physics/0010052 PDF

... Pay attention that if P=const and A is the work of expansion then dQ and dA=PdV are exact differentials. Let's consider heat exchange, one introduces the quantity of heat ∆Q in the system (∆V=0): ∆Q=∆U. Now let's suppose ∆V>0. Let's find out, is it necessary to write ∆Q=∆U-P∆V or ∆Q=∆U+P∆V. It is ne ...
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... which occurs at constant T, P G = U + PV – TS = H – TS (dH = dU + PdV + VdP) • The total differential is: dG = dU + PdV + VdP – TdS – SdT G is therefore the energy that can run a process at constant P, T (though it can be affected by changing P and T) Reactions that have potential energy in a system ...
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Chemical equilibrium



In a chemical reaction, chemical equilibrium is the state in which both reactants and products are present in concentrations which have no further tendency to change with time. Usually, this state results when the forward reaction proceeds at the same rate as the reverse reaction. The reaction rates of the forward and backward reactions are generally not zero, but equal. Thus, there are no net changes in the concentrations of the reactant(s) and product(s). Such a state is known as dynamic equilibrium.
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