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NAME: _________________________________________ DATE: ____________ 1. What gas is formed when Zn metal is mixed with hydrochloric acid, HCl? a) CO2 c) O2 b) He d) H2 2. Which property is always conserved during a chemical reaction? a) mass c) pressure b) volume d) solubility 3. A cylinder is weighed empty and with a liquid. Cylinder with liquid 51.85 g Cylinder, empty 40.11 g Volume of liquid in 7.0 mL cylinder What is the density of the liquid? a) 13 g/mL c) 5.7 g/mL b) 7.4 g/mL d) 1.7 g/mL 4. Which one of the following is the correct formula for aluminum oxide? a) AlO c) Al2O3 b) Al6O6 d) Al3O2 5. What is the name of the compound CF4? 6. 7. 8. a) fluorocarbonate b) carbon tetrafluoride c) tricarbo fluoride d) carbon difluorate Sodium nitride has the formula Na3N. What is the formula for magnesium nitride? a) Mg2N c) Mg3N2 b) Mg3N d) Mg2N3 What is the mass of one mole of aluminum sulfate, Al2(SO4)3? a) 630 g c) 273 g b) 342 g d) 123 g Which set of coefficients balances the equation for the complete combustion of ethane, C2H6? __C2H6 + __O2 __CO2 + __H2O a) 1,3,2,3 c) 2,6,4,5 b) 1,6,2,6 d) 2,7,4,6 9. When this expression is balanced, 2C3H6 + O2 CO2 + 6H2O what is the coefficient of oxygen, O2? a) 6 c) 12 b) 9 d) 18 10. During a “titration lab,” an acid was neutralized by the following reaction: NaOH + HCl NaCl + H2O This reaction would be classified as… a) synthesis b) decomposition c) double replacement d) single replacement 11. Which reaction below would be classified as a decomposition reaction? a) NaHCO3 NaOH + CO2 b) 2 H2 + O2 2 H2O c) 2 AgNO3 + Cu° Cu(NO3)2 + 2 Ag° d) Ba(OH)2 + H2SO4 BaSO4 + 2 H2O 12. The complete combustion of ethane, C2H6, produces a) C2H5OH c) CO2 and H2 b) CH3COOH d) CO2 and H2O 13. What quantity of sulfur dioxide, SO2 (64.0 g/mole), is produced when 245 g of sulfuric acid, H2SO4 (98.0 g/mole) reacts completely with zinc metal? Zn° + 2 H2SO4 ZnSO4 + SO2 + 2 H2O a) 64.0 g c) 128 g b) 80.0 g d) 160 g 14. How many moles of FeS2 are required to produce 64 grams of SO2 according to the equation 4FeS2(s) + 11O2(g) 2Fe2O3(s) + 8SO2(g) a) 0.40 c) 3.2 b) 0.50 d) 4.5 15. Glass, SiO2, reacts with hydrofluoric acid, HF, according to this equation SiO2 + 4 HF 2 H2O + SiF4 Which reagent is completely consumed when 2 moles of SiO2 is added to 6 moles of HF? a) SiF4 c) HF b) H2O d) SiO2 16. Which of the following is an acid? a) NaOH c) HCl b) NH3 d) KOH 17. The acid, H2S, is correctly named as: a) hydrosulfuric acid b) sulfuric acid c) dihydrogen sulfide d) hydrogen(I) sulfide 18. Hydrogen gas was produced according to the following equation: Zn° + 2 HCl ZnCl2 + H2 Which chemical is oxidized? a) Zn° c) ZnCl2 b) HCl d) H2 Table of common polyatomic ions, arranged by charge. 2+ Hg22+ mercury(I) 2- 1CH3COO- acetate CO32- ClO3- chlorate CrO42- chromate ClO2- chlorite Cr2O72- dichromate CN- cyanide NH4+ ammonium H2PO4- dihydrogen phosphate HPO42- hydrogen phosphate H3O+ hydronium HCO3- hydrogen carbonate or mercurous 1+ or bicarbonate HSO4- hydrogen sulfate OH- hydroxide ClO- hypochlorite NO3- nitrate NO2- nitrite ClO4- perchlorate MnO4- permanganate SCN- thiocyanate or bisulfate carbonate O22- peroxide SO42- sulfate SO32- sulfite S2O32- thiosulfate 3PO43- phosphate SOLUBILITY RULES: Salts containing the following ions are normally soluble: All salts of group IA (Li+, Na+, etc) and the ammonium ion (NH4+) are soluble. All salts containing nitrate (NO3-)acetate ( CH3COO-), and perchlorates are soluble. All chlorides (Cl-), Bromides (Br-), and iodides(I-) are soluble except those of Cu+, Ag+, Pb2+, and Hg22+ All salts containing sulfate (SO42-) are soluble except those of Pb2+, Sr2+, and Ba2+. Salts containing the following ions are normally insoluble: Most carbonates (CO32-) and phosphates (PO43-) are insoluble except those of group IA and the ammonium ion. Most sulfides (S2-) are insoluble except those of group IA and IIA and the ammonium ion. Most hydroxides (OH-) are insoluble except those of group IA, calcium, strontium, and barium. Most oxides (O2-) are insoluble except those of group IA, and calcium, strontium, and barium which react with water. Exercise #3 Type of Compound How To Recognize How To Name Types of Compounds Ionic Acids metal + non-metal starts with H + anion names of + ion then ion “ides” hydro---ic acid “ates” ----ic acid S (add “ur”) P (add “or”) N A M I N G Molecular two non-metals mono, di, tri, tetra, penta, hexa, hepta, octa, nona ,deca names ends with “ide” pentaoxide pentoxide, etc. Indicate the Type of Compound and then name the compound using the appropriate rules: 1. NaF ___ __________________ 21. CuCl2 ___ __________________ 2. FeCl3 ___ __________________ 22. AgNO3 ___ __________________ 3. CO2 ___ __________________ 23. CO ___ __________________ 4. MgCl2 ___ __________________ 24. H3PO4 ___ __________________ 5. HF ___ __________________ 25. NaCl ___ __________________ 6. SF4 ___ __________________ 26. N2O5 ___ __________________ 7. HC2H3O2 ___ __________________ 27. NO2 ___ __________________ 8. H2O ___ __________________ 28. HNO3 ___ __________________ 9. NH3 ___ __________________ 29. NaOH ___ __________________ 10. CaO ___ __________________ 30. SnCl2 ___ __________________ 11. NH4NO3 ___ __________________ 31. CaSO4 ___ __________________ 12. NaI ___ __________________ 32. HBr ___ __________________ 13. PbCO3 ___ __________________ 33. Cu(OH)2 ___ __________________ 14. Na2O ___ __________________ 34. Zn(OH)2 ___ __________________ 15. Ba(NO3)2 ___ __________________ 35. BaCl2 ___ __________________ 16. K2CrO4 ___ __________________ 36. PCl5 ___ __________________ 17. NO ___ __________________ 37. PCl3 ___ __________________ 18. HCl ___ __________________ 38. AsF5 ___ __________________ 19. MnO2 ___ __________________ 39. H2CO3 ___ __________________ 20. H2S ___ __________________ 40. ___ __________________ OF2 Exercise #4 Chemical Equations and Stoichiometry WRITING IONIC COMPOUNDS Ionic compounds are formed from a positive ion (cation) and a negative ion (anion). The positive ion is always written first. The resulting compound must be electrically neutral. Use parentheses when you need two or more polyatomic ions in a formula. Cl OH S2 CO32 PO43 Na+ NH4+ Ca2+ Al3+ Sn4+ Hg22+ Naming ionic compounds is easy. The name is simply the name of the cation, followed by the name of the anion. # 1. Name ammonium phosphate Cation NH4+ Anion PO43- 2. barium nitrate Ba2+ NO3- 3. cuprous sulfide or copper (I) sulfide Cu+ S2- 4. aluminum carbonate Al3+ CO32- 5. strontium hydroxide Sr2+ OH- Formula Exercise #6 2f: Inorganic Nomenclature II Add either a name or a formula to complete each table. 1. Potassium dichromate 2. Lithium sulfide 3. Potassium bromide 4. Cesium iodide 5. Calcium phosphide 6. Sodium fluoride 7. Strontium oxide 8. Beryllium sulfide 9. Magnesium bromide 10. Lithium oxide 11. Strontium chloride 12. Barium bromide 13. Magnesium sulfide 14. Magnesium iodide 15. Hydrogen fluoride (Hydrogen monofluoride) 16. Barium phosphide 17. Sodium hydrogen phosphate 18. Potassium chloride 19. Lithium nitride 20. Calcium sulfide 21. Rubidium oxide 22. Strontium nitride 23. Cesium phosphide 24. Magnesium carbonate 25. Beryllium sulfate 26. ScCl3 27. HCl 28. PtO2 29. Sb(ClO3)5 30. GeS2 31. ZnO 32. VSO4 33. CuCl2 34. TiO2 35. NiN 36. Ni3(PO4)2 37. CoF3 38. Au2O3 39. Zn3P2 40. Cr(NO3)6 41. NaIO2 42. NaIO3 43. NaI 44. H2SO3 45. H2CO3 46. AlN 47. AlH3 48. Li3AsO4 49. NaCN 50. Na2O2 Exercise #7: Balancing Equations I Balance the following equations. O2 H2O H3PO4 + NaOH Na3PO4 + H2O 3. Na + B2O3 Na2O + B 4. HCl + KOH KCl + H2O 5. K + KNO3 K2O + N2 6. C + S CS2 7. Na + O2 Na2O2 8. N2 + O2 N2O4 9. H3PO4 + Ca(OH)2 Ca3(PO4)2 + H2O 10. KOH H2CO3 K2CO3 + H2O 11. NaOH + HBr NaBr + H2O 12. H2 + O2 H2O2 13. K + O2 K2O 14. Al(OH)3 + H2SO3 Al2(SO3)3 + H2O 15. Al + S8 Al2S3 16. Li + N2 Li3N 17. Ca + Cl2 CaCl2 18. Rb + RbNO3 Rb2O + N2 19. C6H12 + O2 CO2 + H2O 20. N2 + H2 NH3 1. H2 2. + + Exercise #8: Stoichiometry Summary TYPE 1: Those involving Avogadro’s number. Question 1 A sample of Ag is found to contain 9.7 x 10 23 atoms Ag. How many moles of Ag atoms are in the sample? Question 2 How many Sb atoms are found in 0.43 moles of pure Sb? TYPE 2: Those involving the relationship between mass, moles and molar mass. Question 3 What is the mass in grams of 2.53 moles Al? Question 4 How many moles of Na in 20g of Na? Question 5 If 50 moles of a simple, binary, group I chloride have a mass of 3725g identify the group I metal. TYPE 3: Those combining types 1 & 2. Question 6 How many Zr atoms are found in a 1.23g sample of Zr? Question 7 What is the mass of 5.14 x 1023 atoms of uranium? Question 8 What mass of C atoms have the same number of atoms as are in a 11.2g sample of Si? TYPE 4: % by mass Composition. Question 9 Calculate the percent by mass composition of ethanol, C2H6O. Question 10 What is the percent by mass composition of N2O5? Question 11 A compound has the formula Al4[Fe(CN)6]3. What is the percent by mass composition of this compound? TYPE 5: Empirical formulae. Question 12 A compound contains 26.9% N and 73.1% F. What is the empirical formula of the compound? Question 13 2.3g of magnesium is completely reacted with 6.75g of chlorine. What is the empirical formula of the compound formed? TYPE 6: Molecular formulae from empirical formulae. Question 14 What is its molecular formula of hydrocarbon that has an empirical formula of C 2H5 and a molecular mass of 58. Question 15 A compound contains 68.54% carbon, 8.63% hydrogen, and the remainder oxygen. The molecular weight of this compound is approximately 140g/mol. What is the empirical formula? What is the molecular formula? Type 7: Combustion Analysis. Question 16 The combustion of 2.95 grams of a compound that contains only C, H and S yields 5.48 grams of CO 2 and 1.13 grams of H2O. What is the empirical formula of the compound? Question 17 If, in the reaction below, of 31 grams of C4H10 produces 41 grams of CO2 what is the % yield? 2C4H10 + 13O2 8CO2 + 10H2O Question 18 If, in the reaction below, 80.1 grams of Cl2 produces 33.12 grams of CCl4 what is the % yield? CS2 + 3Cl2 CCl4 + S2Cl2 Type 9: Limiting Reactant. Question 19 Consider the reaction between Aluminum and Iron (III) oxide to produce Aluminum oxide and Iron metal. a) Write an equation for the reaction. b) If 1240g of Al are reacted with 6010g of Iron (III) oxide, identify the limiting reagent. Which reagent is in excess? c) Calculate the mass of Iron formed. d) How much of the excess reagent is left over at the end of the reaction? Type 10: Analysis of hydrated salts. Question 20 Copper (II) sulfate is found as a hydrated salt, CuSO 4.xH2O. A technician carefully heats 2.50g of the salt to a constant mass of 1.60g. a) What is meant by constant mass? b) How many moles of copper sulfate are there in 1.60g of anhydrous copper (II) sulfate? c) How many moles of water were lost? d) What is the value of x in the formula? Type 11: Moles and reacting ratios (including solutions). Question 21 Sodium hydrogen carbonate, NaHCO3, combines with HCl as indicated below. NaHCO3(aq) + HCl(aq) NaCl(aq) + CO2(g) + H2O(l) a) What volume of 1.5M HCl solution should be present to combine totally with 0.14 moles of NaHCO3? b) How many moles of CO2 are produced when 0.49 g of NaHCO3 combines with excess HCl? c) Calculate the mass of NaCl that results when 1.48 moles of HCl combines with excess NaHCO 3. d) What mass of NaHCO3 is required to produce 6.1 x 103 moles of H2O? Question 22 Carbon tetrachloride, CCl4, can be produced in the reaction below. CH4 + 4Cl2 CCl4 + 4HCl a) What mass of CH4 is needed to exactly combine with 3.4 g Cl2? b) How many grams of Cl2 are required to produce 91 g CCl4, assuming excess CH4? c) What mass of CH4 must have reacted, if 2 mg HCl is liberated? d) Calculate the mass of both CH4 and Cl2 required to produce exactly 0.761 kg CCl4? Exercise #10: Writing chemical equations Write balanced equations for the following reactions. Where possible include state(g, l, s) symbols. 1. Pure, molten iron forms when solid iron (III) oxide reacts with carbon monoxide gas. Carbon dioxide gas is also a product. 2. Potassium oxide reacts with water to produce potassium hydroxide. 3. During photosynthesis glucose (C6H12O6) forms from carbon dioxide and water. Oxygen is also a product. 4. Sodium phosphate and barium sulfate are made during a reaction between sodium sulfate and barium phosphate. 5. Ammonium nitrate can decompose explosively to form nitrogen, water and oxygen. 6. The combustion (combination with oxygen) of liquid octane (C 3H8) produces gaseous carbon dioxide and steam. 7. The combination of sodium metal and chlorine gas yields solid sodium chloride. 8. Hydrogen gas forms when magnesium metal comes in contact with an aqueous solution of ethanoic acid (CH3COOH). An aqueous solution of magnesium ethanoate Mg (CH3COO)2 is the other product. 9. The decomposition of solid copper (II) nitrate yields solid copper (II) oxide and nitrogen dioxide, and oxygen gases. 10. Solid mercury (II) oxide forms from the uncombined elements. Mercury is a liquid at room temperature. 11. Magnesium metal and steam combine to form solid magnesium hydroxide and hydrogen gas. 12. An aqueous solution of hydrogen peroxide (H2O2) and solid lead (II) sulfide combine to form solid lead (II) sulfate and water. 13. Solid Sodium reacts with liquid water to produce aqueous sodium hydroxide and hydrogen gas. 14. Zinc reacts with silver nitrate to produce silver and zinc nitrate. 15. Aluminum sulfate reacts with calcium chloride to produce aluminum chloride and calcium sulfate. 16. Solid potassium hydroxide pellets decompose on heating to form solid potassium oxide and water. Name_____________________ Period __ Date __/__/__ Exercise #9_Chemical Equations and Stoichiometry COMBUSTION EQUATIONS For burning to occur, you need a fuel, an oxidizer, and heat. When hydrocarbons are the fuel and O2 in the air is the oxidizer, then CO2 and H2O are the products. Example: Write the balanced equation for the complete combustion of propane, C3H8, in air. Solution: First, set up the basic equation. You memorize the “+ O2 CO2 + H2O” part. C3H8 + O2 CO2 + H2O Next, balance. 3 C’s in C3H8 result in 3CO2’s; 8 H’s in C3H8 result in 4 H2O’s; C3H8 + __ O2 3 CO2 + 4 H2O Total O’s on the product side = 10 [(3 x 2) + (4 x 1)] = total O’s on the reactant side. This would mean that 5 O2’s were involved. Tip: If an UNEVEN number of O’s need to be represented, a fraction should be used. 7 O’s = 7/2 O2 Tip: Take into account fuels that contain oxygen. Subtract the O’s from that represented as O2’s Practice: Write the balanced combustion equations for the following substances. 1. CH4 2. C5H12 3. C9H20 4. C2H6 5. C8H18 6. C4H10 7. C2H5OH 8. C3H7OH 9. HC2H3O2 10. CH3COCH3 Name___________________________ ______ Period ___ Date ___/___/___ Exercise #11 Acids & Bases TITRATION PRACTICE An acid and a base neutralize each other when the moles of H+ = the moles of OH. A formula similar to the dilution formula can be used to determine the concentration of an unknown acid or base. VaMa=VbMb Example: where a = H+ b = OH- What is the concentration of a 10.0 mL sample of HCl if 35.5 mL of 0.150 M NaOH is needed to titrate it to a pink endpoint? (10.0 mL) (x) = (35.5 mL) (0.150 M) x= (35.5 mL)(0.150 M) = 0.5325 M = 0.533 M 10.0 mL 1. What is the concentration of a 15.0 mL sample of HCl if 28.2 mL of 0.150 M NaOH is needed to titrate it? 2. A 10.0 mL sample of a monoprotic acid is titrated with 45.5 mL of 0.200 M NaOH. What is the concentration of the acid? 3. A 5.00 mL sample of vinegar has a concentration of 0.800 M. What volume of 0.150 M NaOH is required to complete the titration? 4. A 10.0 sample of household ammonia, NH3(aq), is titrated with 0.500 M HCl. If 25.7 mL of acid is required, what is the concentration of the household ammonia? 5. A 5.00 mL sample of H2SO4 is titrated with 0.150 M NaOH. If 20.0 mL of the base is required to titrate the acid sample, what is the [H+] of the acid? ________ What is [H2SO4]? _________ 12 The Gas Laws THE IDEAL GAS LAW PV = nRT where P = pressure in atmosphere V = volume in liters n = number of moles of gas R = Universal Gas Constant = 0.0821 Latm/molK T = Kelvin temperature 1. What is the pressure of 1.20 moles of SO2 gas in a 4.00 L container at 30°C? 2. How many moles of oxygen will occupy a volume of 2.50 liters at 1.20 atm and 25 C? 3. What is the volume of 0.60 moles of helium gas at 50°C if the pressure is 600 torr? 4. At what temperature will 1.80 moles of gas occupy 4.00 L if the pressure is 350 mmHg? 5. A balloon filled with helium has a volume of 1.30 L at 15°C when the atmospheric pressure is 700 torr. How many molecules of helium is in the balloon? 6. What is the mass of a 300 mL sample of gaseous hydrogen chloride at 2.0 atm and 30°C? . m = µPV/RT where m is mass in grams and µ is molar mass What is the density of this sample? D = m/V where D is density in grams per Liter 7. A 30.0 g sample of CH4 occupies 150 mL at 0°C. What is the pressure of this sample of gas? P = mRT/Vµ 8. What volume (in liters) does a 85.0-g sample of CO2 gas occupy at 1.40 atm and 80°C? V = mRT/µP What is the density of this gas? D = m/V 9. How many moles of an unknown diatomic gas are contained in a 500 mL container at 1.20 atm and 25°C? If this unknown diatomic gas has a mass of 0.93 g, what is the molar mass of the gas? What is the gas? µ = g/mol 12 The Gas Laws BOYLE’S LAW Boyle’s Law states that the volume of a gas varies inversely with its pressure if temperature is held constant. (If one goes up, the other goes down.) We use the formula: P1 V1 = P2 V2 Solve the following problems (assuming constant temperature). Assume all number are 3 significant figures. 1. A sample of oxygen gas occupies a volume of 250 mL at 740 torr pressure. What volume will it occupy at 800 torr pressure? 2. A sample of carbon dioxide occupies a volume of 3.50 Liters at 125 kPa pressure. What pressure would the gas exert if the volume was decreased to 2.00 liters? 3. A 2.00-Liter container of nitrogen had a pressure of 3.20 atm. What volume would be necessary to decrease the pressure to 1.00 atm? 4. Ammonia gas occupies a volume of 450 mL as a pressure of 720 mmHg. What volume will it occupy at standard pressure (760 mmHg)? 5. A 175 mL sample of neon had its pressure changed from 75.0 kPa to 150 kPa. What is its new volume? 6. A sample of hydrogen at 1.50 atm had its pressure decreased to 0.50 atm producing a new volume of 750 mL. What was the sample’s original volume? 7. Chlorine gas occupies a volume of 1.20 liters at 720 torr pressure. What volume will it occupy at 1 atm pressure? 8. Fluorine gas exerts a pressure of 900 torr. When the pressure is changed to 1.50 atm, its volume is 250 mL. What was the original volume? 12 The Gas Laws CHARLES’S LAW Charles’ Law states the volume of a gas varies directly with the Kelvin temperature, assuming the pressure is constant. We use the following formulas: V1 V2 T1 T2 or V1 T2 = V2 T1 K = C + 273 Solve the following problems assuming a constant pressure. Assume all numbers are 3 significant figures. 1. A sample of nitrogen occupies a volume of 250 mL at 25 C. What volume will it occupy at 95 C? 2. Oxygen gas is at a temperature of 40 C when it occupies a volume of 2.30 Liters. To what temperature should it be raised to occupy a volume of 6.50 Liters? 3. Hydrogen gas was cooled from 150 C to 50 C. Its new volume is 75.0 mL. What was its original volume? 4. Chlorine gas occupies a volume of 25.0 mL at 300 K. What volume will it occupy at 600 K? 5. A sample of neon gas at 50 C and a volume of 2.50 Liters is cooled to 25 C. What is the new volume? 6. Fluorine gas at 300 K occupies a volume of 500 mL. To what temperature should it be lowered to bring the volume to 300 mL? 7. Helium occupies a volume of 3.80 Liters at –45 C. What volume will it occupy at 45 C? 8. A sample of argon gas is cooled and its volume went from 380 mL to 250 mL. If its final temperature was –55 C, what was its original temperature? 12 The Gas Laws THE COMBINED GAS LAW In practical terms, it is often difficult to hold any of the variables constant. When there is a change in pressure, volume and temperature, the combined gas law is used. P1V1 P2 V2 T1 T2 or P1 V1 T2 = P2 V2 T1 K = C + 273 Complete the following chart. 1 P1 V1 T1 P2 1.50 atm 3.00 L 20.0 C 2.50 atm V2 T2 30.0 C 2 3 25.0 C 250. mL 50.0 C 720. torr 256. mL 600. mmHg 2.50 L 22.0 C 760. mmHg 1.80 L 750. mL 0.00 C 2.00 atm 500. mL 25.0 C 101. kPa 6.00 L 471. K or 198. C 900. torr 225. mL 150. C 2.50 L 30.0 C 100 mL 75.0 C 4 5 95.0 kPa 4.00 L 6 650. torr 7 850. mmHg 1.50 L 8 125. kPa 125. mL 100. C 15.0 C 100. kPa Oxidation Numbers: 1) In which reaction does the oxidation number of oxygen increase? A) Ba(NO3 )2 (aq) + K 2SO4 (aq) BaSO4 (s) + 2 KNO3 (aq) B) HCl (aq) + NaOH (aq) → NaCl (aq) + H 2 O (l ) C) MgO (s) + H2 O (l ) Mg(OH)2 (s) D) 2 SO2 (g) + O2 (g) 2 SO3 (g) E) 2 H2 O (l ) 2 H2 (g) + O2 (g) 2) In which reaction does the oxidation number of hydrogen change? A) HCl (aq) + NaOH (aq) → NaCl (aq) + H 2 O (l ) B) 2 Na (s) + 2 H2 O (l ) 2 NaOH (aq) + H2 (g) C) CaO (s) + H2 O (l ) Ca(OH)2 (s) D) 2 HClO4 (aq) + CaCO3 (s) Ca(ClO4 )2 (aq) + H2 O (l ) + CO2 (g) E) SO2 (g) + H2 O (l ) H2 SO3 (aq) 3) In which species does sulfur have the highest oxidation number? A) S8 (elemental form of sulfur) B) H 2S C) SO 2 D) H 2SO3 E) K 2SO4