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Transcript
TYPES OF ORGANIC REACTIONS Organic reaction can be classified into different types. Many of these you learned about last year. This paper summarises them for you. Combustion: All hydrocarbons and some other organic chemicals (e.g. alcohols) undergo complete combustion in a sufficient supply of oxygen to produce carbon dioxide and water. If there is insufficient oxygen the combustion is incomplete and the products are carbon (soot), carbon monoxide and water. e.g. CH4(g) + O2(g) CO2 (g) + H2O (l) Substitution: In these reactions one atom is replaced by another. There are two products. Last year you saw that alkanes undergo a slow substitution reaction in the presence of UV. We will meet some more substitution reaction this year. e.g. CH3CH3 (g) + Br2 (l) UV light CH3CH2Cl (g) + HBr (g) Addition: In addition reactions a double bond is broken and atoms are added to a molecule. These reactions are normally fast and only one product is formed. e.g. CH2=CH2 (g) + Br2(l) CH2BrCH2Br (g) When the molecule that is being added (the addition reagent) is not symmetrical, two products may be possible, as the two carbon atoms will bond with different atoms. e.g. CH3CH=CH2 (g) + HBr CH3CH2CH2Br (g) + CH3CHBrCH3(g) Minor product Major product One product will be there in greater amounts than the other and is called the major product (the other is called the minor product). To decide which is the major product, Markovnikov’s rule is used: The hydrogen atom of the addition reagent goes to the carbon atom of the double bond, that is attached to the greatest number of hydrogen atoms. “the rich get richer” Condensation: In this type of reaction two molecules join together and expel a small molecule (usually water or HCl).An ester if formed when a carboxylic acid undergoes a condensation reaction with an alcohol. e.g. CH3COOH (l) + CH3CH2OH (l) Conc. H2SO4 CH3COOCH2CH3 (l) + H2O (l) The formation of proteins involves a series condensation reactions of amino acids. Elimination: This is the reverse of addition reactions. Something is removed from a molecule and a double bond forms. E.g. the dehydration of an alcohol to form an alkene. CH3CH2OH Conc. H2SO4 CH2 = CH2 + H2O If the molecule is longer, then the reverse of Markonikov’s rule (Saytzeff’s rule) applies: The hydrogen atom tends to be eliminated from the carbon atom joined to the least number of hydrogen atoms. “the poor get poorer” Conc. H2SO4 CH3CH2CH(OH)CH3 CH3CH = CHCH3 + CH3CH2CH = CH2 + H2O Major product poor Minor product rich Oxidation and Reduction Oxidising agents e.g. MnO4- /H+, Cr2O72- / H+ are used to oxidise organic chemicals such as alcohols. A primary alcohol can be oxidised to an aldehydes and then to a carboxylic acid. Cr2O72-/ H+ e.g. CH3CH2OH CH3CHO Cr2O72-/ H+ CH3COOH