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Geology 103 Name: Lab 2: The rocks Outcome: The continents and seafloors are made of rocks, which are in term made of minerals. The properties of the rocks will influence the process of plate tectonics. In this lab, you will discover some of the properties of different minerals and rocks. Igneous rocks All of these elements occur in the crystal structure of eight common igneous rockforming minerals. These minerals in turn make up 95% of the volume of all igneous rocks. The names and chemical formulae for these minerals: Olivine Plagioclase Pyroxene Amphibole Biotite Orthoclase Muscovite Quartz (Mg,Fe)2SiO4 NaAlSi3O8 (sodium-rich) CaAl2Si2O8 (calcium-rich) Complex Ca-Mg-Fe-Al silicates Complex water-bearing Na-Ca-Mg-Fe-Al silicates K(Mg,Fe)3AlSi3O10(OH)2 KAlSi3O8 KAl2(AlSi3O10)(F,OH)2 SiO2 The list of minerals is in decreasing order of freezing (melting) temperature of the mineral; in other words, olivine freezes from a magma first as the magma cools, and quartz last. 1. Using the mineral ID charts in the rock handbook, identify the eight common igneous rock-forming minerals. I don’t care how you do it, but do list the features of the mineral that most distinguished it to you. Mineral # M1 M7 M9 M10 M11 Mineral name Distinguishing characteristic(s) M12 M13 M14 Finally, those minerals made mostly of elements from the first column of elements on the previous page are called felsic, and those minerals made mostly of elements from the second column of elements on the previous page are called mafic (look at the first initials of the top three element symbols in the second column). 2. One way to separate minerals is according to elemental composition, which, fortunately for us, is roughly associated with color (as seen in the mineral ID charts): darker minerals tend to be mafic, and lighter minerals tend to be felsic. The exceptions will be calcium-rich plagioclase, which is considered to be mafic, and biotite, which is considered to be felsic. Color Minerals Average specific gravity (density) Diagnostic chemistry Darkcolored (mafic) 3.3 Magnesium, aluminum and iron-rich Lightcolored (felsic) 2.8 Silica-rich 3. Look at rock samples R4 and R6. Identify the minerals that are present in each sample (a hint is given as to the color of each mineral), then determine if the rock overall is mafic, felsic or intermediate, based on the table in question 2. Sample Minerals present Mafic, felsic or intermediate? Pink = R4 White = Translucent = Dull black = R6 Shiny black = Dull green = 4. So what is the difference between a mineral and a rock? 5. An igneous rock may be identified by either its texture or its characteristic mineralogy and grain size. Mineralogy means “are the minerals in the rock generally felsic, generally mafic, or even amounts of both (intermediate)?”. Grain size means “what is the predominant size of the minerals in this rock? Sand-size? Silt-size? Claysize?” Texture means “overall, what sort of distinguishing irregularities occur over the whole rock? Bubbles (vesicles)? Shattered bits of other rock?” Using Tables B-1a (grain size and mineralogy) and B-1b (texture), identify the following rocks: (BIG hint: use Table B-1a for R4 – R9 and use Table B-1b for R12 – R16) Rock # R4 R5 R6 R7 R8 R9 Felsic, mafic or intermediate? Predominant grain size Rock name Rock # Texture Rock name R12 R13 R14 R15 R16 The viscosity of a fluid is its ability to resist flow; higher viscosity means that the fluid doesn't flow very fast. You will easily be able to outrun a viscous lava flow; you will not be able to outrun a non-viscous (runny) lava flow. The reason for this lies in the chemical composition of the lava: the silicate ion is not as mobile (in other words, tends to stick to other silicate ions) as metal (e.g., iron, magnesium, aluminum) ions. 6. Answer the following questions with mafic, felsic, intermediate or any: a. Which magma contains more silica? b. Which magma will be erupted at an initially lower temperature? c. Which magma will have higher viscosity? d. Which magma will have higher volatile (gas) content? e. Which magma will likely erupt explosively? f. Therefore, which magma will likely end up as a widespread ash? Table B-1a. Igneous rocks which are identified by their composition/grain size Felsic Intermediate Mafic quartz orthoclase biotite Na-plagioclase Na-plagioclase amphibole pyroxene biotite Ca-plagioclase olivine pyroxene Coarse-grained (mostly visible grains) GRANITE DIORITE GABBRO Fine-grained (mostly invisible grains) RHYOLITE ANDESITE BASALT COMPOSITION (Minerals present) TEXTURE Table B-1b. Igneous rocks which are identified by their texture 1. Is the rock glassy on any fresh surface? Yes — Obsidian No — Go to #2. 2. Is the rock vesicular (containing gas bubbles)? Yes — Go to #3 No — Go to #4 3. Is the rock dark-colored on a fresh surface? Yes — Scoria No — Pumice 4. Is the rock composed of large pieces of broken rocks? Yes — Breccia No — Go to #5 5. Is the rock well-cemented (doesn't crumble easily)? Yes — Welded tuff No — Tuff Tuff and pumice are sometimes difficult to tell apart; however, a simple test distinguishes them: pumice floats on water and tuff sinks. Sedimentary rocks Sedimentary rocks are deposited. Using the agents of transport (wind, water or ice), the loose material (called sediment) is compacted (compressed so that the pore space is removed) and cemented (what pore space remaining is filled with a different chemical) into a sedimentary rock. Sediment is made by the erosion of weathered rocks. Weathering is the process that either chemically or physically breaks up fresh rock material; an example of chem-ical weathering is a rock reacting with acid rain, while an example of physical wea-thering is when water freezes with a crack in the rock and makes the crack bigger. Though most sediment deposits on the Earth’s surface (which includes the bottom of the ocean), sediment must be buried to achieve proper lithification. During lithification, the sediment may be heated but nothing close to melting. Instead, the heat may cause chemical reactions that alter some of the minerals; for instance, calcium carbonate in the mineral aragonite may repack into calcium carbonate in the mineral calcite. These kinds of changes are called diagenesis. Sedimentary rocks fall into two categories: clastic sedimentary rocks, which are those that are made of weathering products of pre-existing rocks, and chemical or biochemical sedimentary rocks, which are the result of either evaporation or precipitation of mineral-rich water or the accumulation of the remains of biological organisms. To sum up: “Some sedimentary rocks are born, not made, but all are deposited”. Many of the same elements that occur in the igneous rock-forming minerals also occur in sedimentary minerals. However, since weathering reactions occur, the elements will rearrange and form new crystal patterns, which will have different mineral names. In addition, the surface environment contains compounds such as water (H2O) and carbon dioxide (CO2) that will react and become part of the sedimentary minerals. Sedimentary minerals are the most common minerals found on the earth’s surface because sedimentary rocks make up most of the earth’s surface. The names and chemical formulae for these minerals: Quartz Calcite Gypsum Halite Pyrite Magnetite SiO2 CaCO3 CaSO4•2H2O NaCl FeS2 Fe3O4 Some minerals you will not see in lab, because they are clay minerals and thus difficult to identify without more sophisticated equipment: Kaolinite Al2Si2O5(OH)4 Illite Smectite Complex hydrated potassium and aluminum sheet silicates Complex hydrated sodium and aluminum sheet silicates 7. Again using the mineral ID charts and any means possible, identify the six common sedimentary rock-forming minerals (i.e., the list given above, except for the clay minerals). Note that one of these will be the same as one you saw in the igneous minerals portion of this lab. Give a distinguishing characteristic of each mienral. Mineral # Mineral name Distinguishing characteristic(s) M1 M2 M8 M15 M16 M17 Properly speaking, magnetite is also formed as an igneous mineral, but not a major one. Note the abundance of elements like oxygen (O) and sulfur (S) in sedimentary minerals; these elements help stabilize metal ions at the Earth’s surface and will play a large role in the preservation of fossils. Sediment and the process of making sedimentary rocks Find the drawer with the weathering samples. Samples W1 and W2 are igneous rocks from the first part of the lab. Sample W3 is a partially weathered igneous rock. Sample W4 is beach sediment. 8. Identify W1 and W2 (hint: you’ve seen these before in the previous section). 9. Did sample W3 weather from W1 or from W2? 10. Look at sample W4. Did this sediment weather from W1 or from W2? 11. Obtain rock specimens R4, R18, R19 and R29. When sample W4 lithifies, which rock will it become? What’s a generic name for this type of rock? Is it the same rock as the rock you believe W4 originated? 12. As mentioned above, after compacting sediment, in order to make a sedimentary rock, the sediment needs to be cemented by another chemical agent. If there are only the following three cement materials available, how would you identify each cement (think of a test for each)? calcite: iron oxide: silica: 13. Look at rock samples R18 and R19. What is the cement that holds each rock’s grains together? R18 = R19 = 14. How would you be able to tell apart a sedimentary rock made of calcite from one that was made of quartz grains cemented by calcite? (Hint: is the acid test useful here? What other test might be useful?) 15. Sedimentary rocks will be identified, in large part, to the materials they are made of. Fill in the table with the most common mineral of each rock. Note that this question is not asking you about the cement of each rock! Sample R23 R25 R27 Most common mineral Identifying sedimentary rocks 16. Fill in the following table using the clastic Sedimentary Rock ID flow chart. Note there are separate tables for clastic and chemical/biochemical sedimentary rocks. For clastic rocks: • Determine the most common grain size • Determine the degree of grain rounding (choose from: angular, subangular, subrounded or rounded) • Determine the degree of sorting of the grains that occurs in the rock (choose from: well-sorted, moderately-sorted or poorly-sorted) • Then, based on your observations and the ID table, identify the rock. • Finally, determine whether the sediment that makes up the rock was deposited in a low-energy, medium-energy or high-energy depositional environment. Flow chart for identifying clastic sedimentary rocks — If the rock is made of grains or other materials which have been deposited by wind, water or ice, it's a sedimentary rock. For any sedimentary rock, if it contains any fossils, use the adjective fossiliferous in front of the rock name. Consider the most common grain size in the rock from the following list. cobble or pebble sand silt clay > 2 mm 0.062 — 2 mm 0.005 — 0.062 mm < 0.005 mm easily visible to naked eye; "grains" may contain identifiable minerals visible to naked eye; not visible but can be felt between fingers or across teeth not visible; cannot be felt between fingers or across teeth If the most common grain size is cobble or pebble (it may contain other grain sizes in its matrix) → conglomerate If the most common grain size is sand → sandstone (don’t stop here) If the most common mineral is quartz → arenite If the most common mineral is feldspar (orthoclase or plagioclase — rock may look gray or pink) → arkose If there are many dark rock fragments and a significant volume of the rock is silt or clay size→ graywacke If the most common grain size is silt → siltstone If the most common grain size is clay → claystone If there is both silt and clay in the rock → shale Clastic sedimentary rocks Sample # Grain size Grain rounding Grain sorting R18 Medium Well to subrounded Well-sorted Rock name Energy of depositional environment Medium-energy R19 R20 R21 R22 R29 17. Return to R18 and R19 and circle the correct answers: a. Which rock contains the most stable mineral clasts? (= lowest freezing point of the minerals in the rock) R18 R19 b. Which rock is composed of rounder grains? R18 R19 c. Which rock is more well-sorted? R18 R19 d. Based on a-c, which sample was deposited furthest from its source? R18 R19 e. Therefore, which is the more mature rock? R18 R19 18. The energy of the system (how much force is behind the medium of transport (air or water)) can be characterized by the size of the particles the system can carry. For instance, high-energy systems can carry large grains; low-energy systems can carry small grains. Examine and rank rocks R19, R20 and R21 in order from highest energy to lowest energy depositional system. 19. For chemical or biochemical sedimentary rocks: • Write the name of the greatest percentage mineral component • Determine if the sample was chemical in origin or biological in origin • Determine whether the sediment that makes up the rock was deposited in a lowenergy, medium-energy or high-energy depositional environment. • Then identify the rock, using your observations and the ID table. Remember, if there are fossils, add the adjective fossiliferous before the rock name! Flow chart for identifying chemical or biochemical sedimentary rocks — Identify the most common mineral in the specimen If the most common mineral is quartz → chert If the most common mineral is halite → rock salt If the most common mineral is gypsum → rock gypsum If it is black-colored, not very dense and flaky → coal (also look for plant fibers) If it fizzes, the most common substance is calcium carbonate, usually in the form of the mineral calcite (be careful you are not fizzing the cement, or mistaking the fizzing for the fluid entering holes in the rock) If the rock is not very dense, powdery and pure white → chalk If the rock is made of small, round “clasts” → oolitic limestone If the rock is made of almost exclusively broken-up shells → coquina If the rock is banded and/or breaks into sharp-edged pieces → crystalline limestone If the rock is buff colored, does not fizz readily, but the powdered rock fizzes readily → dolostone Else → micrite Note: all of these rocks that fizz are sometimes generically called limestone. Chemical and biochemical sedimentary rocks Sample # Mineral composition Biological or chemical? R23 Calcite Biological (clam shells) R25 R26 R27 Rock name Energy of depositional environment High-energy R28 R30 R31 R32 R33 20. R31 is deposited under high-energy conditions, usually a tropical beach. How do the individual “clasts” (called ooids) in R31 form? Write a paragraph explaining the formation of these ooids. Hint: At the center of the ooid is typically a grain of sand or a fecal pellet. Also, tropical seawater is saturated in dissolved calcium carbonate.