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Scientific Measurement Ch. 3 Scientific Notation 3-1 Qualitative vs. Quantitative – Qualitative observations – descriptions of the quality of the object or its physical appearance (examples: oval, square, round, cold, hard, salty) – Quantitative observations – numbers or amounts that describe the object (examples: 3 inches wide, 2.5 grams, 98.6 F) The room is cold would be a A) Qualitative observation B) Quantitative observation C) Precise observation D) All of the above Scientific Notation • Way to express numbers through the power of 10 • Powers of 10: 100 = 1 101 = 10 102 = 10x10 103 = 10x10x10 • Goal: express large and small numbers in a single digit • Example: – 3500 becomes – 3.5 x 10 x 10 x10 – 3.5 x 103 Scientific Notation • Short cut: – Count the number of spaces you move left or right until decimal falls just after first nonzero digit – 3500 to 3.5 is 3 jumps left – For each jump left add a positive exponent on the 10. – For each jump right add a negative exponent on the 10 – So 3500 is now 3.5 x 103 Let’s Try! • Convert to scientific notation: 1. 625 6.25 x 102 2. 8,000,000 8 x 106 3. 0.0075 7.5 x 10-3 • Convert to normal: 1. 6 x 102 600 2. 5.003 x 103 5003 3. 8.03 x 10-4 0.000803 4. 3.567 x 10-2 0.03567 When converting back to normal, jump the decimal the opposite way. -For positive exponent, jump right (make # bigger) -For negative exponent, jump left (make # smaller) Scientific Notation when Multiplying + Dividing • When multiplying, add • When dividing, the powers of 10 subtract the powers of 10 • Ex: 12 (4.5 x 1012)(3.0 x 108) • Ex: 4.5 x 10 3.0 x 108 = (4.5 x 3.0) x 1012+8 = 1.5 x 10(12-8) = 13.5 x 1020 4 21 = 1.5 x 10 = 1.35 X 10 Addition/Subtraction in Scientific Notation • Before adding or subtracting in scientific notation, you need to make the exponents the same in both numbers. • (5.40 x 103) + (6.3 x 103) = (5.40 + 6.3) x 103 = 11.7 x 103 = 1.17 x 104 Let’s Try! • (4x107) x (2x10-3) = (4x2) x 107+(-3) = 8x104 • (6.3x10-2) / (2.1x104) = (6.3/2.1) x 10-2-4 = 3.0x10-6 • (4.6x103) – (1.8x103) = (4.6-1.8) x 103 = 2.8x103 Significant Figures + Uncertainty in Measurements 3-2 Significant Figures • • • Used for accurate measurements Meaningful digits are significant figures (sig figs). Rules: 1. 2. 3. 4. 5. All nonzero digits are significant (1-9) Ex: 283.47g ____ # of sig figs Zeros occurring in the middle are significant Ex: 56.06g ____ # of sig figs Zeros to the right (trailing), if there is a decimal point, are significant Ex: 73.00g ____ # of sig figs Zeros to the right (trailing), with NO decimal point, are NOT significant Ex: 100g ____ # of sig figs Zeros to the left (beginning) of the first nonzero digit are NOT significant Ex: 0.09g ____ # of sig figs Let’s Try! • How many sig figs? – 0.0672mL 3 – 1.526g 4 – 0.10mg 2 – 607mm 3 – 0100 1 • Round to 2 sig figs: – 0.0672mL 0.067mL – 1.526g 1.5g – 0.10mg 0.10mg – 536,000 540,000 Rounding: If > 5 round up If < 5 stays same More Sig Figs (College Prep only, Concept cross out) • Addition/Subtraction: – The answer has only as many decimal places as the measurement having the least # of decimal places. – Ex: 190.2g + 65.291g + 12.68g = 267.871g • Round to tenths place 267.9g • Multiplication/Division: – The answer has only as many sig figs as the measurement with the least # of sig figs. – Ex: 13.78g/11.3mL = 1.219469g/mL • Round to 3 sig figs 1.22g/mL (College Prep ONLY) Addition or Subtraction The limiting term is the one with the smallest number of decimal places to the right. 12.11 8.0 +1.013 21.123 Round off 21.1 (College Prep ONLY) Multiplying or Dividing The limiting term is the one with the fewest number of sig figs. 12.11 x 18.0 = 217.98 Round off 218 You Try! (College Prep ONLY) • What is the answer in the correct sig figs? • 7.55m x 0.34m = 2.567m2 2.6m2 • 74.626m - 28.34m = 46.286m 46.29m MEASUREMENT in LAB • Always Estimate the last place. 1 cm 2 cm 1.85 or 1.84 cm While the last number is uncertain, it is more accurate than rounding to 1.8 cm READING A RULER Accuracy, Precision and Error • Accuracy is the measure of how close a measurement comes to the actual or true value • Precision is the measure of how close a series of measurements are to one another • Error is the difference between the accepted value and the experimental value. Precision vs Accuracy • The first bulls-eye has no precision and no accuracy. • The second bulls-eye has precision but no accuracy. • The third bulls-eye has precision and accuracy. In a lab setting, which outcome is most desirable? Calculating Percent Error • Accepted value = correct value based on reliable references • Experimental value = value measured in lab. • Percent error = [accepted - experimental] x 100 accepted value • Ex: [100°C – 99.1°C] x 100 100°C = 0.9% error Calculator Input (not in notes) • Find button: EE, EXP, x10, x10n, x10x (DON’T use 10x or ∧) • These buttons mean “x10” with one press • To input (3.2x106) x (6.8x10-3) type: 3.2 EE 6 x 6.8 EE -3 = 21760 • Try (8.99x104) / (6.5x10-23) 8.99 EE 4 / 6.5 EE -23 = 1.383x1027 Calculator Input (not in notes) • Put calculator in scientific notation: – Find “mode,” should see “norm or flo, sci, ….” among other options. Put it in “sci” – Try 9.5 x 6225 – Should get “5.91375x104” NOT “59137.5” • Take calculator out of scientific notation: – Find “mode,” put back in “norm or flo” – Try 9.5 x 6225 again – Should get “59137.5” NOT “5.91375x104” Calculator Input (not in notes – College Prep only) • Try: (6.25x1024) (8.3x103) (1.6x10-5) (1.92x103) (6.7x1015) = 6.5x104 • Try: 3.21x10-3 x 2.6x104 x 2.9x106 1.2x10-6 7.9x109 = 2.6x104 International System of Units 3-3 Measurement • Scientists use the International System of Units, or SI. – Required to keep measurement consistent • Length in meter (m) • Mass kilogram (kg) • Volume in cubic meters (m3) • Temperature in Kelvin (K) • Energy in Joules (J) DRAW! Let’s Try Metrics • 1250 m = _____ km – 1.25km • 5.6 kg = _____ g – 5600g • 16 cm = _____ mm – 160mm • 120 mg = ____ g – 0.12g • Use <, >, = (College Prep only) 5 g ____ 508 mg 5 g > 0.508 g 3.6 m ____ 36 km 3.6 m < 36,000 m Mass vs. Weight • Mass is the amount of matter that makes up an object. • Weight is a measure of the force of gravity on an object • Weight changes based on location, mass does NOT change. Volume • Volume is the amount of space contained in an object • Volume of a box = length x width x height, with the unit cm3 • V=lxwxh • Water: 1 cm3 = 1 mL = 1 g = 0.001 L • Volume of object not box shaped: use water displacement Water Displacement • Ex: – fill graduated cylinder with 200mL (cm3) of water – Drop in a penny – Water level increases to 270mL – How much volume does the penny have? 270mL – 200mL = 70mL! Density 3-4 Density • Density is the amount of matter (mass) compared to the amount of space (volume) the object occupies. • Units in g/cm3 or g/mL • Calculate using formula or wheel D=m v m = D*v v=m D Ex: D = ? m = 10 g v = 2 mL D = 5 g/mL Mass Density Volume Ex: m = ? D = 12 g/cm3 v = 2 cm3 m = 24 g • Which substance is the densest? honey • Which substance is the least dense? lamp oil Temperature 3-5 Measuring Temperature • Celsius scale: water freezes at 0°C, boils at 100°C • Kelvin scale: water freezes at 273K, boils at 373K • Absolute zero = 0 K = -273 °C • Conversion: K = °C + 273 °C = K – 273 • If it is 37 °C, what K is it? K = 37 °C + 273 = 310K