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PowerPoint Lecture Presentation by Myung-Hoon Kim, GPC Introductory Overview Copyright © Myung-Hoon Kim PowerPoint Lecture Presentation by Myung-Hoon Kim, GPC Why Carbon was Chosen for Organisms by Mother Nature? Copyright © Myung-Hoon Kim Characteristics of Living Organism (“Life”): (1) Organization: ordered (2) Exchange matter and energy with surroundings (environments) - consume matter & energy to maintain (& move) (3) Response to stimuli (4) Reproduction (5) Evolution: Undergo change to adapt to new environments which is changing all the time. Brief history of Life on Earth: time before present (BP) 4.6G BP, Earth formed (CO2, CO, CH4, NH3, OH2, H2) 4.3~3.8G BP, Age of Bombardment, Chemical Evolution 3.8G BP, First Prokaryote (Archeo-Bacteria ?) 3.5G BP, Blue-green Algae, (O2 ~ 0.2%) 3.2G BP, Bacteria O2 from Photosynthesis, but used up 2.1G BP, First Eukaryotes, O2 started to buildup 1.5G BP, Multicellular organism (O2 ~ 3%) 800-550M BP, Cryogenic Era (-40oC) 544M BP, Large, complex organisms (Cambrian Period starts: Explosion) 505M BP, Fish 480M BP, Land plants 400M BP, Insects 380M BP, Amphibians 330M BP, Reptiles, Birds 220M BP, Mammals 40M BP, Primates 5M BP, Hominids 2M BP, Homo Brief history of mammals on Earth: 544M BP, Large, complex organisms (Cambrian Period starts) 505M BP, Fish 480M BP, Land plants 400M BP, Insects 380M BP, Amphibians 330M BP, Reptiles, Birds 220M BP, Mammals (Other Classes: Reptila, Amphibia) 50M BP, Primates (Other Orders: Carnivora, Insectivora) 5M BP, Hominids (Other Families: Lemur, Monkeys) 2M BP, Genus Homo diverged from Australopithecines (Homo Hablis started to use Stone Tool) .25M BP, Homo Sapiens evolved replacing H. Erectus & H. Neanderthalensis (in Asia) (in Europe) 0.05M BP, culture develop more rapidly 0.01M BP, Neolithic Age (Domestication of Animals, Plants), First Town 0.005 M BP, History started Brief History of Sciemce/Chemistry Natural Historyof Human BP 220M : Mammals (65M : KT Mass Extinction) 50M : Primates (65M) 2,000,000 : Home species diverged from A. 250,000 : Homo Sapience – Stone Tool. 80,000 : Fire (Cooking) 10,000 : Farming, Neolithic Age 7,000 : Copper 6,000 : Wine 5,000 : Bronze 3,300 : Iron 2,400: Atomic Theory(Democritus) 2,000: (Alchemy) 500: Metallurgy (Bauer), Alchemy (Paracelsus ) 400: Modern Chemistry: ~100: (Robert Boyle, Priestley Lavoisier, Proust, Dalton …) - Greeks were the first to attempt to explain why chemical changes occur: Thales(634-546 BC), “Water” Heraclitus (535-475): “Recycle” Empedocles (490-430): “Water, Earth, Air, & Fire” Democritus(455-370): “Atom” - Alchemy dominated for 2000 years. Several elements discovered. Mineral acids prepared. -Modern Science Bacon(1561-26), Descartes(1596-50) Newton(1642-27) - Robert Boyle (1627-91): the first “chemist” - Performed quantitative experiments. - Dalton (1766-44), Darwin(1809-82) 6 Why Carbon has been chosen by Mother Nature? (1)One of the most Abundant elements cosmically, #5 in mass %: H He O N C Fe Ne Si Mg S 90.8 9.10 0.05 0.04 0.03 0.03 (%) How? (2)Its location in the PT (4th Group, 2nd Period) gives it a moderate electronegativity of 2.5. - forms good Covalent Bond (rather than ionic bond) with others. (3)One of few nonmetals that can form Four covalent bond per atom. This provides it with many different way of combining with other carbon atoms (and atoms of other elements). Branched bonds can be formed to different directions 7 BP Noble Gas Halogen Group Alkali Metal Alkali Earth Metal Period 2.4 Terrestrial & Cosmic Abundance of Element Elements Planet Earth: 3.14(12,800km) = 40,200km 3.14(8,000mi) = 25,000mi 25,000mi/(70mi/hr) = 360hrs = 15days 25,000mi/(600mi/hr) = 42hrs ~ 2days Atmosphere : ~ 1% of the Diameter “Earth is a tiny fragile spaceship in a vast universe.” Earth Planet Earth • Lithosphere: Crust: < 1% (Thin) Everest: 8.85 km Mantle, Core •Hydrosphere: (oceans) 3.8 km Mariana Trench (11mi) ~ 0.2 % • Atmosphere: ~1%: 30 km (99% of air) extends to 120 km • Biosphere: World of Living Organisms Composition Composition of Earth Elements in Air (Atmosphere): N 78%, O 21% Human Body : H2O 65% 2.4 Natural Abundance Elements in Earth’s crust (Lithosphere) Elements in Air (Atmosphere): N 78%, O 21% Elements in Human Body (Biosphere): H2O 65% 2.4 2.2 2.7 • Molecular compounds • nonmetals or nonmetals + metalloids • common names • H2O, NH3, CH4, C60 • element further left in periodic table is 1st • element closest to bottom of group is 1st • if more than one compound can be formed from the same elements, use prefixes to indicate number of each kind of atom • last element ends in ide 2.7 Then why not? • • • • September: 7th month October : 8th November: 9th December: 10th 2.7