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Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Acid, Base, and Salt Solutions CONTENT STATEMENT Acids and bases are frequently encountered in our daily lives in the environment, in the foods we eat, but most importantly, in our bodies. Acids, in general, are proton donors while bases are proton acceptors. Acids and bases react in a neutralization reaction to form a salt and water. Unknown solutions can be titrated with a standard using an acid-base indicator. Weak acids and bases reach equilibria in aqueous solutions. These can be calculated using pH and pOH equations. Buffers protect living organisms by resisting changes in pH when limited amounts of acids or bases are added from physiologic processes or diet. CONCEPTS VOCABULARY Acids and bases Salts and solutions Water equilibria Titration Electrolyte Hydronium ion Conjugate acid and base Binary and ternary acid Amphoteric, Anhydrides Spectator ions Neutralization Salt Ionization constant pH pOH Titration Indicator Buffers Ion product constant Grade 10-12: Chemistry 2011-2012 Science Course of Study PERFORMANCE SKILLS: Distinguish the definitions of acids and bases as outlined in the theories of Arrhenius, Bronsted-Lowry and Lewis Name acids and bases Define acidic and basic anhydrides and write their formulas Define and give examples of strong and weak acids and bases Explain the concepts of neutralization and the composition of a salt and be able to name salts Write net ionic equations Derive and use ionization constants Compute the percent ionization of a weak electrolyte Explain the concepts of solubility product and solve problems using the solubility product constant Solve problems using the ion product constant of water Explain how the pH scale is used for measuring solution acidity Describe the process of hydrolysis and buffering State the principles and uses of indicators Explain the process of titration and perform calculations using the data from titrations Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Energy CONTENT STATEMENT The transfer of energy and how energy interacts with matter is the driving force behind human processes, geologic systems and atmospheric conditions. Energy can be released (exothermic) or gained (endothermic) during both chemical and physical reactions. Energy of a reaction can be measured with a colorimeter using Joules. Chemical reactions require activation energy to proceed from reactants to products. Heat and temperature are not the same thing. Specific heat is the amount of energy required to heat 1 g of a substance 1 degree Celsius. CONCEPTS VOCABULARY Energy transfer Energy and Chemical Change Measuring energy changes Calorimeter Activation energy Endothermic Exothermic Heat Joule PERFORMANCE SKILLS: Describe conditions under which heat is transferred Convert between units Describe exothermic and endothermic processes State the function of activation energy Perform calculations involving specific heat Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Thermodynamics CONTENT STATEMENT Heat released or absorbed in chemical reactions is proportional to the amounts of reactants consumed. When a reversible process occurs, the same amount of energy is involved no matter which way the reaction proceeds. The difference will be if the energy is released or absorbed. Potential energy is stored whenever work must be done to change the distance between two objects. Chemical potential energy is the result of electrostatic attractions between atoms. Energy transferred in a reaction will be the same regardless of the chemical pathway. This relationship is called Hess’s Law. In an exothermic reaction, the products have less energy than the reactants. In an endothermic reaction, the products have more energy than the reactants. Changes of state require a transfer of energy. Water has unusually high-energy changes associated with its changes of state. CONCEPTS VOCABULARY Introduction to thermodynamics Driving forces of chemical reactions Isothermal Isobaric Thermodynamics Internal energy Enthalpy Hess’s law Gibbs free energy Exergonic Endergonic PERFORMANCE SKILLS: State reasons why reactions occur Calculate changes in internal energy Explain why energy changes occur in chemical reactions and perform calculations Relate Gibbs free energy to the spontaneity of reactions and to equilibrium Perform calculations involving Gibbs free energy and entropy, equilibrium constants or cell voltage Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Kinetic Theory: Solids, Liquids and Gases CONTENT STATEMENT Atoms and molecules are constantly in motion, as a substance changes phase, the movement of the atoms or molecules that make up that substance also changes. Gas molecules undergo random motions in a container. This causes them to collide into each other as well as the surface of the container. Spaces between molecules in a gas are larger than spaces in liquids, which are larger than spaces in solids. The properties of gasses can be determined through a combination of equations derived from the ideal gas law. Diffusion is the gradual mixing of two substances due to the spontaneous random motion of their particles. Effusion is the process of a molecule randomly passing through a tiny opening in a container. Grade 10-12: Chemistry 2011-2012 Science Course of Study CONCEPTS Pressure Motion and physical states Variable conditions of the gas laws Avogadro’s Principle Gas Stoichiometry Crystal structure Changes of State VOCABULARY Kinetic theory Pressure Manometer Barometer Absolute zero Mean free path Point mass Ideal gas STP Boyle’s Law Dalton’s Law Charles’ Law Graham’s Law Diffusion Effusion Molar volume Ideal gas equation Limiting and excess reagents Unit cells Macromolecule Doped Network crystals Isomorphous Polymorphous Hygroscopic Deliquescent Anhydrous Liquid crystal Vapor Equilibrium Sublimation Triple point Enthalpy Grade 10-12: Chemistry 2011-2012 Science Course of Study PERFORMANCE SKILLS: List and explain the basic assumptions of the kinetic theory Relate pressure to molecular motion Describe characteristics of solid substances Explain relationship of melting point to bonding type and crystal type Distinguish isomorphous and polymorphous crystals Identify and explain crystal defects Describe semiconductors Distinguish between hydrated ions and anhydrous substances Describe the structure and properties of crystals, liquid crystals and amorphous solids Describe the properties of liquids and changes of state in terms of kinetic theory Use LeChatelier’s principle to explain reversible changes Determine the relationship between energy and change of state and perform related calculations Differentiate among open and closed arm manometers Calculate the pressure of gases using manometers Relate temperature and energy transfer to molecular motion Determine the relative velocities of gas molecules at the same temperature Differentiate among the four states of matter Explain the concepts of an ideal gas Describe the conditions of STP Relate and perform calculations using gas laws Differentiate between an ideal gas and a real gas State Avogadro’s principle Define molar volume Explain, use and manipulate the ideal gas equation Solve gas stoichiometry problems Identify the limiting reactant and solve problems based upon it Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Organic Chemistry CONTENT STATEMENT Carbon is found in nature both as an element and in combined form. It is exceedingly important because it is found in all living matter. Different variations of carbon-carbon bonding allows for different carbon allotropes: Diamond, graphite and fullerenes. Carbon atoms can form single double and triple bonds, as well as ringed structures with itself or with other atoms, leading to a large diversity of organic compounds. Hydrocarbons are long chains that contain a carbon backbone. They have many uses and are of significant importance in today’s world. They can be saturated – containing only single bonds – or unsaturated – containing double or triple bonds. CONCEPTS Hydrocarbons Organic reactions and products Biochemistry VOCABULARY Alkanes Alkenes Alkynes Single, double and triple bonds Benzene Aromatic Radicals Branches Functional groups Saponification Polymer Octane rating Enzyme Protein Amino acid Carbohydrate Fat Grade 10-12: Chemistry 2011-2012 Science Course of Study PERFORMANCE SKILLS: Differentiate between different types of hydrocarbons Identify, name and write structural formulas for hydrocarbons Differentiate between functional groups Describe esterification, polymerization and condensation reactions Describe the processing of petroleum and the octane rating of gasoline Explain how synthetic fibers, plastics and elastomers are produced industrially State the structure and function of the four main biomolecules Describe the progress in and problems associated with the biomaterials industry TOPIC: Periodic Table CONTENT STATEMENT Diversity of species occurs through gradual processes over many generations. Fossil records provide evidence that changes have occurred in number and types of species. Fossils provide important evidence of how life and environmental conditions have changed. Changes in environmental conditions can affect how beneficial a trait will be for the survival and reproductive success of an organism or an entire species. Throughout Earth’s history, extinction of a species has occurred when the environment changes and the individual organisms of that species do not have the traits necessary to survive and reproduce in the changed environment. Most species (approximately 99 percent) that have lived on Earth are now extinct. Grade 10-12: Chemistry 2011-2012 Science Course of Study CONCEPTS Developing the periodic table Using the periodic table Periodic trends Reaction Tendencies Hydrogen and the main group metals Nonmetals Transition metals VOCABULARY Groups Periods Families Metals Nonmetals Metalloids Transition metals Triads Mendeleev Moseley Atomic radii Noble gas configurations Stable configurations First ionization energy Shielding effect Electron affinity Ionic radius Hydrogen ion Hydride ion Catalyst Allotrope Amphoteric Galvanizing Grade 10-12: Chemistry 2011-2012 Science Course of Study PERFORMANCE SKILLS: Describe the early attempts at classifying elements Use the periodic table to predict the electron configurations of elements Explain the basis for the arrangement for the modern periodic table Identify, characterize and give uses for metals, nonmetals and metalloids using the periodic table Relate chemical reactivity of the families due to similar electron configurations Predict the chemical stability of the atoms using the octet rule and Hund’s rule Use examples to explain the periodic properties of elements State how atomic and ionic sizes change in groups and periods Predict oxidation numbers of elements Define ionization energy, electron affinity and shielding effect and its importance to reactivity Describe the factors that affect ionization energy and electron affinity Use multiple ionization energies to predict oxidation numbers of elements List ways in which hydrogen can bond and give examples Relates importance of elements to everyday life Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Atomic Structure and Quantum Theory CONTENT STATEMENT Atoms are the base unit of all matter in the universe. They are the structural make-up for all substances that we know of. Atoms are made up of a nucleus of protons and neutrons which are surrounded by a cloud of charged electrons. Inside of an atom, neutrons have no charge, while protons are positively charges and electrons are negatively charged. Protons and electrons exist in equal quantities in all atoms, so the overall charge of all atoms is zero. Atoms are organized and categorized by there properties as well as the number of protons they contain in their nucleus. The wave properties of electrons can be mathematically described through the quantum theory developed by Heisenberg and Schrodinger. Light is a form of electromagnetic radiation and exhibits properties of both a particle and a wave, giving it many unique attributes and characteristics. Grade 10-12: Chemistry 2011-2012 Science Course of Study CONCEPTS Early atomic models Parts of the atom Modern atomic structure Quantum theory Electron configurations VOCABULARY Rutherford Bohr Dalton Nucleus Protons Neutrons Electrons Quarks Leptons cathode ray tubes Isotopes Atomic number Average atomic mass Mass spectrums Spectroscopy Electromagnetic spectrum Emission spectra Absorption spectra Planck’s constant Quantum theory Photons Wave-particle duality of nature Heisenberg uncertainty principle Sublevels Orbitals Pauli exclusion principle Lewis dot structures Schrodinger’s equation Grade 10-12: Chemistry 2011-2012 Science Course of Study PERFORMANCE SKILLS: Discuss early developments in atomic theory Explain the laws of definite and multiple proportions and give examples Determine the atomic number (Z) and mass number (A) of given isotopes of elements Differentiate among the major subatomic particles Discuss the development of modern atomic theory Calculate the average atomic mass Calculate problems using E=h Compare and contrast relative sizes and masses of subatomic particles Describe the wave-mechanical view of the hydrogen atom Characterize the position and velocity of an electron in an atom Describe an electron cloud Characterize the four quantum numbers Use the Pauli exclusion principle and quantum numbers to describe an electron in an atom Determine the electron configurations of the elements Write Lewis dot structures Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Reaction Rate and Chemical Equilibrium CONTENT STATEMENT Knowledge of the rate of a reaction and its equilibrium gives important information about chemical processes. Reaction rate can be fast or slow. The lower the activation energy, the faster the reaction Reaction rates and equilibrium can be controlled by changing concentration, pressure and temperature of the reactants and products. Catalysts speed up reactions by providing an alternative pathway with a lower activation energy. When a reaction is at equilibrium, the rates do not change. Le Chatelier’s principle explains what happens when a stress is put on a system already at equilibrium. . CONCEPTS Reaction Rates Chemical equilibrium VOCABULARY Thermodynamically stable Kinetically stable Reversible reactions Reaction rate Catalysts Inhibitor Rate determining step Reaction mechanism PERFORMANCE SKILLS: Distinguish between thermodynamic and kinetic stability List and describe factors that influence the rate of reaction Distinguish among heterogeneous and homogeneous catalysts and inhibitors Describe and determine reaction mechanisms for simple reactions Determine an equilibrium expression Use Le Chatelier’s principle to explain the effects of changes on equilibrium Calculate equilibrium constants and concentrations of reactants or products Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Solutions and Colloids CONTENT STATEMENT Systems containing more than one component are mixtures. Mixtures can be either homogeneous or heterogeneous. A solution is when a solute is mixed with a solvent. Different concentrations of solutions can be measured using molarity, molality, and percent concentration. All substances have different solubilities which are directly affected by temperature. Solubility depends on the chemical make up of both the solute and the solvent. Colligative properties depend only on the number of solute particles present. Colligative properties include freezing point depression, boiling point elevation and osmotic pressure. CONCEPTS VOCABULARY Solutions Colloids Vapor Pressure Changes Solvents Solute Dissociation Salvation Solution equilibrium Saturated solutions Unsaturated solutions Supersaturated solutions Suspension Tyndall effect Colligative property Raoult’s law Ideal solution Semi-permeable membrane Osmostic pressure Grade 10-12: Chemistry 2011-2012 Science Course of Study PERFORMANCE SKILLS: Describe and explain the process of solution formation Discuss factors that effect solubility Relate enthalpy of solution to endothermic and exothermic dissolving processes Solve problems involving molarity, molality, mole fraction and mass percent Distinguish, describe and characterize solutions, colloids and suspensions State Roult’s law and use to calculate the vapor pressure of solutions Explain how the process of fractional distillation can be used to separate components of a solution Identify the effects of solute particles on boiling point and freezing point of a solvent Explain the concept of osmotic pressure Calculate the effect of a solute on the boiling point, freezing point and osmotic pressure of a solution Determine the molecular mass of a solute from freezing point, boiling point or osmotic pressure data Relate the concept of ion activity to non-ideal solutions Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: The Mole CONTENT STATEMENT The mole is the amount of substance that contains as many atoms, molecules or ions as there are atoms in 12 g of Carbon-12. Avogadro’s number is equal to one mole. Molar mass is the formula mass of a substance expressed as grams. Percent composition of elements allows the empirical formula of a compound be determined. Hydrates contain a specific mole ratio of water attached to one mole of an ionic compound. Molarity of solutions is the number of moles of solute dissolved in 1 liter of solution. Specific molarities of solutions are necessary for most chemical reactions to take place. CONCEPTS VOCABULARY The mole and Avogadro’s Number Moles in solution Percent composition Hydrates Molecular and formula mass Avogadro’s constant Molar mass Molarity PERFORMANCE SKILLS: Use the Avogadro constant to define the mole and to calculate molecular and molar mass Use the molar mass to calculate the molarity of solutions, percentage composition and empirical formulas Determine the formulas of hydrates Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Oxidation and Reduction CONTENT STATEMENT Oxidizing and reducing (redox) reactions must take place simultaneously as the electrons involved move from one chemical species to another. Oxidizing agents accepts electrons while reducing agents donate electrons. All combustion reactions are redox reactions where the compounds burned are oxidized by oxygen. All humans and animals get their energy from respiration, where the oxygen in the air oxidizes carbon-containing compounds in cells. Metals oxidize to form either protective metallic oxides or destructive metallic oxides. Batteries store and release electrical energy utilizing redox reactions. CONCEPTS VOCABULARY Oxidation and reduction processes Balancing redox reactions Oxidation Reduction Reducing agent Oxidizing agent PERFORMANCE SKILLS: Compare the process of oxidation with the process of reduction Explain an oxidizing agent and a reducing agent Describe how to assign oxidation numbers to atoms in compounds State how to identify oxidation-reduction reactions Explain the concept of half-reactions Determine how to balance redox equations by the half-reaction method Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Nuclear Chemistry CONTENT STATEMENT Radioactivity energy emanating from the nucleus has major uses in the health and biological sciences. Nuclear energy is a major source of power in our modern world. Radioactive nuclides are capable of producing alpha particles, beta particles and gamma rays. Half-life is the time it takes for one half of any sample to decay. Half-life is important for dating historical and archeological artifacts. Nuclear medicine is the use of radionuclei for diagnostic imaging and therapy. Nuclear fusion releases massive amounts of energy and creates heavier elements. Nuclear fission is the combining of two nuclei to create heavier elements. This process takes place within stars and particle accelerators. CONCEPTS VOCABULARY Nuclear structure and stability Nuclear applications Isotopes Accelerator Fission Fusion Half-life Nuclear reactor PERFORMANCE SKILLS: Describe the operation of particle accelerators and fission reactors Describe the probing of the nucleus through the use of accelerators and reactors Apply three tests for relative stability of nuclides Explain the concept of half-life and write nuclear equations Explain how synthetic elements are produced List the biological effects of radiation and the units used to measure them Describe the uses of radioactive nuclides Describe fusion reactions and the ongoing research being devoted to controlling the fusion process Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Intermolecular Forces CONTENT STATEMENT The forces of attraction between molecules are intermolecular forces (IMFs). The strength of IMFs determine physical phases as well as solubilities. Dipole-dipole interactions are the strongest IMFs and exist between polar molecules. Hydrogen bonds are a specialized form of dipole-dipole interactions that contribute unique qualities to substances. London dispersion forces account for attractions between nonpolar molecules. CONCEPTS VOCABULARY Molecular attraction Chromatography Hydrogen bonding Polar covalent Dipole Intramolecular force Intermolecular force Chromatography Mobile phase Stationary phase Hydrogen bond Surface tension Capillary rise PERFORMANCE SKILLS: Distinguish between polar and non-polar covalent bonds Use electronegativities to predict polarities of bonds Compare the strengths of intermolecular forces based on dipole moments Define and describe the types of van der Waals forces and list the three factors contributing to them Define chromatography, mobile phase, and stationary phase Describe the uses for the different types of chromatography Use polarity to explain hydrogen bonding Explain the unique properties of water in terms of its molecular structure Explain surface tension and capillary rise on the basis of unbalanced surface forces Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Electrochemistry CONTENT STATEMENT Electrochemistry involves electricity-related applications of oxidation reduction reactions. Redox reactions that occur naturally can be sources of electrical energy. Electricity can drive redox reactions which do not occur naturally. An electrode and its electrolyte in an electrochemical cell make up half-cells. The potential difference between an electrode and its solution is the electrode potential. Standard electrode potentials are measured relative toa standard hydrogen electrode and indicate the relative strengths of substances as oxidizing and reducing agents. CONCEPTS VOCABULARY Cells Quantitative electrochemistry Salt bridge anode cathode electrochemical cell Volt Ampere electrode potential standard electrode potential reduction potenetial half-cell electrolytic cell electrolysis Voltaic cell PERFORMANCE SKILLS: Describe the construction and functioning of electrolytic and voltaic cells Compare electrolytic and electronic conduction Describe and use reaction cells Use the tables of standard reduction potentials Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Classification and Properties of Matter CONTENT STATEMENT Chemistry is the study of the composition, structure and properties of matter and its changes. All matter can be classified according its chemical and physical properties. Matter can be classified into elements, compounds, solutions and heterogeneous mixtures. Chemical changes involve a rearrangement of atoms whereas physical changes do not. The periodic table organizes the elements based on reoccurring properties and increasing atomic number. Energy changes accompany physical and chemical changes. CONCEPTS VOCABULARY Physical and chemical changes Physical and chemical properties Homogeneous and heterogeneous materials Elements and compounds Material Mixture Solution Solute Solvent Phase Interface Extensive physical properties Intensive physical properties Precipitate PERFORMANCE SKILLS: Describe and distinguish heterogeneous and homogeneous materials Describe and give examples of elements and compounds Classify examples of matter Classify changes in matter as chemical or physical Obtain information from a graph Distinguish among extensive and intensive physical and chemical properties Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Chemical Reactions CONTENT STATEMENT When atoms rearrange to form something new, a chemical reaction has taken place. Chemical reactions can be classified into five basic types where products are able to be predicted. Chemical reactions must be balanced so that the law of conservation of mass is observed. Chemical reactions can either consume or produce energy and this can be calculated using a balanced chemical reaction. CONCEPTS VOCABULARY Chemical Equations Stoichiometry Synthesis Decomposition Single and double displacement Combustion Reactants Products Percentage yield Mass-mass problems Mass-energy problems PERFORMANCE SKILLS: Write chemical equations to represent chemical reactions Balance chemical equations Differentiate among different types of chemical reactions Determine the mass of a reactant or product in a mass-mass problem Calculate the actual yield of product as a percentage of the theoretical yield Determine the heat of reaction for a chemical reaction using mass-energy problems Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Chemical Nomenclature CONTENT STATEMENT Naming and writing correct chemical formulas of atoms, compounds and molecules are important for the efficient communication of a chemical reaction. Ionic compounds are held together via electrostatic attraction and named by naming the cation first, followed by the anion. Binary molecules are held together by covalent bonds and named using multiplying prefixes. Oxidation numbers are the resulting charge on an element after electrons are lost or gained. Metallic ions with multiple oxidation states require Roman numerals in their name. Polyatomic ions are held together via covalent bonds and carry a charge that is the net sum of the oxidation numbers of the elements involved. CONCEPTS VOCABULARY Symbols and formulas Naming compounds Symbols Polyatomic ions Oxidation numbers Binary compounds Molecular formulas Empirical formulas Formula units PERFORMANCE SKILLS: Demonstrate proficiency in writing chemical formulas Define oxidation number and state oxidation numbers for common monatomic ions and charges for polyatomic ions Demonstrate proficiency for naming chemical formulas Distinguish between molecular and empirical formulas Demonstrate the use of coefficients Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Bonding Theory and Molecular Structure CONTENT STATEMENT Bonding occurs between atoms because it is an energetically favored physical state. The combination of bond types and atom order determine the overall shape of a compound. Atoms combine with each other in order to gain an octet of electrons in their valence shell. Valence-shell electron-pair repulsion (VSEPR) predicts bond angles and molecular shapes. An asymmetrical distribution of charge on a molecule contributes a degree of polarity. Metallic bonding is a result of delocalized electrons and this give metals characteristic properties, such as malleability and luster. CONCEPTS VOCABULARY Bond formation Particle sizes Molecular arrangements Ionic bonds Covalent bonds Metallic bonds Bond angle Bond length\ Bond axis Internuclear distance Van der Waals radius Shared and unshared pairs of electrons Delocalization VSEPR PERFORMANCE SKILLS: Identify the type of bonding between two elements Differentiate among properties of ionic, covalent and metallic bonds Use covalent radii to calculate bond length Use models to demonstrate the structure of molecules Grade 10-12: Chemistry 2011-2012 Science Course of Study TOPIC: Chemistry and the Chemistry Lab CONTENT STATEMENT The lab is an integral part of learning chemistry. Experimentation allows the students to see first-hand how manipulating variables directly affects the outcome. All equipment in the lab has a specific purpose and proper handling technique. Each piece of measuring equipment has its own precision which directly contributes to significant digits, accuracy and calculations. Safety rules must be followed at all times to ensure accidents are avoided. CONCEPTS VOCABULARY Lab Safety Measurements Equipment Scientific method The chemist Scientific processes PERFORMANCE SKILLS: Locate safety equipment and be able to use it. Read and follow directions. Listens and follows safety instructions Goggles Aprons Close-toed shoes Horse-play Metric system Significant digits Accuracy Precision Beakers Graduated cylinders Pipets Inquiry Theory Law Conclusions Experiment Research