* Your assessment is very important for improving the workof artificial intelligence, which forms the content of this project
Download 1 - Hatboro
History of chemistry wikipedia , lookup
Bent's rule wikipedia , lookup
Chemistry: A Volatile History wikipedia , lookup
Molecular Hamiltonian wikipedia , lookup
X-ray fluorescence wikipedia , lookup
Computational chemistry wikipedia , lookup
Metastable inner-shell molecular state wikipedia , lookup
Rutherford backscattering spectrometry wikipedia , lookup
Molecular orbital wikipedia , lookup
Atomic orbital wikipedia , lookup
X-ray photoelectron spectroscopy wikipedia , lookup
Biochemistry wikipedia , lookup
Stoichiometry wikipedia , lookup
Physical organic chemistry wikipedia , lookup
IUPAC nomenclature of inorganic chemistry 2005 wikipedia , lookup
Molecular dynamics wikipedia , lookup
Resonance (chemistry) wikipedia , lookup
Metallic bonding wikipedia , lookup
Periodic table wikipedia , lookup
Gas chromatography–mass spectrometry wikipedia , lookup
Extended periodic table wikipedia , lookup
Electronegativity wikipedia , lookup
History of molecular theory wikipedia , lookup
Photosynthetic reaction centre wikipedia , lookup
Molecular orbital diagram wikipedia , lookup
Chemical bond wikipedia , lookup
Electron configuration wikipedia , lookup
Hypervalent molecule wikipedia , lookup
1 Your chemistry final will be on _____________________________ Room # ________. The final begins at 10:00. You must bring the following with you or you will not be permitted to take the final: 2 #2 pencils calculator text book The following will be included on the final exam. The exam consists of a. 100 multiple choice questions b. 6 math problems worth a total of 100 points c. 2 essential questions to answer, worth 10 points each. You have your choice of two out of the 4 questions given. The topics of these questions are: Question 1 Hydrate lab, calculate percent water of hydrate, and analyze likely sources of error Question 2 Describeing atomic model changes over time Question 3 Significance of the mole Question 4 Significance of the periodic table in determining properties of atoms 2 Final Exam Sample Problems Sheet 1. An element has r has two naturally occurring isotopes: X-63 and X-65. The relative abundance of X-63 is 69.17%; the atomic mass of X-63 is 62.94 amu; the relative abundance of X-65 is 30.83%; the atomic mass of X-65 is 64.93 amu. (10 points) a. Determine the average atomic mass for X. You must show all of your work and include the units. b. What element is element “X” 2. You are given 0.551 g of ferric nitrite. (20 points) 1. Calculate the molar mass and percent composition of ferric nitrite. (5) 2. Calculate the number of moles of ferric nitrite in 0.551 g (5) 3. Calculate the number of molecules in 0.551 g of potassium ferricyanide(5) 3. Chemical analysis of citric acid shows that it contains 64.27% C, 7.19% H, and 28.54% O. a. What is its empirical formula? (10 points) b. If the molar mass of the molecular formula 168.19, determine the molecular formula of the compound (10 points) 3 4. The following questions refer to the molecule PCl3 a) Draw its Lewis structure (10 points) b) What is the name of the shape of the molecule (2 points) c) Is it polar or nonpolar? (2 points) d) What type of intermolecular force would occur between these molecules? (2 points ) e) Would the boiling point likely be low, medium or high for this compound?(2 points ) f) Name the hybridization that occurs on the central atom of this molecule (2 points) 4 5. Aluminum carbonate reacts with magnesium bromide Write the balanced equation for this reaction a. If 15.0grams of aluminum carbonate reacts with 46.0 grams of magnesium bromide, what is the limiting reagent? (10) b. How many grams of each product will be produced ? (5) c. What is the excess reagent? d. How many grams of excess reagent will remain ? (5) 6. (10 points) a. . What is the electron configuration notation for Zr ________________________ b. What is the shorthand notation for Pb ___________________________________ c. Write the orbital notation for S ________________________________________ 5 Other types of questions 1. Define matter 2. Distinguish between quantitative and qualitative data 3. Distinguish between intensive and extensive properties 4. Distinguish between a physical and chemical properties 5. Distinguish between endothermic and exothermic changes 6. List the 6 phase changes, determine which are endothermic and which are exothermic 7. Define solid, liquid, and gas 8. Distinguish between pure substances and mixtures 9. How many significant digits are in .005700 10. How many significant digits are in 240,000,100 11. Distinguish between accuracy and precision 12. Round .00980040 to 3 significant digits 13. Write 2.5 x 105 in standard notation 14. Write 450,300 in scientific notation 15. Write .005701 in scientific notation 16. (3.35 x 107) + (2.26 x 106) 17. (2.24 x 104) - (3.1 x 102) 18. (3.2 x 105) x (8.1 x 102) 19. (4.5 x 10-3) / (2.25 x 104) 20. Meaning of kilo? 21. If a substance has a mass of 3.2g and a volume of 8.7 ml. What is its density. 22. How do you convert from celsius to kelvin? 23. Where on the periodic table are the metals? Metalloids? Nonmetals? Nobel gases? 24. What is Dalton's atomic theory? 25. What is an atomic mass unit? 26. What is the law of Conservation of mass? 27. Describe Rutherford’s experiment and his model of the atom 28. What did Bohr find? 29. How are wavelength and frequency related? 30. What is an isotope? 31. How do you find how many grams of an element are in a mole? 32. How many atoms are in a mole? 33. What is an orbital? 34. What are quantum numbers? 35. What is: Hund's Rule, Pauli exclusion principle? Aufbau principle? Heisenberg uncertainty principle? 36. What happens to the frequency of light as its wavelength increases? 37. How manyelectrons are in the 1st energy level? 2nd energy level? 3rd? 4th? 38. How many orientations or sublevels do the following have: s____ p____ d____ f_____ 39. How many electrons can each of the following hold? S___ p____ d____ f____ 40. How did Mendeleev and then Mosely arrange the periodic table? 41. What are the alkali metals: alkaline earth metals transition metals: 42. What is ionization energy 6 43. What happens down a group and across a period for the following trends: Atomic radius: GROUP PERIOD Ionization energy: Electron affinity Shielding effect Electronegativity 47. Oxidation number of halogens: alkaline earth metals alkali metals 48. How many extra electrons does the slfate polyatomic ion have? 49. What are anions and cations? 50. What is the formula for triphosphorus pentoxide? 51. What is the formula for iron III sulfide? 52. What is a covalent bond? An ionic bond? 53. Know how to subtract electronegativities to find bond type (ionic, polar and nonpolar covalent) Ex: What kind of bond is between: H-F _____ O-O _____ Ca-Cl_______ (you will need to look up their electronegativities) 54. What is the octet rule? 55. What is the relationship between bond length and bond energy? 56. Use VSEPR theory to find the shapes of: O2 CCl4 CS2 PCl3 57. Are the above molecules polar or nonpolar? 58. Name the molecules from #56. 59. State the hybridization around the central atom that is occurring in each molecule in question 56. 60. Be able to determine if a reaction is SD, DD, COM, SYN, or DEC ( 6 questions) Forr the next questions, identify what type of reaction it is. Use the abbreviations S, D, SD, DD, AB, or C. 1. AgNO3 + NaCl NaNO3 + AgCl 2. F2 + 2 NaCl 2 NaF + Cl2 3. CH4 + 2 O2 CO2 + 2 H2O 4. 2 Mg + O2 2 MgO 5. HCl + NaOH NaCl H2O 6. H2O H2 + O2 Special Decompositions: What do the following decompose into: 7. Metal hydroxides 8. Metal carbonates 9. oxyacids 61. What do these symbols mean? (s)(aq) (ppt) 62. Be able to predict products if given reactants and balance. 63. What is the ideal gas law?