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History of the Atom Democritis - Ancient Greek Philosopher used the word Two discoveries led to the rebirth of the idea of the atom 1. Lavoisier 2. Proust (1799) This led to: John Dalton (1803) - 1 Dalton’s Atomic Theory 1. Each element is 2. All atoms of a given atom 3. Atoms are neither 4. A given compound always has the ATOM - The 2 1 Electrons Ben Franklin - Experiments with Michael Faraday - shows that William Crookes (1870s) – creates and experiments 3 J.J. Thompson Crookes used a Thompson (1897) was able to deflect the beam with 4 2 The Proton Thompson experimented with different gases in the tube and always Thompson then reversed the CRT and found the particle coming from the anode By doing careful measurements he was able to conclude that the electron was about 5 Models of the Atom If a particle gains or loses an electron it becomes Anion - Cation - 6 3 Oil Drop Experiment Robert Millikan (1909) measured the charge Millikan exposed oil droplets to X-rays. This caused the oil droplets to become Using the strength of the electric field, Millikan was able to Millikan was awarded the 7 Radioactivity Henri Becquerel - discovered Radioactivity - The spontaneous emmission of Much of the work to describe the three basic radioactive particles was done by 8 4 Radioactive Particles Radioactive Particle Alpha Beta Gamma Symbol Charge Mass (AMU) Characteristic Penetrating Ability 9 Rutherford’s Experiments 1909 - Ernest Rutherford used a material that emitted 10 5 Inside the Atom Most of the α-particles went 11 The Rutherford Atom Rutherford concluded that most of the atom was Around the nucleus, Rutherford thought the 12 6 The Neutron Neutrons were discovered by n n n 13 The Nuclear Atom Nucleus - Particle Symbol Relative Relative Actual Mass Charge Mass (amu) (g) Electron 9.11 X 10–28 Proton 1.67 X 10–24 Neutron 1.67 X 10–24 14 7 Atomic Number Atomic Number - is the number of The elements on the periodic table are organized In a neutral (uncharged) element, the number of Mass Number - is the # of Neutrons = 15 Isotopes Atoms that have the same number of Most elements have more than one isotope - Hydrogen has Hydrogen-1 has Hydrogen-2 has Hydrogen-3 has 16 8 Complete Isotope Symbols Y Z XH Where X= Y= Z= Hydrogen-1 Chlorine-35 Hydrogen-2 Hydrogen-3 17 More Isotope Examples 27Al +3 13 Protons Neutrons Electrons 127I –1 53 Protons Neutrons Electrons 197Au +2 79 Protons Neutrons Electrons 18 9 Nuclear Stability The stability of a nucleus depends on its neutron-to-proton ratio. Elements with atomic #s less than 19 Nuclear Stability 2 Nuclei with too many neutrons go through Just because an atom has gone through radioactive decay does not mean it is In addition to the spacing provided by the neutrons, the repulsive forces of the protons are overcome by the 20 10 Average Atomic Mass Atomic Mass Unit (AMU) Average Atomic Mass - The atomic mass of an element listed on the periodic table is a In order to calculate the average atomic mass of an element you must know: 1. The 2. The 3. The 21 Sample Problem #1 Boron has two naturally occurring isotopes. B-10 has an atomic mass of of the naturally occurring Boron. B-11 has an atomic mass of What is the average atomic mass of Boron? 22 11