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Group 1: Front right of the classroom Adam Brendan Stephen Sophie Lilly Alicia Taylor V Phoebe Group 2: Desks in the middle of the room Davis Kyle Haley Chrissy Eva Emily Tessa Shannon Group 3: Back of The classroom Nestor Ben Tyler Christine Brooke Taylor W Olivia Castro Smaller Groups Group A: Adam Eva Brooke Group B: Brendan Haley Christine Group E: Lilly Davis Taylor W Group F: Alicia Kyle Ben Group C: Stephen Emily Tyler Group G: Taylor V Shannon Olivia Group D: Sophie Tessa Nestor Group H: Phoebe Chrissy Castro Do Now • What do you think of when you hear the word metal? • What is a nonmetal? • Do you know of any examples of each? The Periodic Table consists of: • METALS • NONMETALS • METALLOIDS Properties of Metals • Metals are good conductors of heat and electricity • Metals are malleable (can be hammered or rolled into sheets) • Metals are ductile (can be made into wire) • Metals have high tensile strength • Metals have luster Examples of Metals Potassium, K reacts with water and must be stored in mineral oil Copper, Cu, is a relatively soft metal, and a very good electrical conductor. Examples of Metals Zinc, Zn, is more stable than potassium Mercury, Hg, is the only metal that exists as a liquid at room temperature Mixing metals • Alloy = mixture of a metal with another element, usually another metal • Alloys have properties different from the individual elements, usually eliminating some disadvantages. – Alloys are usually harder and more resistant to corrosion • • • • Ex: brass = copper + zinc Ex: sterling sliver = copper + silver Ex: steel = iron + carbon + manganese + nickel Ex: Stainless steel = iron + chromium Properties of Nonmetals • Carbon, the graphite in “pencil lead” is a great example of a nonmetallic element. • Nonmetals are poor conductors of heat and electricity • Nonmetals tend to be brittle • Many nonmetals are gases at room temperature Examples of Nonmetals Sulfur, S, was once known as “brimstone” Microspheres of phosphorus, P, a reactive nonmetal Examples of Nonmetals Graphite is not the only pure form of carbon, C. Diamond is also carbon; the color comes from impurities caught within the crystal structure Bromine is a nonmetal that exists as a liquid at room temperature. Properties of Metalloids • Metalloids straddle the border between metals and nonmetals on the periodic table. • They have properties of both metals and nonmetals. • Metalloids are more brittle than metals, less brittle than most nonmetallic solids • Metalloids are semiconductors of electricity • Some metalloids possess metallic luster Silicon, Si – A Metalloid Silicon has metallic luster Silicon is brittle like a nonmetal Silicon is a semiconductor of electricity Other metalloids include: Boron, B Germanium, Ge Arsenic, As Antimony, Sb Tellurium, Te Elements classified as metals and nonmetals http://www.ptable.com/ Do Now • Take out your Reference Table and open to the Periodic Table of Elements • Do you notice any patterns as you look at the properties of elements? – Hints: scan left to right, and scan from the top down The Periodic Table • PERIODIC LAW – The physical and chemical properties of the elements are periodic functions of their atomic numbers (elements with similar properties appear at regular intervals). • THE MODERN PERIODIC TABLE – An arrangement of the elements in order of increasing atomic number so that the elements with similar properties fall in the same column or group. Periodic Table with Group Names PERIODS= Horizontal rows GROUPS= vertical columns VALENCE ELECTRONS • Elements within the same group have the same number of valence electrons. VALENCE ELECTRONS • Most loosely bound electron is called the VALENCE ELECTRON! • Valence electrons participate in chemical reactions, so elements with similar valence electrons react in similar ways. • Noble gases are stable with 8 valence electrons. • All elements with the exception of Hydrogen and Helium want 8 valence electrons to be stable. • Hydrogen and Helium want 2 valence electrons to be stable. GROUP 1 Alkali Metals • Properties: – – – – – – – – Metal Easily lose valence electron 1 valence electron Chemically reactive – do not occur as free elements in nature Soft, silvery Good conductor of electricity React violently with water React with halogens to form salts EXCEPTION: Hydrogen is in group 1, but has different properties than the alkali metals Hydrogen • Most common element in the universe. • It consists of one proton and one electron. • It can react with many other elements: – With oxygen to make water – With carbon to make organic compounds – With nitrogen to make ammonia GROUP 2 Alkaline Earth Metals • Properties: – They are metals, but have less metallic characteristics than Alkali Metals – 2 valence electrons – Chemically reactive – do not occur as free elements in nature – Harder, denser, stronger, higher boiling points, and slightly less reactive than alkali metals GROUP 17 Halogens (“Salt makers”) • Properties: – Most reactive nonmetals. – 7 valence electrons – need 1 electron to become stable – They vigorously react with metals to form salts. • • • • F2 - most reactive element Cl2 Br2 I2 GROUP 18 NOBLE GASES (or INERT GASES) • Properties: – Full set of valence electrons: most elements have 8 valence electrons, except Helium with 2 valence electrons, but it is still associated with this group because its properties match these elements. – Extremely stable and occur as monoatomic gases in nature – Although they do not readily combine with other elements, but compounds of Krypton and Xenon have been prepared. Monoatomic Atoms • All of the noble gases are monatomic. • Monatomic means it only contains one atom of the element. • • • • Transition Metals (d-Block) They have “typical metallic properties” Luster, ductile, malleable, good conductors of heat and electricity Less reactive than Group 1 and 2 Many are unreactive (for example, palladium, platinum and gold are found as pure elements in nature) • As ions, the transition elements form colorful solutions. • These elements begin in Period 4 and include Groups 3-12. Lanthanides and Actinides (f-Block) • Lanthanide Series- shiny metals similar in reactivity to Alkaline Earth Metals • Actinides Series- all radioactive (mostly synthetic) Magic seven • Diatomic molecules= always exist as 2 of the same atoms bonded to each other H2 N2 O2 F2 Cl2 Br2 I2 Liquids on the Periodic Table • There are 2 liquids on the periodic table at STP • Mercury is the only metal that is a liquid • Bromine is the only nonmetal that is a liquid Allotropes • An allotrope is the same element that can be found in more than one different form – Graphite and Diamond are allotropes of Carbon – Dioxygen (O2)and Ozone are allotropes of Oxygen Color-Code the Periodic Table • You can use any colors you want, just make a key on your personal periodic table • On your personal periodic table color the following, every bullet has to be a different color: – Metalloids (on the staircase- 6 of them) – The 2 liquids (Mercury and Bromine) – The 7 Diatomics – Noble Gases – Transition Metals – Color and Label groups 1,2,17, and 18 with the proper name Stephen Eva Christine Tessa Ben Tyler Castro Brooke Davis Sophie Brendan Chrissy Emily Lilly Alicia Olivia Kyle Adam Shannon Taylor V Phoebe Taylor W Haley Nestor Liquids on the Periodic Table • There are 2 liquids on the periodic table at STP • Mercury (Hg) is the only metal that is a liquid • Bromine (Br) is the only nonmetal that is a liquid Allotropes • An allotrope is the same element that can be found in more than one different form – Graphite and Diamond are allotropes of Carbon – Dioxygen (O2)and Ozone are allotropes of Oxygen Periodic Trends • • • • • • • ELECTRONEGATIVITY –Straws Lab ATOMIC RADIUS- Pipe Cleaners/Bead IONIC RADIUS IONIZATION ENERGY- Straws Lab ELECTRON AFFINITY METALLIC CHARACTER MELTING AND BOILING POINT The trend depends on 3 factors: 1. NUCLEAR CHARGE= atomic number= # of protons- the higher the nuclear charge the more the electrons are pulled toward the nucleus. 2. PRINCIPAL ENERGY LEVEL- Principal energy level is determined by the period an atom is located; the higher the principal energy level, the higher the potential energy, the larger the atom. 3. ELECTRON CLOUD SHIELDING EFFECT- inner electrons shield the outer electrons so they are less attracted to the nucleus so the atom is larger Electronegativity • A measure of the ability of an atom in a chemical compound to attract electrons. • FLUORINE is the most electronegative atom on the Periodic Table • PERIOD TREND: Electronegativity increases across a period (the closer to 8 valence electrons the more they will pull on the electrons) • GROUP TREND: Electronegativity decreases down a group (the larger the atomic radius the less ability of that atom to attract electrons due to electron shielding) Periodic Table of Electronegativities Electronegativity Review • Element with most Electronegativity: • Fluorine (F) • Element with least Electronegativity: • Francium (Fr) Atomic Radius • Atomic radius = half of the distance between nuclei of identical atoms bonded together (bond radius). • This is determined by how strongly an atom’s nucleus (positive charge) is attracted to its outermost electrons. • PERIOD TREND: Radius decreases across a period • Nuclear charge increases across a period so electrons are more closely attracted to the nucleus • GROUP TREND: Radius increases down a group • Addition of principal energy levels, so inner electrons shield outer electrons and the electrons are farther away from nucleus, so atom is larger. Table of Atomic Radii Review Ions • Ions are formed when atoms gain or lose electrons • Ions have a positive or negative charge • Ionic Radii: The loss or gain of electrons by an atom causes a corresponding change in size. Ionic Radii Cations • Positively charged ions • Smaller than the corresponding atom • Metal tend to form CATIONS by LOSING an electron. • Metal cations are smaller than their corresponding neutral atoms (they lost electrons). Anions • Negatively charged ions • Larger than the corresponding atom • Nonmetals tend to for ANIONS by GAINING an electron. • Nonmetal anions are larger than neutral atoms because they gained electrons. Ionic Radius Review • The loss or gain of electrons by an atom causing a corresponding change in size. Metals • Tend to lose their valence electrons. • What happens to their valence electrons? decrease Before: After: • Therefore the atomic radius of metals is larger than their ionic radius. Ionic Radius Review • The loss or gain of electrons by an atom causing a corresponding change in size. Nonmetals • Tend to gain electrons. • What happens to their radius? increases Before: After: • Therefore the atomic radius of nonmetals is smaller than their ionic radius. Table of Atomic Radii and Ionic Radii Ionic Radius Metals form CATIONS Loss of electron Get a Positive Charge Nonmetals Form ANIONS Gain of electron Get a Negative charge Radius Decreases when it becomes an ion Radius Increases when it becomes an ion Ionization Energy • Ionization energy = the energy required to remove an electron from an atom A + ionization energy A+ + e• PERIOD TREND: Tends to increase across a period – Within same principle energy level: due to increased nuclear charge the electrons are more closely attracted to nucleus • GROUP TREND: Tends to decrease down a group – Addition of principle energy levels, so outer electrons are farther from the nucleus due to electron shielding, so less attracted to the nucleus Ionization of Magnesium • Ionization energy increases for successive electrons taken from the same atom Mg + 738 kJ Mg+ + eMg+ + 1451 kJ Mg2+ + eMg2+ + 7733 kJ Mg3+ + e- Ionization Energy Review • Element with the most Ionization Energy: • Helium (He) • Element with the least Ionization Energy: • Cesium (Cs) • Why do noble gases have such high ionization energy but no electronegativity? Electron Affinity- Similar to Electronegativity • The energy change that occurs when an electron is acquired by a neutral atom is called the atom’s electron affinity. A + e- A- + energy A + e- + energy A- (unstable) • PERIOD TREND: Tends to increases across a period – due to increasing nuclear charge (remember: the Halogens gain electrons most readily) • GROUP TREND: Tends to decrease down a group – due to increasing electron shielding from addition of principle energy levels REACTIVITY • METALS- most reactive in lower left corner • NONMETALS- most reactive in top right corner Reactivity Review: • Place the following elements in increasing order of reactivity: (least reactive first) – Sodium, potassium, calcium Metallic Character • As you go down a group, the metallic character increases. • As you go across a period, the metallic character decreases. (Because they are nonmetals) Summation of Periodic Trends- Add them to your Periodic Table Electronegativity Electronegativity Periodic Trends Definition Trend in Period Electronegativity The measure of Increases across the ability of an a period atom in a chemical compound to attract electrons Trend in Group Decrease down a group Atomic Radius Half the distance Decreases across Increases down a between nuclei a period group of identical atoms bonded together Ionization Energy The energy required to remove an electron from an atom Increases across a period Decreases down a group