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Notes on Atoms and Molecules Law of Chemical Combination Law of conservation of mass- Mass can neither be created nor destroyed in achemical reaction. A+B=C+D Mass of Reactants = Mass of Products Law of constant proportions- According to law of constant proportions, in a chemical substance, the elements are always present in definite proportions by mass. Dalton’s Atomic Theory Dalton’s observations: Matter is made of atoms. Atoms are indivisible and indestructible. Atoms of a given element are identical in mass and in properties. Compounds are formed by a combination of two or more different kinds of atoms and. A chemical reaction is a rearrangement of atoms. Atoms of different elements have different masses and chemical properties. Atom- Atoms are the smallest particles of an element which can take part in a chemical reaction Size of an atom : 1nm = 1/109 m Symbols of common element: Carbon is represented as C Boron as B Oxygen as O Sulphur as S Nitrogen is written as N and Hydrogen as H Symbols of some elements were the first two alphabets, where the second alphabet is in the lower case. Examples: Aluminum is represented as Al Chlorine as Cl. Atomic mass- Atomic mass is the mass of an atom.The relative atomic mass of an atom of an element is the number of times an atom of that element is heavier than 1/12th of the mass of a carbon-12 atom. Molecule- A molecule is the smallest particle of an element or compound that can exist independently. Examples: H2O, O2, O3 etc. Single Hydrogen is not a molecule. When this hydrogen bonds to other hydrogen (H2) or to other elements like oxygen (H2O), a molecule is formed. Atomicity: The number of atoms constituting a molecule is referred to as atomicity. A molecule which contains only one atom is called monatomic Example: Noble gases like Helium (He), Neon (Ne), Argon (Ar) etc. A molecule which contains two atoms is called diatomic Example: Hydrogen (H2), Chlorine (Cl2), Nitrogen (N2) etc. Valency: The combining capacity of an element is known as valency. The combining capacity of the atoms to form molecules either with same or different elements is defined as valency. Atom contains less than four electrons in its outermost shell; the valency of an atom is equal to the number of electrons present in the valence shell. Example: Sodium has one electron in its outermost shell, so the valency of sodium is 1. Calcium has two electrons in its outermost shell, so the valency of calcium is 2. If the outer shell has more than four electrons, the valency = 8 - the number of electrons in the outer shell. Ions- The charged particles are called ions, they are formed by attaining positive charge or negative charge on it. A positively charged ion in a molecule is called cation. An anion is a negatively charged ion in a molecule. Chemical Formula Steps for writing the formula of simple compound like H2O is: Write the symbols of the constituent elements. Write the valencies of each element below its symbol. Criss cross the valencies of the constituent elements and place as the subscripts to get the desired formula. Example : Water Molecular Mass- It’s the sum of atomic masses of all atoms in a molecule in a molecule of a substance Mole Concept- The mole is the amount of a substance that contains as many elementary entities as there are atoms in exactly 12 grams of 12C 1 mole = 6.022 x 1023 in number