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Transcript
Annexure ‘CD-01’
Course Title: SUBSIDIARY CHEMISTRY-II
Course Code: CHEM113
Credit Units: 4
Level: Under Graduate
L
T
P/
S
SW/F
W
TOTAL
CREDIT
UNITS
2
1
2
0
4
Course Objectives:
Chemistry is essential to develop analytical capabilities of students, so that they can characterize, transform and apply knowledge in their field. All other fields of science
have unique bonds with chemistry whether it is physics, mathematics or statistics. The makeup of substances is always a key factor, which must be known. With this versatile
need in view, course has been designed in such a way so that the student should get an overview of the whole subject, starting with the basics in the first semester and
advances topics in the second semester.
Prerequisites:
Basic knowledge of chemistry upto Std XII
Course Contents/Syllabus
Module I Organic chemistry-II




Types of organic reactions;
Substitution ,
Elimination,
Addition including both aliphatic and aromatic reactions.
Module II Coordination compounds







Weightage
(%)
30
Complex salts, ligands and their types,
coordination number,
Werner’s theory, EAN, Nomenclature,
Factors affecting stability,
Experimental determination of composition of complexes and stability constant,
Isomerism,
VBT in complexes.
30
Module III Chemical kinetics





Module IV Chemical equilibrium






Introduction ; Le Chatelier’s Principle;
Equilibrium constant from Thermodynamic Constants;
Acid-Base Concept; Weak acid and Weak base and their salts;
Solubility Product;
pH and pOH,
Buffer Solution, Buffer Action.
List of experiments
1. To determine the number of water molecules of crystallization in Mohr’s salt (ferrous ammonium sulphate) provided
standard potassium dichromate solution (0.1N) using diphenylamine as internal indicator.
2. To determine the ferrous content in the supplied sample of iron ore by titrimetric analysis against standard K 2Cr2O7
solution using potassium ferricyanide [K3Fe(CN)6] as external indicator.
3. (a) To determine the surface tension of a given liquid by drop number method.
(b) To determine the composition of a liquid mixture A and B (acetic acid and water) by surface tension method.
4. Determination of viscosity of ethyl acetate using ostwald’s viscometer.
5. Separation of mixture of dyes with paper chromatography.
6. To prepare and describe a titration curve for phosphoric acid – sodium hydroxide titration using pH-meter.
7. Determination of kinetics of hydrolysis of ethyl acetate by NaOH.
8. Inorganic Preparations:
i) Sodium tetrathionate
ii) Preparation of potash alum
iii) Cuprous Chloride
Student Learning Outcomes:





20
Reaction velocity, factors affecting, rate constant,
order and molecularity of reaction,
ero, first, second and third order reactions with examples and numericals,
Arrhenius equation,
Theories of reaction rate
The student will be able to master a broad knowledge in the field of chemistry.
The students will be able to apply their knowledge of organic chemistry, kinetics to their relevant areas of study
The will understand the formation of coordination compounds
They will be able to analyse the factors affecting the equilibrium process
They will be able to apply their theoretical knowledge and also demonstrate it practically through experiments
20
Pedagogy for Course Delivery:
The class will be taught using theory and experiments. A number of assignments will be given to understand the topic better.
Assessment/ Examination Scheme:
Theory Assessment
Continuous Assessment/
Internal Assessment
HA
S/V/Q CT
AT
75% 07
Practical Assessment LR
25% 5
08
P
10
10
V/Q
10
05
AT
05
End Term
Examination
EE
-
TT
70
EX
35
100
TP
100
Viva
35
Total
Abbreviations:
CT – Class Test, S- Seminar, V- Viva, Q- Quiz, HA- Home Assignment, TT- Total Theory
LR- Lab record, EX-Experiment, P – Performance, TP- Total Practical
The total marks (out of 100) shall be the weighted average of TT and TP in the ratio of theory and lab credit units i.e.
3:1
Text and References:
1. “A New Concise Inorganic Chemistry”, J. D. Lee, 5th Edition (1996), Chapman & Hall, London.
2. “Basic Inorganic Chemistry”, F. A. Cotton, G. Wilkinson, and Paul L. Gaus, 3rd Edition (1995), John Wiley & Sons, New
York.
3. “Organic Chemistry”, R. T. Morrison and R. N. Boyd, 6th Edition (1992), Prentice-Hall of India (P) Ltd., New Delhi.
4. “Organic Chemistry”, S. M. Mukherjee, S. P. Singh, and R. P. Kapoor, 1st Edition (1985), New Age International (P) Ltd.
Publishers, New Delhi.
5. “Principles of Physical Chemistry”, B. R. Puri, L. R. Sharma, and M. S. Pathania, 37th Edition (1998), Shoban Lal Nagin
Chand & Co., Jalandhar.
6. “Physical Chemistry”, K. J. Laidler and J. M. Meiser, 3rd Edition, Houghton Mifflin Comp., New York, International
Edition(1999).
7. Experiments in Applied Chemistry, Dr. Sunita Rattan, S.K. Kataria & Sons, Delhi.
8. Advanced Practical Physical Chemistry, J.B. yadav, Goel Publishing house, Meerut
9. Advanced Practical Inorganic Chemistry, Gurdeep Raj, Krishna Prakashan Media(P) Ltd.
Remarks and Suggestions:
_______________________________
Date:
Name, Designation, Organisation