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Welcome to chemistry Science a search for facts about the world around us understanding the past , predicting the future Aristotle (384-322 B.C.) one can work out all the laws that govern the universe by pure thought Roger Bacon (1300’s) science should base its reasoning on experimental evidence. science replaces philosophy science A procedure for processing and understanding certain types of information If there is no test for its possible “wrongness”, then it is not scientific. The Scientific Method Experiment Hypothesis Observation Theory Law The Scientific Method Experiment Hypothesis Observation Theory Law click on any underlined word for its definition Science and Technology science is a method of answering theoretical questions technology is a method of solving practical problems. chemistry The study of matter, its structure, properties, composition and changes that matter undergoes. Chemists are problem solvers Problem: the paper in 40% of old library books is crumbling how to preserve the crumbling books paper is made from cellulose cellulose is formed from long chains of glucose (C6H12 O6) Al2(SO4)3 is used to prevent ink from “fuzzing” Al3+ ions interact with water to form Al (H2O)6 3+ an equilibrium is established producing H+ ions H+ ions destroys cellulose ie: crumbling paper Al (H2O)6 3+ [Al(OH) (H2O)5] 3+ + H+ remove H+ stop the crumbling add a base remove the acid Add NaOH(aq) H+ + OH- H2O we are left with wet paper Add NH3(g) H+ + NH3 NH4 + as the pressure is reduced NH3(g) leaves, shifting the equilibrium producing more H+ H+ (aq) + NH3 (g) NH4 + (aq) the solution to the problem is only temporary adding (C2H5)2 Zn(g) (C2H5)2 Zn(g) + H2O diethyl zinc ZnO (aq) + 2 C2H6 2H+ (aq) + O2- (aq) H2O thus ZnO is a nonvolatile base that can placed on paper by a gaseous substance Classifications of Matter Matter is anything that occupies space and has mass. mass - a measure of the quantity of matter Volume - space Matter We define matter as anything that has mass and takes up space. © 2012 Pearson Education, Inc. Matter And Measurement Matter • Atoms are the building blocks of matter. • Each element is made of the same kind of atom. • A compound is made of two or more different kinds of elements. © 2012 Pearson Education, Inc. Matter And Measurement Matter Homogeneous mixtures Compounds Mixture Substance Heterogeneous mixtures Elements Matter Homogeneous mixtures Compounds Mixture Substance Heterogeneous mixtures Elements click on words for definitions Physical and Chemical Properties of Matter Properties A set of characteristics by which a substance can be recognized Physical property can be measured and observed without changing the composition or identity of a substance Chemical property requires a chemical change in order to be observed Extensive property depends on amount of material; mass and volume are examples of extensive properties Intensive property does not depend on amount of material; density and temperature are examples of intensive properties Types of Changes • Physical Changes – These are changes in matter that do not change the composition of a substance. ◦ Changes of state, temperature, volume, etc. • Chemical Changes – Chemical changes result in new substances. ◦ Combustion, oxidation, decomposition, etc. Chemical Reactions In the course of a chemical reaction, the reacting substances are converted to new substances. © 2012 Pearson Education, Inc. Matter And Measurement Separation of Matter Filtration In filtration, solid substances are separated from liquids and solutions. © 2012 Pearson Education, Inc. Matter And Measurement Distillation Distillation uses differences in the boiling points of substances to separate a homogeneous mixture into its components. © 2012 Pearson Education, Inc. Matter And Measurement Chromatography This technique separates substances on the basis of differences in solubility in a solvent. © 2012 Pearson Education, Inc. Matter And Measurement Periodic Table of the Elements Chemical Symbols abbreviations for the names of the elements the first letter is always capitalized O, Al, C, Cl, H, He……. An elements position on the periodic gives indications of its various physical and chemical properties Main groups group numbers indentified by suffix A Main group metals Alkali metals Alkaline earth metals Nonmetals Halogens Noble gases Lanthanides transition metals Actinides Lanthanides transition metals The Three States of Matter solid liquid gas solid liquid gas (slides that follow are linked to earlier ones) law a concise verbal or mathematical statement of a relationship between phenomena that is always the same under the same conditions theory a unifying principle that explains a body of facts and those laws that are based on them hypothesis a tentative explanation for a set of observations leads to “if… then…” questions test of theory a substance is form of matter that has a definite or constant composition and distinct properties, for example water ammonia table sugar gold oxygen a mixture is a combination of two or more substances in which the substances retain their distinct indentities, for example air milk the composition of a homogeneous mixture is the same throughout, for example copper (II) sulfate dissolved in water a mixture of nonuniform composition is a heterogeneous mixture, for example granite Sand and iron filings an element is a substance that cannot be separated into simpler elements by chemical means a compound is a substance composed of atoms of two or more elements chemically united in fixed proportions