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Getting Started in AS Chemistry Chemistry is a fun subject. Now that you’ve chosen to study chemistry in more depth, you may be feeling rather unsure about starting your AS chemistry course. This is understandable – it’s a new beginning and we all feel a bit insecure about those! However, you will be surprised at how much you already know from your GCSE studies, and it’s this knowledge that is built upon during the AS course. So, it’s important that you remember your GCSE work; it may be prudent to revise your GCSE studies before starting your AS course – then you’ll be ready for your new and exciting course. The following invaluable advice will show you how to work through the AS chemistry course and, crucially, how to attain a rewarding grade. What is the AS chemistry course like? You may have glanced through the specification of your AS chemistry course and many parts of it, particularly topic titles, may already seem familiar to you. The OCR AS chemistry course has been outlined for you below. How many of the words and terms can you recognise from your GCSE science courses? 1 The enjoyment factor Remember, you have chosen to study chemistry for a reason. You may be good at it, you may like carrying out experiments or you may find the background theory interesting – whatever your reasons, do enjoy your work. As with most things in life, you get out what you put in! What are the main differences between GCSE and AS chemistry? As we have already discussed, many of the areas covered at AS level are similar, if not the same, as those covered at GCSE. Furthermore, if you decide to study chemistry or chemistry-based courses at University, you will find the same pattern. However, it is essential that you realise that studying AS chemistry is more challenging than GCSE chemistry; it is more testing in a variety of ways. The main difference is the way in which you think – from studying chemistry to becoming a chemist! • You will need to raise your thinking level Many of the ideas covered at GCSE may have come quite easily to you and consequently you did not need to work hard at trying to understand them. At AS level you may find more areas that challenge you, so be prepared to work harder at furthering your understanding. This will require patience, but will pay dividends when you crack it and your marks start improving. Making sure you go over concepts you’re not sure about, reworking notes or using other information sources are all areas that may help you understand these new ideas. • There will be more facts to recall During your GCSE courses you were required to recall certain facts during examinations and this number increases at AS level. Whether it be the formula for sodium hydroxide or sulfuric(VI) acid, or knowing a particular use for chlorine, you will be expected to know these facts and many more besides. This should not come as a great surprise, since we know the AS course is more challenging than a GCSE one. So, remembering your chemistry facts is a key area at this level. • The amount of chemistry increases During your AS course you will become more involved in the chemistry experience. Chemistry has its own language or codes, for example, chemical formulae and equations. In order to develop a greater understanding of chemistry 2 at this higher level, more of the serious ideas that chemists use in their work will be explored during your AS course. Think of it as learning a new language – chemists use concepts and ideas understood by other scientists. You will become familiar with these throughout the course and it is important that you become confident in using this language, especially chemical equations, since this is how chemists represent chemical reactions. If you’re a bit rusty on these it may be wise to revise some of your GCSE chemistry before you start your AS course. Another area that may benefit from a revisit is chemical calculations, for example the mole – find appropriate problems to see if you can do the calculations. Chemical structure and bonding is a topic also worth revisiting – even good AS level students can find it difficult to explain why molten ionic compounds conduct electricity! It’s important to use the appropriate words in the correct context. Is the question referring to atoms, molecules, ions or electrons? Are you going to discuss electrostatic forces between ions to explain your answer or intermolecular forces between molecules? It is important to realise which terms to use in which context. Of course, you may find, as many do, that things just click into place once you start your new course. • There will be a greater expectation of your advanced skills For example, your skills in applying what you know to unfamiliar areas will be assessed in examinations. This is an area that many students find daunting at first. You may only have experienced examinations that test what you have been taught and know. However, as you progress through higher educational levels examinations will begin to test your ability in applying your understanding to unfamiliar areas. In our case, for example, the chemistry of ant stings, sun creams, poisons and pharmaceuticals. You may find this difficult at the beginning, but as you practise questions you will find it becomes easier and your marks will improve. As with anything we’re unfamiliar with patience and dedication help us get it right in the end! It is also important to be able to discuss areas from other modules throughout the AS and A2 specification. You will need to apply AS ideas and contexts covered in the first AS module to other modules both at AS and A2 levels. So try not to box things up and forget them, because you will need to revise all key areas before you sit the rest of your papers. • There is a greater emphasis on practical skills You will already have carried out chemistry experiments, often a part of the course that many students enjoy. You may be used to being assessed in your practical work during your GCSE course, and this may have counted towards your final grade. It will be the same during your AS course. Again you will be asked to carry out various experiments, but this time you will be expected to 3 think about these experiments at a higher level than previously. As with GCSE, you will have plenty of practice in this vital area and your practical skills will improve as you gain in confidence. You can use the 'Build Your Practical Skills' section of this CD to help you as well. Remember that the practical assessment component is worth 20% of your total grade – this is worth a couple of grades, so recognise the importance of your practical components! To summarise: Deeper THINKING regarding new concepts and proper PREPARATION in how you work within your AS course – get these right and success should follow. Using a different approach at AS level This is probably the most important concept for success in your AS chemistry course. Remember that you need to earn your success – it does not just happen! However you decide to work throughout the course, the biggest challenge can be sticking to your work routine for the whole academic year. At GCSE you achieved success by revising and preparing well for tests and exams; the same is true at AS. However, there is more to learn and there are more ideas to understand, so it is important that you not only work hard for the tests but develop a work routine that you stick to throughout the course. • When can you work? We all have days in which we are busy at certain times and free at others. Whenever you are free, you must learn to work smart and make the most of your free time. If you make sure that it becomes a regular occurrence, i.e. a habit, you will develop a routine way of working. It is always easy to put off work – everybody does it! However, if you timetable your AS chemistry work you will find it easier to stick to a plan that works and thus continues. For example, you may be free on Monday, Wednesday and Friday evenings from 7 to 9 o’clock, so you timetable the AS chemistry work you’ve been set for this free time. But if you have enough time you could also do extra work – the work that really makes a difference. Successful students are those who develop a work routine in their own time, so they are able to enhance their learning. This is independent learning. 4 • How do you work throughout the course? This may seem a strange question – surely the fact that you are working harder will automatically make a difference? Well, this is not always the case; you may have been unable to find a method that works or you could have improved the way you worked. Many students revise by reading a textbook and assume that they will magically get better results. Why not reflect on how you worked and revised at GCSE – do you think that it is a method that is right for you? Was it an interesting way to work? Did you feel engaged with the material? It isn’t easy to sit on your own and work through the AS chemistry course without finding some of the work difficult. You must try to make your work routine as interesting as possible by engaging with the work. How many times have you read a page from a textbook and after a few minutes can’t remember anything you’ve just read? Don’t worry, this is very common! However, you may find that when you go shopping, just by writing a list of the required items is enough to remember them by – you often don’t need to refer to your list at all! What does this everyday example reveal about the way in which we learn? You must make your learning as interactive as possible and do as much as you can with the information that you are trying to remember Most people learn about 10% of what they hear, about 20% of what they read, about 60% of what they read and write and about 80% of what they read, write and say! As a teacher myself, I discovered that I only understood something when I had to explain it to someone else. It is easy to fall into the trap of thinking that we understand something well once we’ve worked on it; however, try to explain it to someone else and you may be unpleasantly surprised! If you have a friend who is also studying AS chemistry try to pair up while revising and test and explain concepts to each other. This approach works really well and can be highly motivating. So, work smart, don’t just work! • How do you remember facts? During your AS chemistry course you will come across many more facts and you must find a way to remember them. Unfortunately, there is no single method for remembering these facts that works for all students; you must find a method that works for you. Remember, that the more you do with the information, the more likely you are to remember it. For example, how to learn the AS organic 5 reactions of alkenes? What reactions do you need to know? This is where your AS specification will come in handy. Consult it to find out which reactions are important, i.e. reactions with hydrogen, hydrogen bromide, bromine, steam and polymerisation. Now, how to remember them: (a) Writing and blanking out This method works for some students, but not all. Firstly, copy the reactions from your notes. Now cover them and see how many you can rewrite correctly from memory. There may not be as many as you first thought! Look at your notes again and repeat the process. You will find that by practising this process you will start to remember more of the reactions. It may seem hard work initially, but it will be worth it in the long run. To reinforce your memory you should re-test yourself the following day to see how much you can remember. Re-test again three days later and again after seven days. Increasing the time difference between the tests will aid your long-term recall. (b) Using coloured pictures When information is presented in sentence form it is not always easy for the brain to process and remember. Presenting the information in different and more interesting ways may aid you in remembering it. For alkene reactions you could draw a spider diagram using a different colour for each reaction. Sticking this coloured diagram on your wall will also help you remember the information as you’ll see it every day, rather than it being tucked away in a file. You may find that the position of each reaction on the paper, along with its unique colour, makes it easier for you to remember. (c) Sharing your information As mentioned earlier, it is also helpful if you can pair up with a fellow AS chemistry student or a family member and test each other. For instance you could test each other on: (i) the structure of a propene molecule; (ii) the structure of the product(s) formed when propene reacts with hydrogen with a nickel catalyst; hydrogen bromide; or bromine. Try using flashcards and draw a molecule’s structure with its name on the reverse, then try to work out the molecule’s name. Your aim is to score more than 8 out of 10! Make it a challenge – aim for something that may motivate you, for example, a personal best score on naming alkenes or for working out reaction products. 6 • Why not use previous examination papers? These are available from OCR or your teacher, as s/he will have access to them. However, make sure that you are using papers that are appropriate for your course since courses may vary in content, and if your course is new very few appropriate papers may exist other than specimen papers. The Exam Cafe CD has example questions and answers that you can practise on and that will help improve your understanding of the chemical concepts. You can see how you do by using the mark schemes provided. When you’re comfortable with your AS chemistry knowledge, it is essential that you test your understanding by trying some AS questions, just a few at a time. Don’t forget, your marks will improve as you practise more questions. Try and ensure that you have access to an examiners’ mark scheme – this shows what the examiner is looking for. Sometimes mark schemes have their own unique criteria, for example, in the definition for le Chatelier’s principle – different examination boards may expect slightly different definitions. So ensure you know what OCR requires and don’t just go by the definitions you find in general texts. Hopefully you should now have surmised that it is important to practise – grades do not just happen, they are earned. Successful students practise questions to see whether they understand as well as know their chemistry – they are genuinely concerned with their progress. Furthermore, the natural emphasis at AS level is more on the student than it was at GCSE, so try and do some extra chemistry work each week – a type of drip-feed approach which you routinely stick to throughout the course. The result will be a grade that you can be proud of and, perhaps more importantly, help you progress to A2. However, remember that whilst you are working hard you should also try to analyse how you are working. Work as effectively as you can in the time available and ensure your extra work makes a real difference. 7 My action plan What I need to do to make sure I am ready for my AS studies • What do I already know? • What are my strengths and weaknesses? • What do I need to do before my AS course starts? 1. Make notes/ show evidence of the following: Revise ionic/covalent/metallic bonding and structures Revise writing and balancing chemical equations Revise atomic structure and electron configuration Revise mole calculations 2. Complete the following numeracy tasks 8 AS Chemistry transition numeracy tasks 9 a) Calculating Relative Masses The relative atomic mass (Art) of an atom is shown in the periodic table, usually at the top, it is the larger of the 2 numbers given (the other is the atomic number). It is called relative because the mass does not have units, it is the mass compared to 12C isotope. Find the Ar of 1) Sodium, Na 2) Zinc, Zn 3)Carbon, C 4) Sulphur, S The molecular or formula mass (Mr) is found by adding up the Ar values of the atoms present e.g. 1) O 2 (oxygen) contains 2 O atoms. Ar of O = 16, Mr = 2x16 = 32 2) H 2 O (water) contains 2 H and one O atoms. Ar of H=1, Ar of O =16 Mr = 2x1 + 1x16 = 18 3) Na 2 SO 4 (sodium sulphate) contains 2 Na, 1 S and 4 O atoms Ar of Na = 23, Ar of S =32, Ar of O=16 Mr = 2x23 + 1x32 + 4x16 = 142 4) Mg(NO 3 ) 2 (magnesium nitrate) contains 1 Mg, 2 N and 6 O (the 2 at the end of the bracket doubles the atoms inside) Ar of Mg =24, N=14, O=16 Mr = 24 + 2x14 + 6x16 = 148 Find the Mr of H2 C2H6 CO 2 CaCO 3 NaCl NaNO 3 P2O3 Ca(OH) 2 H 2 SO 4 Pb(NO 3 ) 2 b) PERCENTAGE OF AN ELEMENT To find the percentage of an element 1) Find the mass of all the atoms of the required element 10 2) Find the relative mass of the whole compound (Mr) 3) Divide 1) by 2) and multiply by 100 % of Element = Mass of all atoms of Element x 100 Mr of Compound Example Find the % of iron in Fe 2 O 3 (Mr: Fe = 56, Fe 2 O 3 = 160) Mass of 2 Fe atoms = 2x56 = 112 Mr of Fe 2 O 3 = 2x56 + 3x16 = 160 % of iron in Fe 2 O 3 = 112/160 x 100 = 70% Or % of iron in Fe 2 O 3 = 2x56 x 100 = 70% 160 Find the % of C in CO 2 Find the % of H in H 2 O Find the % of Zn in ZnCO 3 Find the % of Mg in MgCl 2 Find the % of Pb in PbO 2 Find the % of Cl in MgCl 2 Find the % of Pb in Pb 2 O 3 c) PERCENTAGE YIELD. When a substance is made by a chemical reaction, you do not always get as much as you expected. 11 This can be for a number of reasons: 1) Some of the material is lost in the experimental process. 2) An unwanted reaction takes place, giving you less of your product. 3) The reaction is reversible. The percentage yield compares the mass you actually get with the amount you expected to get under ideal conditions. Percentage Yield = Mass obtained in Experiment x 100 Expected Mass e.g. Ebenezer expects to get 4.6g of alcohol from his experiment. The actual mass obtained was 3.5g. Find the % yield. Answer = 3.5 x 100 = 76.1% 4.6 Priscilla is making some exclusive perfume. She expects to get a maximum of 10.6g from her procedure, but only manages to get 7.1g. What is her percentage yield? Answer = 7.1 x 100 = 67% 10.6 Complete the following Mass obtained from experiment Expected Mass 10g 20g 2.5g 12.5g 1.7g 5.1g 25kg 18.5kg Percentage Yield d) FINDING THE EMPIRICAL FORMULA OF A COMPOUND 12 The empirical formula of a compound shows the ratio of the atoms in it. If we can find the mass of each element present, we can convert this to numbers of particles and find the ratio. This will give us the empirical formula. Note that the empirical formula only gives us the ratio of atoms, while the molecular formula tells us the actual number of atoms. e.g Molecular Formula Empirical formula H2O2 HO C2H4 CH 2 C2H6 C 4 H 10 K2O2 C 6 H 12 O 6 Rules for Finding an Empirical Formula a) Write the symbols for the elements present. b) Find the mass (or %) of each element present in the compound. c) Find the relative mass of each element from the Periodic Table d) Divide the mass of each element by its relative atomic mass to give ratio or atoms. e) Divide each number in the ratio by the smallest number to get a whole number ratio f) This gives the empirical formula, i.e. the ratio of atoms in its simplest form. Example 13 20g of a compound of Silicon with hydrogen contains 17.5g of silicon. Find the empirical formula. Element Si H 17.5 20-17.5 = 2.5 28 1 Mass ÷ Ar 17.5÷28 = 0.625 2.5÷1 = 2.5 Divide through by smallest. 0.625 ÷ 0,625 = 1 2.5 ÷ 0.625 = 4 1 4 Mass of element present Relative Mass (Ar) Whole Number Ratio Empirical Formula SiH 4 Percentages can be used in place of masses A compound contains Na 33.3%, N 20.3% and O 46.4%. Find its empirical formula: Element Na N O 33.3 20.3 46.4 23 14 16 Mass ÷ Ar 33.3÷23 = 1.447 20.3÷14 =1.45 46.4÷16 = 2.9 Divide through by smallest. 1.447÷1.447 = 1 1.45÷1.447 = 1.002 2.9÷1.447 = 2.004 1 1 2 % of element present Relative Mass (Ar) Whole Number Ratio Empirical Formula Na NO 2 EXERCISES 14 Find the empirical formulae of compounds containing: (useful Ar values: S=32, O=16, Mg=12, Br=80, K=39, C=12, H=1) a) 24g of sulphur and 36g of oxygen b) 3g of magnesium with 40g of bromine. c) 54.9% potassium with 45.1% oxygen d) 6g of carbon with 2 g of hydrogen e) 52.1% carbon, 13% hydrogen, 34.9% oxygen. e) 1g of a compound of hydrogen and oxygen containing 0.0588g hydrogen. 15