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CHAPTER 1 SAMPLE TEST Modified True/False Indicate whether the sentence or statement is true or false. If false, change the identified word or phrase to make the sentence or statement true. ____ 1. Atoms of the same element with the same number of protons, but a different number of neutrons are called isomers. _________________________ ____ 2. Neutrons are so light that their mass is usually considered to be zero ____ 3. The electrons in the outermost s and p orbitals are called valence orbitals. _________________________ ____ 4. Electronegativity is a measure of an atom's ability to attract a shared electron pair when it is participating in a covalent bond with another atom. _________________________ ____ 5. Acids release hydroxyl ions into solution when they dissociate in water ____ 6. The sulfhydryl group is a functional group found in some amino acids. _________________________ ____ 7. Radioisotopes are used to date prehistoric life forms ____ 8. The amount of adenine equals the amount of cytosine in a molecule in DNA ____ 9. A molecular formula gives information about the arrangement of atoms in a molecule ____ 10. Fibrous proteins are rich in helix ____ 11. The production of a large molecule from smaller subunits is referred to as a catabolic reaction. _________________________ ____ 12. The pH of vinegar is lower than the pH of pure water ____ 13. Compounds that contain amino groups are called organic acids ____ 14. A pH of 13 would indicate acidic conditions. ____ 15. An enzyme is observed to have several -pleated sheets. These are example of tertiary structures. _________________________ ____ 16. Organisms form various types of small organic molecules called monomers, which may be linked together to form polymers ____ 17. Chaperone proteins help assemble DNA molecules ____ 18. Several polypeptides may make a protein. ____ 19. An exothermic reaction that involves an increase in entropy is spontaneous at all temperatures. _________________________ ____ 20. An atom that has gained or lost electons is called an isotope ____ 21. The bond that results from the reaction between potassium and chlorine is an ionic bond ____ 22. Feedback inhibition is a method used by cells to control metabolic pathways in which a product formed later in the sequence of reaction steps competitively inhibits an enzyme that catalyzes a reaction occurring earlier in the process. _________________________ ____ 23. A pentose is a monosaccharide that has four carbon atoms ____ 24. Competitive inhibitors attach to the active site of an enzyme ____ 25. The innermost energy level of an atom can accommodate only two electrons Multiple Choice Identify the letter of the choice that best completes the statement or answers the question. ____ 26. The most abundant class of biological molecules in a “typical” cell is a. carbohydrates d. proteins b. lipids e. ammonia c. nucleic acids ____ 27. In looking at the periodic table, the following information would be found about nitrogen: ____ 28. ____ 29. ____ 30. ____ 31. ____ 32. ____ 33. From the above, it can be determined that an atom of nitrogen has the following characteristics: a. it has 7 protons, 14 neutrons and 7 electrons b. it has 2 protons in the first energy level and 5 protons in the second energy level c. it has an atomic mass of 14 atomic mass units and 7 electrons d. it has 7 neutrons and 4 electrons e. it as an atomic number of 14 and contains 7 protons Element 'X' has 7 electrons in the outermost energy level of each of its atoms. Atoms of element 'Y' also contain 7 electrons in the outermost energy level. However, when neutral, element 'Y' has a much lower atomic mass. Therefore a. both elements will form covalent bonds more readily that ionic bonds b. element 'X' has a lower electronegativity than element 'Y' c. it is highly probable that these elements will form polar covalent bonds d. both elements will tend to give up an electron to become chemically stable e. there is not enough information to answer this question Which of the following is not a type of intermolecular force of attraction? a. covalent bond d. hydrogen bond b. London dispersion force e. hydrophobic interaction c. dipole-dipole interaction Which of the following is the essential characteristic of a polar molecule? a. contains double or triple bonds b. is formed at extremely low temperatures c. contains ions as part of the structure d. has an asymmetrical distribution of electrical charge e. contains the element oxygen Isomers are molecules that a. react readily with one another b. have the same molecular formula c. have different molecular masses d. differ in the number of unsaturated bonds e. must contain the same functional group Starch, cellulose, and glycogen are all classified as: a. carbohydrates d. proteins b. lipids e. ammonia c. nucleic acids By what factor would the concentration of hydrogen (hydronium) ions be decreased if the pH of a solution changed from 4.5 to 6.5? ____ 34. ____ 35. ____ 36. ____ 37. ____ 38. ____ 39. ____ 40. ____ 41. a. 2 d. 20 b. 5 e. 100 c. 10 Which one of the four major lipids consists of four joined carbon rings plus various side goups? a. fatty acids d. steriods b. triglycerides e. ammonia c. phospholipids When atoms from two different elements are brought together under conditions that will favour a reaction and they have similar electronegativities, which type of chemical bond is most likely to form? a. nonpolar covalent bond d. polar covalent bond b. ionic bond e. London forces c. hydrogen bond A chemical bond involving carbon and hydrogen (C-H) is present in many biological molecules. Based upon their electronegativities the bond could be described as a. a weak ionic bond d. a covalent bond b. both ionic and covalent e. a strong ionic bond c. a hydrogen bond Choose the element that is found in all organic compounds. a. nitrogen d. hydrogen b. carbon e. oxygen c. sulphur Glycogen is an example of a. carbohydrate d. protein b. lipid e. ammonia c. nucleic acid A combination of two or more atoms of different elements in specific proportions and with a specific pattern of bonds is known as a: a. molecule d. salt b. substance e. compound c. isomer A dissaccharide is formed by a condensation reaction in which two molecules are gained by the removal of a molecule of what? a. carbon dioxide d. salt b. water e. sulfur dioxide c. ammonia The following structural formula is representative of which functional group? a. sulfhydryl d. carbonyl b. hydroxyl e. amino c. carboxyl ____ 42. The following structural formula is representative of which functional group? a. sulfhydryl b. hydroxyl d. carbonyl e. amino ____ 43. ____ 44. ____ 45. ____ 46. ____ 47. ____ 48. ____ 49. ____ 50. ____ 51. ____ 52. ____ 53. ____ 54. c. carboxyl Which of the following is not a component of DNA? a. deoxyribose d. adenine b. uracil e. thymine c. phosphate A nitrogen atom would be found bonded to a hydrogen atom in which of the following functional groups? a. sulfhydryl d. carbonyl b. hydroxyl e. amino c. carboxyl At what pH value could an enzyme have both positive and negative charges upon it? a. 1 and 13 d. 7 b. 1, 7, and 13 e. 1 c. 13 Of the following, which is not considered to by a polymer? a. cellulose d. protein b. RNA e. fat c. starch Of the following biological compounds, which one contains the element, nitrogen? a. fatty acids d. starch b. sugar e. protein c. glycerol There are four elements that make up all amino acids. Two of these are carbon and hydrogen. The other two are a. sulfur and nitrogen d. nitrogen and oxygen b. phosphorus and nitrogen e. phosphorus and oxygen c. sulfur and oxygen When digested, which of the following substances would yield a mixture of amino acids? a. carbohydrate d. protein b. nucleic acids e. fat c. sugar Of the list of compounds below, which one cannot result in the production of urea, a nitrogen-containing waste product found in urine? a. glucose d. proteins b. amino acids e. peptides c. enzymes When two organic molecules are joined together and a water molecule is removed, the reaction is called which of the following? a. dehydration synthesis (condensation) d. oxidation b. hydrogenation e. reduction c. hydrolysis The hydrolysis (breakdown) of an ester results in a. a sugar and an acid d. two sugars b. two acids e. an acid and an alcohol c. an acid and an amine The hydrolysis (breakdown) of a dipeptide results in the production of which of the following? a. a sugar and an amino acid d. two sugars b. two amino acids e. an amino acid and an alcohol c. an acid and an amine Protons have what charge? ____ 55. ____ 56. ____ 57. ____ 58. ____ 59. ____ 60. ____ 61. ____ 62. ____ 63. ____ 64. a. positive d. ionic b. negative e. isomeric c. neutral The production, or synthesis, of proteins, fats, and carbohydrates involves the a. production of ATP d. temporary hydrogen bonding b. addition of water e. removal of nitrogen c. removal of water Which of the following properties of water helps move water to the tips of trees? a. high specific heat of vapourization d. high surface tension b. adhesion e. lower density as a solid than as a liquid c. high solubility Which of the following does a buffer comprise? a. a strong acid only d. a weak acid and a weak base b. a weak base only e. a weak acid and a strong base c. a strong acid and a strong base What fatty acids and glycerol chemically combine to form a fat, one other product is a. carbon dioxide d. water b. ATP e. an amino group c. a monosaccharide Which of the following bonds hold together a protein’s primary structure a. hydrogen bonds d. covalent bonds b. ionic bonds e. dipole-dipole interactions c. London forces The extremely large diversity of structure seen in proteins is mainly due to a. the disulfide and hydrogen bonds that determine molecular shape b. the action of the ribosomes c. the precise location of specific amino acids, common to all proteins d. different numbers, kinds, and sequences of amino acids e. different kinds of bonds between successive amino acids Proteins tend to denature at temperatures over a. 0 ºC d. 40º C b. 10 ºC e. 60º C c. 20º C Many people are aware that water is the most abundant substance in all organisms. However, next to water, what is the major component of living cells? a. nucleotides d. vitamins b. carbohydrates e. lipids c. proteins The mass of an atom is determined by adding the number of a. protons and electrons d. isotopes b. protons and neutrons e. isotopes and isomers c. neutrons and electrons Of the following, which are reasons why molecular models are useful to biologists? Models help I. visualize the shape of functional groups II. visualize geometric isomers III. visualize the three-dimensional shapes of molecules IV. determine the presence of symmetry in molecules V. predict products of chemical reactions a. I only d. III, IV and V only ____ 65. ____ 66. ____ 67. ____ 68. ____ 69. ____ 70. ____ 71. ____ 72. ____ 73. b. I and II only e. I, II, III, IV and V c. I, II, IV and V only In the electron transport chain of the mitochondria, electrons are commonly transferred from one molecule to another. In one such reaction a Fe3+ ion in a cytochrome is converted to a Fe2+ ion. This is known as a. isomer formation d. hydrolysis b. reduction e. neutralization c. oxidation An oxidation/reduction is best shown by which of the following? a. an amino and carboxyl group form a peptide bond b. two small molecules chemically combine to form a large one c. a base reacts with an acid to form water and a salt d. electrons are transferred from one substance to another e. a large molecule is broken into two smaller molecules During photosynthesis, water molecules are split according to the following reaction: H2O + NADP+ NADPH + H+ + O2 In the reaction, which substance undergoes reduction? a. the hydrogen ions (protons) d. the NADP+ b. the NADPH e. the water molecules c. the oxygen that is released DNA is an example of a. carbohydrate d. protein b. lipid e. ammonia c. nucleic acid Of the following characteristics, which one is not true about enzymes? a. They are essential to the metabolism of cells for the conversion of energy. b. They function best at specific temperatures but break down at high temperatures. c. Some enzymes need activators or cofactors. d. They function best at a particular pH. e. They undergo major chemical change after reacting with their specific substrate. Of the following five statements, which is most correct with respect to enzymes? a. A denatured enzyme is more specific in its action. b. Denaturation of proteins always involves enzymes. c. Catalysts prevent chemical reactions. d. All catalysts are enzymes. e. All enzymes are catalysts. At which temperature would you expect any enzyme extracted from a human tissue to have its optimal performance? a. 5C d. 37C b. 10C e. 95C c. 25C The activity of an enzyme can be altered by changing the pH of its surroundings slightly. This change in pH works by a. causing the enzyme to precipitate b. masking its active site c. increasing the activation energy of the reaction d. breaking its peptide bonds e. altering its three dimensional shape Which of the following statements about enzymes is not true? a. They are proteins with tertiary or quaternary structures. b. They are very specific for the substrate to which they bind. c. They will bind their substrate and any isomer of their substrate. d. Their names usually end in 'ase.' e. All of the above statements are true. ____ 74. Which of the following is a statement of the second law of thermodynamics a. Energy is conserved in the universe d. The entropy of the universe always increases b. Entropy is conserved in the universe e. The energy of the universe always increases c. Living organisms are exempt from this law ____ 75. Which of the following statements regarding enzyme inhibition is incorrect? a. Competitive inhibitors have a similar structure to the normal substrate. b. Competitive inhibitors bind to the active site of an enzyme. c. Noncompetitive inhibition can be overcome by adding more substrate. d. Noncompetitive inhibitors do not have a similar structure to the normal substrate. e. Noncompetitive inhibitors do not bind to the active site of an enzyme. CHAPTER 1 SAMPLE TEST Answer Section MODIFIED TRUE/FALSE 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: F, isotopes F F, valence electrons T F T T F F T F, anabolic reaction T F F F, secondary structure T F T T F T F, allosterically inhibits F T T MULTIPLE CHOICE 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: D C B A D B A E D A D B A 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60. 61. 62. 63. 64. 65. 66. 67. 68. 69. 70. 71. 72. 73. 74. 75. ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: ANS: E B E D B E D E E D D A A E B A C B D D D D E C B E B D D C E E D E C D C