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LESSON 16: Crystal Art ESTIMATED TIME Setup: 5 minutes | Procedure: 15–30 minutes • DESCRIPTION • MATERIALS Mix different solid crystals in water, and then use the solutions to make fun designs on paper. • OBJECTIVE This lesson illustrates states of matter, classifications of matter, and changes between states of matter. Students mix different substances in water, use the solutions to paint on paper, and watch as fun crystal designs appear when the liquid vaporizes. The lesson can be extended to address the concepts of solubility and saturation. • CONTENT TOPICS Scientific inquiry; states of matter; mixtures (solutions); physical changes (vaporization) o Table salt Epsom salt o Sugar o Cotton swabs o Clear plastic cups o Pen o Masking tape o Black construction paper o Teaspoon o Magnifying glass (optional) o Always remember to use the appropriate safety equipment when conducting your experiment. Refer to the Safety First section in the Resource Guide on pages 391–393 for more detailed information about safety in the classroom. Jump ahead to page 209 to view the Experimental Procedure. NATIONAL SCIENCE EDUCATION STANDARDS SUBJECT MATTER This lesson applies both Dimension 1: Scientific and Engineering Practices and Dimension 2: Crosscutting Concepts from “A Framework for K–12 Science Education,” established as a guide for the updated National Science Education Standards. In addition, this lesson covers the following Disciplinary Core Ideas from that framework: • PS1.A: Structure and Properties of Matter • ETS2.A: Interdependence of Science, Engineering, and Technology (see Analysis & Conclusion) OBSERVATION & RESEARCH BACKGROUND Matter exists primarily as a solid, liquid, or gas on the earth. Gases have no definite shape and no definite volume. Examples of gases are the oxygen we breathe and the helium that fills balloons. Liquids have a definite volume but no definite shape. Examples of liquids are water and oil. Solids have a definite volume and a definite shape. Examples of solids are chairs, trees, and salt. Certain solids, called crystalline solids, are made up of atoms or molecules that have a specific, repeating structure. Ice and salt are crystalline solids. Other solids are made up of atoms or molecules that are locked into place but do not have a specific, repeating structure. Those solids are known as amorphous solids. Wax is an example of an amorphous solid. Matter can change from one state to another, generally as a result of a change in temperature. These changes are physical changes. A physical change is any change in a substance’s form that does not change its chemical makeup. The chemical formula of the substance stays the same before and after the change. For example, tearing or cutting a piece of paper is an example of a physical change. The paper is in smaller pieces, but the chemical makeup of the paper has not changed. Likewise, ice, water, and water vapor are all H2O in different physical You Be TheLESSON Chemist®Activity Activity Guide Guides | page 206 1: Goofy Putty 206 LESSON 16: Crystal Art states. The chemical formula remains H2O regardless of whether it is in the solid, liquid, or gaseous state. FORMULAS & EQUATIONS Common table salt is mainly made up of the compound sodium chloride. Melting is a change in state from a solid to a liquid. The opposite change is freezing. Freezing is a change in state from a liquid to a solid. A change in state from a liquid to a gas is known as vaporization, while a change in state from a gas to a liquid is known as condensation. Changes that occur directly between the solid and gaseous states, without going through the liquid state first, are less common. Sublimation is a change in state from a solid directly to a gas. The opposite is deposition, when a gas changes directly into a solid. In the experiment, students mix different crystalline solids in water. A mixture is made of two or more substances that are combined physically. A solution is a specific type of mixture. A solution is a uniform mixture in which one or more substances (solutes) are dissolved in another substance (solvent). Dissolving sugar or salt in water creates a solution. The solute is either sugar or salt, and the solvent is water. The students can then “paint” on a piece of paper with the different solutions. Over time, the water will vaporize (becoming water vapor), leaving behind the solid crystals in fun designs. The chemical formula for sodium chloride is NaCl. Most table salts are made of about 97–99% NaCl. The remaining 1–3% is usually iodine and other ingredients. Epsomite, commonly known as Epsom salt, is hydrated magnesium sulfate. The chemical formula for Epsom salt is MgSO4 • 7(H2O). The chemical name for table sugar is sucrose. It is a white, odorless, crystalline powder with a sweet taste. A molecule of sucrose is made up of two simple sugars, glucose and fructose. Sucrose has the formula C12H22O11. Tap water is a mixture of pure water, minerals, and other substances. The chemical formula for pure water is H2O. CONNECT TO THE YOU BE THE CHEMIST CHALLENGE For additional background information, please review CEF’s Challenge study materials online at http://www.chemed.org/ybtc/challenge/study.aspx. Fun Fact Diamonds are crystalline solids. A diamond is the hardest natural substance and can scratch glass and most other gemstones and metals. • Additional information on physical changes and states of matter can be found in the Classification of Matter section of CEF’s Passport to Science Exploration: The Core of Chemistry. • Additional information on mixtures and solutions can be found in the Classification of Matter section of CEF’s Passport to Science Exploration: The Core of Chemistry. HYPOTHESIS uWhen a salt or sugar solution is used to “paint” on black paper, fun crystal designs will remain on the paper after the water vaporizes. You Be The Chemist® Activity Guide | page 207 LESSON 16: Crystal Art DIFFERENTIATION IN THE CLASSROOM LOWER GRADE LEVELS/BEGINNERS Perform the experiment as described on page 209, but spend more time on states of matter. Show pictures of different things and have the students identify the state of matter. An important concept directly related to solubility is saturation. Saturation is the point at which no more of a solute can be dissolved into a solvent. If you continue to add a solute to a solution, eventually the additional solute will no longer dissolve. This point is the saturation point. Likewise, show images of matter changing states—snow melting, a pond freezing, etc. Again, have the students identify which changes they see and how they know. You may have to show a series of images to illustrate the changes. In this experiment, different crystalline solids will be added to water one teaspoon at a time. When no more of each solute can be dissolved in the water, the solution has become saturated. At this point, the solutions will be used to “paint” on black paper. Over time, the water will vaporize (becoming water vapor), leaving the solid crystals behind in fun designs. HIGHER GRADE LEVELS/ADVANCED STUDENTS DESCRIPTION Create various solutions, and use those solutions to make fun designs on paper. OBJECTIVE This lesson explores states of matter, solubility, and saturation. Students mix different substances in water, use the solutions to paint on paper, and watch as fun crystal designs appear as the liquid vaporizes. OBSERVATION & RESEARCH Mixtures and solutions are all around us—the air, the ocean, and the soil are all mixtures in different physical states. A mixture is made of two or more substances that are combined physically. A solution is a specific type of mixture. A solution is a uniform mixture in which one or more substances (solutes) are dissolved in another substance (solvent). Dissolving sugar or salt in water creates a solution. The solute is either sugar or salt, and the solvent is water. CONNECT TO THE YOU BE THE CHEMIST CHALLENGE For additional background information, please review CEF’s Challenge study materials online at http://www.chemed.org/ybtc/challenge/study.aspx. • Additional information on mixtures and solubility can be found in the Classification of Matter section of CEF’s Passport to Science Exploration: The Core of Chemistry. • Additional information on solutions and saturation can be found in the Chemicals by Volume— Solutions section of CEF’s Passport to Science Exploration: Chemistry Connections. In addition, solubility is a physical property that describes the ability of a chemical substance (the solute) to dissolve in a solvent to create a uniform solution. A substance that dissolves in another substance is soluble. For example, salt is soluble in water. If a substance does not dissolve, it is insoluble. For instance, butter is insoluble in water. Several factors can affect solubility, including temperature, pressure, and the amount of solute or solvent in a solution. You Be The Chemist® Activity Guide | page 208 LESSON 16: Crystal Art EXPERIMENTATION As the students perform the experiment, challenge them to identify the independent, dependent, and controlled variables, as well as whether there is a control setup for the experiment. (Hint: If you use a different solute, do the results change?) Review the information in the Scientific Inquiry section on pages 14–16 to discuss variables. EXPERIMENTAL PROCEDURE 1. Divide a piece of black construction paper into three sections. Use masking tape and a pen to label one section “salt,” a second section “sugar,” and the third section “Epsom salt.” 2. Take three clear plastic cups, and label them “salt,” Be sure the water in each cup is the same temperature to determine which substance will dissolve the most in water. Increasing temperature will increase the solubility of all the substances. At the same temperature, sugar is the most soluble, followed by table salt, and then Epsom salt. “sugar,” and “Epsom salt.” 3. Fill a quarter of each cup with hot tap water, and place each cup in its section on the black construction paper. 4. Put one level teaspoon of table salt into the cup labeled “salt,” and stir with a spoon or swirl the cup until the salt crystals dissolve (until you can’t see any or can only see very few crystals against the black background). Add another teaspoon and stir or swirl until these crystals dissolve as well. 5. Repeat step 4, continuing to add teaspoons of salt, DATA COLLECTION Have students record data in their science notebooks or on the following activity sheet. How many teaspoons of table salt can you dissolve in the water? How many teaspoons of sugar can you dissolve? How many teaspoons of Epsom salt can you dissolve? You can use the table in the activity sheet (or a similar one of your own) for students to record their data. NOTES until the water cannot dissolve any more crystals (when you still see crystals after stirring or swirling). Record the number of teaspoons used. 6. Repeat steps 4–5 using the sugar and then the Epsom salt. Record the number of teaspoons of each type of crystal that dissolved in the water. 7. After each solution is made, dip a cotton swab in the table salt cup. Use the solution to write your name or draw a design in the “salt” section on the black construction paper. Do the same with the other two liquids using separate cotton swabs. 8. Allow the water to vaporize (15–30 minutes), and watch as the crystal designs appear. You Be The Chemist® Activity Guide | page 209 LESSON 16: Crystal Art ANALYSIS & CONCLUSION Use the questions from the activity sheet or your own questions to discuss the experimental data. Ask students to determine whether they should accept or reject their hypotheses. Review the information in the Scientific Inquiry section on pages 14–16 to discuss valid and invalid hypotheses. ASSESSMENT/GOALS Upon completion of this lesson, students should be able to … • Apply a scientific inquiry process and perform an experiment. REAL-WORLD APPLICATIONS • Scientists use the process of crystallization to purify solid compounds. To do this, the solid compound is dissolved completely in a hot solvent. The hot solution contains both the desired compound and the impurities. As the solution cools, the solvent can no longer hold all of the solute particles, so those particles begin to crystallize out of the solution. During this process, each solute particle will approach a growing crystal and will attach to the crystal surface if it fits the structure of the crystal (if it is the same type of molecule). Therefore, the desired solid compound (solute) is separated from the impurities. • Compare and contrast solids, liquids, and gases, and give examples of each. COMMUNICATION • Differentiate between crystalline and amorphous solids. Discuss the results as a class and review the activity sheet. Review the information in the Scientific Inquiry section on pages 14–16 to discuss the importance of communication to scientific progress. • Define and identify physical changes between states of matter. • Define and identify solutions, solutes, and solvents. • Explain solubility and saturation (see Differentiation in the Classroom). MODIFICATIONS/EXTENSIONS Modifications and extensions provide alternative methods for performing the lesson or similar lessons. They also introduce ways to expand on the content topics presented and think beyond those topics. Use the following examples or have a discussion to generate other ideas as a class. • To demonstrate the relationship between temperature and solubility, try the experiment again, but this time, use refrigerated or cold water. You will find that less of each substance will dissolve in the water. The amount of solid solute that can dissolve in a solvent decreases as the temperature decreases. You Be The Chemist® Activity Guide | page 210 LESSON 16 ACTIVITY SHEET: Crystal Art OBSERVE & RESEARCH 1. Write down the materials you see. ____________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ 2. How might these materials be used? __________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ 3. Define the following key terms. Then, provide an example of each by writing the example or drawing/pasting an image of the example. Term Definition Example (write or add image) Gas Liquid Solid Physical change Melting Freezing Vaporization Condensation Mixture Solution You Be The Chemist®Activity ActivityGuides Guide | page 211 LESSON 16 ACTIVITY SHEET: Crystal Art 4. Consider what happens when salt or sugar solutions are applied to black construction paper and why. uWrite your hypothesis. ______________________________________________________________ ______________________________________________________________________________________ ______________________________________________________________________________________ PERFORM YOUR EXPERIMENT 1. Divide a piece of black construction paper into three sections. Use masking tape and a pen to label each section. Label one section “salt.” Label the second section “sugar.” Label the third section “Epsom salt.” 2. Get three clear plastic cups. Label one “salt.” Label the second “sugar.” Label the third “Epsom salt.” 3. Fill a quarter of each cup with hot tap water. Place each cup in its section on the black construction paper. 4. Put one level teaspoon of table salt into the cup labeled “salt.” Stir with a spoon or swirl the cup until the salt crystals dissolve. Stir until you can’t see any or can only see very few crystals against the black background. Then, add another teaspoon of table salt. Stir or swirl until these crystals dissolve as well. 5. Repeat step 4. Continue to add teaspoons of salt until the water cannot dissolve any more crystals. At this point, you will still see crystals after stirring or swirling. Record the number of teaspoons used. 6. Repeat steps 4–5 using the sugar. Then, repeat steps 4–5 again using the Epsom salt. Record the number of teaspoons of each type of crystal that dissolved in the water. 7. After each solution is made, dip a cotton swab in the table salt cup. Use the solution to write your name or draw a design in the “salt” section on the black construction paper. Use two other cotton swabs and do the same with the other two liquids. 8. Allow the water to vaporize (15–30 minutes). Observe. You Be The Chemist® Activity Guide | page 212 LESSON 16 ACTIVITY SHEET: Crystal Art ANALYZE & CONCLUDE 1. In the table below, record the number of teaspoons needed to completely saturate each solution. Substance Salt Sugar Epsom salt Number of Teaspoons 2. Which substance dissolves the most in water? (Into which cup did you add the most teaspoons?) ________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ 3. Which substance dissolves the least in water? __________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ 4. What happens when you first write or draw on the paper? Can you see the designs? __________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ 5. What happens after the liquid vaporizes? Can you see the designs? ______________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ 6. Is your hypothesis valid? Why or why not? If not, what would be your next steps? ____________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ You Be The Chemist®Activity ActivityGuides Guide | page 213 LESSON 16 ACTIVITY SHEET: Crystal Art EXPAND YOUR KNOWLEDGE—ADVANCED 1. Define the following key terms. Then, provide an example of each by writing the example or drawing/pasting an image of the example. Term Definition Example (write or add image) Solute Solvent Soluble Insoluble Saturation 2. Is it possible to dissolve more crystals in a saturated solution? How could you do it? ____________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ 3. List other crystal substances. __________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ You Be The Chemist® Activity Guide | page 214 LESSON 16 ACTIVITY SHEET: Crystal Art ANSWER KEY Below are suggested answers. Other answers may also be acceptable. OBSERVE & RESEARCH Sugar, table salt, Epsom salt, water, plastic cups, black construction paper … 1. Write down the materials you see. ____________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ Sugar and table salt may be used in cooking. Epsom salt may be used to soothe aches and 2. How might these materials be used? __________________________________________________________________ pains. These substances may be added to water to create solutions and compare their physical properties. Water may be used to drink, ______________________________________________________________________________________________________ bathe, or clean. Black construction paper may be used for drawing or in crafting. ______________________________________________________________________________________________________ 3. Define the following key terms. Then, provide an example of each by writing the example or drawing/pasting an image of the example. Term Definition Gas A state of matter that has no definite volume or shape. Liquid A state of matter that has a definite volume but no definite shape; a liquid will take the shape of the container that holds it, filling the bottom first. Solid A state of matter characterized by a definite volume and a definite shape; a gas will take the shape of the container that holds it, filling the entire container. Physical change A change that alters the form or appearance of a substance but does not change its chemical makeup or create a new substance. Melting A physical change in which a substance changes states from a solid to a liquid. Freezing A physical change in which a substance changes states from a liquid to a solid. Vaporization A physical change in which a substance changes states from a liquid to a gas. Condensation A physical change in which a substance changes states from a gas to a liquid. Mixture A physical combination of two or more substances that can be physically separated. Solution A homogeneous (uniform) mixture in which one or more substances (solutes) are dissolved in another substance (solvent). Example (write or add image) You Be The Chemist® Activity Guide | page 215 LESSON 16 ACTIVITY SHEET: Crystal Art ANSWER KEY Below are suggested answers. Other answers may also be acceptable. 4. Consider what happens when salt or sugar solutions are applied to black construction paper and why. When a salt or sugar solution is applied to black construction paper, crystal designs uWrite your hypothesis. ______________________________________________________________ ______________________________________________________________________________________ will eventually appear as the water vaporizes. ______________________________________________________________________________________ PERFORM YOUR EXPERIMENT 1. Divide a piece of black construction paper into three sections. Use masking tape and a pen to label each section. Label one section “salt.” Label the second section “sugar.” Label the third section “Epsom salt.” 2. Get three clear plastic cups. Label one “salt.” Label the second “sugar.” Label the third “Epsom salt.” 3. Fill a quarter of each cup with hot tap water. Place each cup in its section on the black construction paper. 4. Put one level teaspoon of table salt into the cup labeled “salt.” Stir with a spoon or swirl the cup until the salt crystals dissolve. Stir until you can’t see any or can only see very few crystals against the black background. Then, add another teaspoon of table salt. Stir or swirl until these crystals dissolve as well. 5. Repeat step 4. Continue to add teaspoons of salt until the water cannot dissolve any more crystals. At this point, you will still see crystals after stirring or swirling. Record the number of teaspoons used. 6. Repeat steps 4–5 using the sugar. Then, repeat steps 4–5 again using the Epsom salt. Record the number of teaspoons of each type of crystal that dissolved in the water. 7. After each solution is made, dip a cotton swab in the table salt cup. Use the solution to write your name or draw a design in the “salt” section on the black construction paper. Use two other cotton swabs and do the same with the other two liquids. 8. Allow the water to vaporize (15–30 minutes). Observe. You Be The Chemist® Activity Guide | page 216 LESSON 16 ACTIVITY SHEET: Crystal Art ANSWER KEY Below are suggested answers. Other answers may also be acceptable. ANALYZE & CONCLUDE 1. In the table below, record the number of teaspoons needed to completely saturate each solution. Substance Salt Sugar Epsom salt Number of Teaspoons Answers will vary Answers will vary Answers will vary Answers will vary. 2. Which substance dissolves the most in water? (Into which cup did you add the most teaspoons?) ________________ (In general, sugar dissolves the most in water. It is the most soluble in water.) ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ Answers will vary. (In general, the Epsom salt dissolves the least in water. It is the 3. Which substance dissolves the least in water? __________________________________________________________ least soluble in water.) ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ 4. What happens when you first write or draw on the paper? Can you see the designs? When you first write on the paper, __________________________ the paper just appears wet where you applied the solution. You cannot clearly see any designs. ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ After the water vaporizes, you can see designs from the 5. What happens after the liquid vaporizes? Can you see the designs? ______________________________________________ crystals left behind. ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ 6. Is your hypothesis valid? Why or why not? If not, what would be your next steps? ____________________________ Answer 1: Valid because the data support my hypothesis. ______________________________________________________________________________________________________ Answer 2: Invalid because the data do not support my hypothesis. I would reject my hypothesis and could form a new one, such as … ______________________________________________________________________________________________________ You Be The Chemist® Activity Guide | page 217 LESSON 16 ACTIVITY SHEET: Crystal Art ANSWER KEY Below are suggested answers. Other answers may also be acceptable. EXPAND YOUR KNOWLEDGE—ADVANCED Have students complete this section if you used the advanced differentiation information, or challenge them to find the answers to these questions at home and discuss how these terms relate to the experiment in class the next day. 1. Define the following key terms. Then, provide an example of each by writing the example or drawing/pasting an image of the example. Term Definition Solute A substance that is dissolved in a solution. Solvent A substance capable of dissolving another substance. Soluble The ability of a substance to dissolve in another substance. Insoluble The inability of a substance to be dissolved into another substance. Saturation The point at which no more of a solute can be dissolved into a solvent or solution. Example (write or add image) It is possible to dissolve more crystals 2. Is it possible to dissolve more crystals in a saturated solution? How could you do it? ____________________________ in a saturated solution. If the solute is a solid, you can heat the solution to dissolve more of the solute. In this experiment, if you heated the ______________________________________________________________________________________________________ saltwater solution, you could dissolve more salt into the solution. ______________________________________________________________________________________________________ Diamonds and other gemstones are examples of crystalline solids. Ice is also a crystalline solid. 3. List other crystal substances. __________________________________________________________________________ ______________________________________________________________________________________________________ ______________________________________________________________________________________________________ You Be The Chemist® Activity Guide | page 218