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Biogeochemical Cycles Nutrient cycling at its finest! Four Criteria for Sustainability Sustainable Ecosystems Need: Reliance on Solar Energy High Biodiversity Population Control Nutrient Cycling This note set aligns with this concept. What is a Biogeochemical Cycle? • Bio - = life / living • Geo - = Earth • Chemical = chemical • These are cycles in which elements or chemicals move through biotic (living) and abiotic (nonliving) parts of an ecosystem Examples of Biogeochemical Cycles • • • • • • • • Carbon cycle Nitrogen cycle Phosphorus cycle Oxygen cycle Water cycle Sulfur cycle Rock cycle Mercury cycle What Are Reservoirs/Sinks? • A reservoir/sink is a place where the chemical of a cycle may be stored. • There are 3 general places that chemicals in biogeochemical cycles are stored: – Atmosphere – the air – Hydrosphere – the water – Lithosphere – the land Carbon Cycle Processes • Label the processes on your carbon cycle diagram. The 6 processes are: – Photosynthesis – Decomposition – Cellular Respiration – Combustion – Sedimentation – Diffusion #1 = DIFFUSION #2 = SEDIMENTATION #3 = DECOMPOSITION or CELLULAR RESPIRATION #4 = PHOTOSYNTHESIS #5 = CELLULAR RESPIRATION or DECOMPOSITION #6 = COMBUSTION Prompt • Make the definitions in this form: • When carbon in the form of ____ and found in _____ is converted into the form of ____ and found in ____. Carbon Cycle Processes • Photosynthesis = movement of CO2 from air into food/sugar found in biomass of autotrophs • Decomposition = release of carbon gases into atmosphere by decay of biomass by decomposers (like bacteria) • Cellular Respiration = release of CO2 into atmosphere from breakdown of food/sugar • Combustion = burning of organic biomass to release carbon gases (mainly CO2) into atmosphere • Sedimentation = burial and reaction of carbon based materials with other elements to create sedimentary rock • Diffusion = dissolving of carbon from atmosphere into water and vice versa Forms That Carbon Come In • CO2 = Carbon dioxide (gas) • CO32- = Carbonate (ion) – shells of marine organisms • HCO3- = Bicarbonate (ion) – shells of marine organisms • Carbon in Biomass • Sediments/Rock • Fossil Fuels Terrestrial Carbon Reservoirs/Sinks • Carbon can be stored in: – Plant Biomass – Sedimentary Rocks (Limestone!) – Fossil Fuels – Soil Organic Matter – Wetlands #1 = DIFFUSION #2 = SEDIMENTATION #3 = DECOMPOSITION or CELLULAR RESPIRATION #4 = PHOTOSYNTHESIS #5 = CELLULAR RESPIRATION or DECOMPOSITION #6 = COMBUSTION Aquatic Carbon Reservoirs/Sinks • Carbon can be stored in: – Aquatic Producer Biomass – Coral – Marine Organisms’ Shells/Skeletons – Water – Sedimentary Rocks (Limestone!) Organize the Nitrogen Cycle • Place a form of nitrogen into each box/rectangle in the diagram. Use the information given about each form to select where each form could go. • Use each form once, except for N2, which is used twice! N2 N2 Organically bound Nitrogen NO3 NO2 NH4 Wastes with Organic Nitrogen N2O Forms of Nitrogen (Full Names) • • • • • NH4+ – Ammonium NO3- – Nitrate N2 – Nitrogen gas NO2- – Nitrite N2O – Nitrous Oxide Keep Organizing the Nitrogen Cycle! • There are 5 nitrogen cycle processes. Label each one on your diagram from the definitions that are given to you. • Then jot down the definitions for your records! N2 N2 Organically bound Nitrogen NO3 NO2 NH4 Wastes with Organic Nitrogen N2O Nitrogen Cycle Processes • AMMONIFICATION – conversion of nitrogen from waste materials into ammonium • ASSIMILATION – uptake of usable nitrogen forms into nitrogen-containing molecules in organisms (protein, DNA) • DENITRIFICATION – conversion of nitrate into gaseous forms of nitrogen • NITRIFICATION – conversion of usable ammonium into nitrite and then to usable nitrate • NITROGEN FIXATION – conversion on inert nitrogen gas into usable ammonium N2 N2 N2O NITROGEN FIXATION Organically bound Nitrogen ASSIMILATION NO3 NO2 NH4 DENITRIFICATION Wastes with Organic Nitrogen AMMONIFICATION Facts on Nitrogen Cycle • All chemical transformations in the nitrogen cycle are performed by bacteria. • Legumes (type of plant) are well known to house nitrogen fixing bacteria. – If farmers plant legumes, they will also have bacteria in the soil that perform nitrogen fixation. – This helps reduce fertilizer use! • Farmers who use manure for fertilizer are trying to promote ammonification to get more usable ammonium in the soil. Human Alteration of Nitrogen Cycle • The Haber Process – This is a method developed to make inorganic (synthetic) fertilizer. – In the process, you put N2 through a series of high energy chemical reactions to make NH3 or NH4. – Positives: – We make more fertilizer that is easy to use. – We are finally using a readily found form of nitrogen (N2) – Negatives: – Fossil fuels are used to create the high energy chemical conditions needed for the reaction. – Humans now make and use much more fertilizer than before, and fertilizer is a pollutant in waterways. Phosphorus Cycle • Forms of Phosphorus – Phosphate ion (PO43-) • Found in rock, water – Organically bound phosphorus – in living things • What is phosphorus used for? – Building block of DNA, RNA, ATP, cell membranes Phosphorus Cycle • Reservoirs/Sinks of Phosphorus – Organisms – Lithosphere – Hydrosphere • How Can Humans Impact This Cycle? – Phosphate can be mined from rocks to use in fertilizers. – This means more phosphates get into water quicker, when fertilizers are used.