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Exam Review - Chapter 2: Stoichiometry 1) The formula for fructose is C6H12O6. Which of the following is true for fructose? ____ a) the empirical formula is C2H4O2 ____ b) there is a total of six atoms in each molecule ____ c) a molecule contains six carbon atoms ____ d) the ratio of carbon to oxygen atoms is 1:2 2) A positively charged ion ____ a) is formed when an atom loses electrons ____ b) is called an anion ____ c) is formed when an atom gains a proton ____ d) has more electrons than protons 3) Which of these ions has the same electron configuration as Ar? ____ a) Na+1 ____ b) Ca+1 ____ c) S-1 ____ d) Cl-1 4) Monatomic anions (negative ions) are named with the suffix ____ a) -ide ____ b) -ate ____ c) -ite ____ d) -ade 5) To use the criss-cross method of writing the formula of an ionic compound, write the numerical charge of ____ a) the cation as the subscript of the cation ____ b) the anion as the subscript of the cation ____ c) each ion as its own subscript ____ d) each ion as its own superscript 6) What is the name for the compound (NH4)3PO4? ____ a) triammonium quatrophosphate ____ b) polyammonum phosphate ____ c) ammonium phosphate ____ d) ammonium (III) phosphate 7) What is the name of the compound whose formula is FeSO4? ____ a) iron (II) sulfate ____ b) iron sulfate ____ c) iron (III) sulfate ____ d) iron (I) sulfate 8) Determine the formula of the compound formed between calcium and hydroxide ions. ____ a) CaOH ____ b) Ca(OH)2 ____ c) CaOH2 ____ d) Ca2OH 9) Determine the formula of the compound aluminum phosphide. ____ a) AlP ____ b) AlPO4 ____ c) Al(PO)4 ____ d) Al3(PO4)3 10) Determine the formula for copper (II) chloride. ____ a) Cu2Cl ____ b) (CuCl)2 ____ c) CuCl ____ d) CuCl2 11) Determine the formula for iron (III) nitrate. ____ a) Fe(NO3)3 ____ b) FeN ____ c) Fe3NO3 ____ d) Fe3(NO3)3 12) A substance that enters into a chemical reaction is called a ____ a) mole ____ b) product ____ c) coefficient ____ d) reactant 13) The word equation “magnesium reacts with chlorine to produce magnesium chloride would be represented by which of the following formula equations? ____ a) Mg + Cl ---> MgCl ____ b) Mg + 2 Cl ---> MgCl2 ____ c) Mg + Cl2 ---> MgCl2 ____ d) MgCl ---> Mg + Cl 14) In a chemical reaction, what is the relationship between the total mass of the reactants and the total mass of the products? ____ a) they must be equal ____ b) the mass of the products must be greater ____ c) the mass of the reactants must be greater ____ d) there is no general relationship between the two 15) In balancing a chemical equation, which of the following are you allowed to do? ____ a) change subscripts ____ b) write coefficients ____ c) change charges ____ d) add new substances H. Chem 16) Which of the following means a substance dissolved in water? ____ a) (aq) ____ b) (s) ____ c) (w) ____ d) (l) 17) What number should be written in front of Na to balance the equation ___ Na + ___ MgCl2 ---> ___ NaCl + ___ Mg ____ a) 1 ____ b) 2 ____ c) 3 ____ d) 4 18) In what kind of reaction does an uncombined element displace an element that is part of a compound? ____ a) synthesis ____ b) double replacement ____ c) single replacement ____ d) decomposition 19) What kind of reaction is represented by the equation CH4 + 2 O2 ---> CO2 + 2 H2O ____ a) synthesis ____ b) single replacement ____ c) double replacement ____ d) combustion 20) Balance the chemical equation Al + F2 ---> AlF3 ____ a) already balanced ____ b) 2 Al + F2 ---> 2 AlF3 ____ c) Al3 + F6 ---> Al3F6 ____ d) 2 Al + 3 F2 ---> 2 AlF3 21) Mercury (II) oxide, HgO, is heated until it is broken down into its elements. Which is a balanced equation for the reaction? ____ a) HgO2 ---> Hg + O2 ____ b) 2 HgO ---> 2 Hg + O2 ____ c) 2 HgO ---> 2 Hg + 2 O ____ d) HgO ---> Hg + O 22) Write a balanced equation for a reaction in which gaseous ethane (C2H6) burns in air. ____ a) C2H6 (g) ---> C2 (g) + 3 H2 (l) ____ b) C2H6 (g) + O2 (g) ---> 2 CO2 (g) + 3 H2O (l) ____ c) 2 C2H6 (g) + 7 N2 (g) ---> 4 CN2 (g) + 6 H2N (l) ____ d) 2 C2H6 (g) + 7 O2 (g) ---> 4 CO2 (g) + 6 H2O (l) 23) When an element and a compound undergo a chemical reaction, the type of reaction is called a ____ a) single replacement ____ b) double replacement ____ c) synthesis ____ d) decomposition 24) When two substances come together to make one compound, this is called a _________ reaction. ____ a) combustion ____ b) synthesis ____ c) decomposition ____ d) single replacement 25) What is the molar mass of Zn(NO3)2? ____ a) 159 g/mol ____ b) 189 g/mol ____ c) 173 g/mol ____ d) 255 g/mol 26) How many atoms are in a sample of an element whose mass in grams is numerically equal to the atomic mass? ____ a) 1 ____ b) 6.02 x 1023 ____ c) 1 x1023 ____ d) 6.02 27) Which of the following normally exists as a diatomic element? ____ a) sodium ____ b) chlorine ____ c) neon ____ d) sulfur 28) What is the empirical formula of a compound whose molecular formula is C2Cl6? ____ a) CCl3 ____ b) CCl4 ____ c) CCl ____ d) C2Cl6 29) What is the molecular formula for a compound whose empirical formula is CH and has a molar mass of 39 g/mol? ____ a) CH ____ b) C2H2 ____ c) C3H3 ____ d) C4H4 30) In a balanced equation describing a chemical reaction involving solid substances, the coefficients refer to the relative number of ____ a) grams ____ b) liters ____ c) cubic centimeters ____ d) particles H. Chem 31) The number of mole of a reactant or product is determined by dividing its mass by ____ a) Avogadro’s number ____ b) the molar mass of the substance ____ c) the volume of the substance ____ d) the molar ration of reactants to products 32) In mass-mass problems, the steps to follow are best summarized as going from ____ a) grams to moles to moles to grams ____ b) liters to moles to liters to moles ____ c) grams to moles to moles to liters ____ d) grams to moles to liters to molecules 33) Which type of stoichiometry problem is essential to solving the other types? ____ a) mass-mass ____ b) mass-volume ____ c) volume-particles ____ d) mole-mole 34) When two reactants are available in stoichiometric proportions represented by the chemical reaction ____ a) only the most massive reactant will be used up ____ b) neither of the reactants will be used up ____ c) both of the reactants will be used up ____ d) only the least massive reactant will be used up 35) The limiting reactant in a completed chemical reaction will be the substance ____ a) used up ____ b) left over ____ c) with the greatest mass before the reaction ____ d) with the least mass before the reaction Use the following diagram to answer questions 37 & 38. 37) The reaction of methane and oxygen is represented by the equation CH4 + 2 O2 ---> CO2 + 2 H2O. If the balloons of methane and oxygen in the figure above are forced into a third container and allowed to react, what substances will be present in the container after the reaction is over? ____ a) carbon dioxide and water ____ b) carbon dioxide, methane, oxygen and water ____ c) carbon dioxide, water and oxygen ____ d) carbon dioxide, water and methane 38) The reaction of hydrogen and chlorine is represented by the equation H2 + Cl2 ---> 2 HCl. If the balloons of hydrogen and chlorine in the figure above are forced into a third container and allowed to react, what substances will be present in the container after the reaction is over? ____ a) hydrogen chloride ____ b) hydrogen chloride and chlorine ____ c) hydrogen chloride and hydrogen ____ d) hydrogen chloride, hydrogen and chlorine 36) The percent yield of products from a chemical reaction is the ratio of ____ a) expected yield to actual yield ____ b) actual yield to expected yield ____ c) actual yield to minimum yield ____ d) expected yield to minimum yield H. Chem Problems: 1) Calculate the volume of a balloon filled with 15.0 g of NO2 at STP. 2) Calculate the number of moles of 76.1 g SO2. 3) An 11.78 g sample of an unknown compound is decomposed and analyzed. The procedure produces 0.36 g of H, 3.73 g of P and 7.69 g of O. Determine the percent composition of hydrogen in the compound. 4) What is the percent of oxygen by mass in water? 5) A sample of ammonia (NH3) contains 7.22 moles of ammonia. How many molecules of ammonia are in the sample? 6) What is the mass of 2.0 mol of CuCl2? 7) A susbstance is analyzed and determined to be made up of 69.4 % carbon, 4.13 % hydrogen, and 26.4 % oxygen. The molar mass of the substance is found to be 242 g/mol. a) What is the empirical formula for the substance? b) What is the molecular formula for the substance? 8) How many liters of ammonia gas would be produced by 3.00 grams of magnesium nitride, according to the reaction Mg3N2 + 6 H2O --> 3 Mg(OH)2 + 2 NH3? 9) Solid iron (II) sulfide reacts with aqueous hydrochloric acid (HCl) to produce hydrogen sulfide gas and a solution of iron (II) chloride. How many grams of hydrochloric acid must react to produce 2.50 L of hydrogen sulfide at STP? 10a) When CH4 burns in the presence of oxygen, it produces CO2 and H2O. What mass of water would be made from 4.25 g of CH4? b) If 9.05 g of water is recovered when performing the lab, what is the percent yield of the lab? 11) Copper is made by mixing aqueous copper (II) chloride with solid aluminum. If a solution containing 32.4 g of copper (II) chloride is mixed with 5.00 g of aluminum powder, how many grams of copper would be produced? Answers to problems 1) 7.30 L 2) 1.19 mol 5) 4.35 x 1024 molecules 8) 1.34 L 9) 8.15 g 3) 3.1 % H 6) 269 g 10a) 9.56 g 4) 88.9 % O 7) C7H5O2, C14H10O4 b) 94.7 % 11) 15.3 g H. Chem