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11/16/2013 Chapter 2 Vocabulary Base Unit Second (s) Meter (m) Kilogram (kg) Kelvin (K) Derived unit Liter Density Co‐Curricular Data Analysis Review Scientific notation Dimensional analysis (Equality) – not in book Conversion factor Accuracy Precision Significant Figures 2 Chapter 2 – Analyzing Data Scientific Notation Units of measure Base units: A defined unit in a system of measurement that is based on an object or event in the physical world and is independent of other units. Examples: time (sec), mass (gram), length (meter) Derived units: combinations of base units such as volume (length3), velocity (length/time), and density (mass/volume). Temperature: Either Celsius (⁰C) or Kelvin (K). Scientific Notation – It is notation used to express very large or very small numbers using powers of 10. Proper format: (1≤Number<10) x 10n Examples 175 L = 1.75 x 102 L 15,000,000 g = 1.5 x 107 g 0.00000000530 m = 5.30 x 10-9 m 3 Scientific Notation Metric Units of Length Comparison Scientific Notation and Commonly Used Metric Prefixes Prefix Symbol Meaning 4 Factor Unit Makes Unit BIGGER! kilometer mega M 1 million times larger than the unit it precedes 106 kilo k 1000 times larger than the unit it precedes 103 Makes Unit smaller! deci d 10 times smaller than the unit it precedes 10-1 centi c 100 times smaller than the unit it precedes 10-2 milli m 1000 times smaller than the unit it precedes 10-3 micro μ 1 million times smaller than the unit it precedes 10-6 nano n 1 billion times smaller than the unit it precedes 10-9 Examples: 1 kilometer = 1000 meters 1 millimeter = 0.001 meters (10-3 m) 5 Symbol Relationship km 1 km = 103 m 10-3 km = 1 m Example Length of about 5 city blocks ≈ 1 km meter m Base unit Height of doorknob from the floor ≈ 1 m decimeter dm 101 dm = 1 m 1 dm = 10-1 m Diameter of a large orange ≈ 1 dm centimeter cm 102 cm = 1 m 1 cm = 10-2 m Diameter of a shirt button ≈ 1 cm millimeter m 103 mm = 1 m Thickness of a dime ≈ 1 mm 1 mm = 10-3 m Micrometer μ 106 μm = 1 m Diameter of a bacteria cell ≈ 1 μm 1 μm = 10-6 m Human hair ≈ 25 μm nanometer n 109 nm = 1 m 1 nm = 10-9 m Thickness of RNA molecule ≈ 1 nm Example: 123,000 m = 123 x 103 m = 123 km 6 1 11/16/2013 Scientific Notation Metric Units of Mass Comparison Scientific Notation Metric Units of Volume Comparison Unit Symbol Relationship Liter L milliliter mL Cubic centimeter microliter cm3 or cc μL Example Base unit Quart of milk ≈ 1 L 103 mL = 1 L 1 mL = 10-3 L 20 drops of water ≈ 1 mL 1 cm3 = 1 mL 103 cm3 = 1 L Cube of sugar ≈ 1 cm3 106 μm = 1 L 1 μm = 10-6 L Crystal of table salt ≈ 1 μL Drop of water from a needle ≈ 1 μL Unit Symbol Relationship Example kilogram kg 1 kg = 103 g gram g Base unit Dollar bill ≈ 1 g milligram mg 103 mg = 1 g Ten grains of salt ≈ 1 mg microgram μg 106 μg = 1 g 1 particle of baking powder ≈ 1 μg A small textbook ≈ 1 kg Example 1: 43,000 g = 43 x 103 g = 43 kg Notice we are not putting in proper scientific notation, but in an order of magnitude that corresponds to a prefix. Example 2: 0.0000033 g = 3.3 x 10-6 g = 3.3 μg Example: Break up number into groups of 3. 0.000005 L = 0.000 005 L = 5 x 10-6 L = 5 μL (10-6) 7 8 Scientific Notation Addition and Subtraction Scientific Notation Practice Express in Scientific notation: 3.8 x 104 m 38000 m 5.06 x 103 s 5060 s 5.4 x 10-3 g 0.0054 g Convert: 4.5 km 4500 m to km 5.33 μg 0.00000533 g to μg 777 x 10-6 L or 7.77x10-4 L 777 μL to L Unit to measure: Thickness of a quarter? mm (millimeter) Mass of a car? kg (kilogram) Volume of soda can? mL (milliliter) Make sure numbers are in the same order of magnitude (You don’t have to have them in proper format to add and subtract.) 2. Then add or subtract as usual, carry down the exponent and the unit. 1. 9 Scientific Notation Addition and Subtraction Example 10 Scientific Notation Rules of Exponents Add 3.553 x 104 ft+ 2.22 x 103 ft 3.553 x 104 ft + 0.222 x 104 ft 3.775 x 104 ft You can use the Rules of Exponents to multiply or divide numbers in scientific notation. The Rules of Exponents: ◦ (10m)(10n) = 10m+n ◦ (10m)n = 10m*n ◦ 10m/10n = 10m-n ◦ 10-m = 1/10m ◦ 100 = 1 Subtract 4.753 x 106 m – 8.52 x 105 m 47.53 x 105 m - 8.52 x 105 m 39.01 x 105 m 11 12 2 11/16/2013 Scientific Notation Multiplication and Division More Scientific Notation Practice For multiplication, multiply the two first factors, then add the exponents. Multiply the units too. Ex: (6.5 x 102 ft)(2.0 x 102 ft) = 13 x 104 ft2 or 1.3 x 105 ft2 For division, divide the two first factors, than subtract the denominator from the numerator. Keep units in same position. Ex: 1.5 x 104 g 3.0 x 103 cm3 = 1.5/3.0 x 101 g/cm3 = 0.50 x 101 or 5.0 g/cm3 Solve: 5 x 10-5 m + 2 x 10-5 m 1.26 x 104 kg + 2.5 x 103 kg 5.36 x 10-1 kg – 7.40 x 10-2 kg (4 x 102 cm) x (1 x 108 cm) (6 x 102 g) / (2 x 101 cm3) 7 x 10-5 m 1.51 x 104 kg 4.62 x 10-1 kg 4 x 1010 cm2 3 x 101 g/cm3 13 14 Dimensional Analysis Dimensional Analysis Dimensional analysis is a method of problem solving that focuses on the units to describe what you are looking at. It uses a conversion factor, which is the ratio of equivalent values (equalities) used to express the same quantity with different units. Example: 1 mile = 5280 ft…so 1 mile = 1 and 5280 ft = 1 5280 feet 1 mile When using them, put the unit given in the denominator and the unit you want in the numerator. New Unit ‘ Old (Given) Unit 15 Dimensional Analysis 16 Dimensional Analysis If you are using a derived unit, such as density, the equality will show the relationship between units that measure different properties. Example: If the density of iron is 7.87 g/cm3, that really means: Remember that units work like variables. ◦ Example: 8 .00 a * Every 7.87 g of iron will take up 1 cm3 Or 7.87 g = 1 cm3 (for iron) 2 .54 b 20 .3b a ◦ Same as: 8.00in * 17 2.54cm 20.3cm 1in 18 3 11/16/2013 Dimensional Analysis Dimensional Analysis Practice Convert: 12.0 feet to inches 12.5 meters to centimeters 2500 cm2 to m2 65 miles/hr to ft/s Remember that units work like variables. ◦ Example: 1b 1b * 32 .50 a 2 * 0 .003250 b 2 100 a 100 a ◦ Same as: 32 .50 cm 2 * 1m 1m 0.003250 m 2 * 100 cm 100 cm 144 inches 1250 cm 0.25 m2 95 ft/s 19 Reliability of Measurements 20 Reliability of Measurements Percent Error How far you are off from an accepted measurement. Error Percent Error x100 Accepted Value Error = |obtained value – accepted value| The error is the absolute difference. It doesn’t matter if the error is above or below the accepted value. With scientific measurements, you want to know accuracy, precision and certainty. ◦ Accuracy – How close a measurement is to an accepted value ◦ Precision – How close a measurement is to other measurements of the same thing. 21 Accuracy Example 22 Precision Example A student runs an experiment three times and obtains values of 6.54 g, 6.60 g, and 6.65 g. Ideally, they should have gotten 6.55 g as a result. Determine the overall accuracy of the experiment. The average of the three results is: 6.54 + 6.60 + 6.65 = 6.60 g 3 | 6.60 – 6.55| x 100 = 0.7% error 6.55 A. One set of balances give the following readings: 10.05 g, 9.92 g, 10.77 g for a 10.00 g mass. B. Another set of balances give these readings: 9.95g, 10.02 g, and 10.00 g. Which set, A or B, is more precise? 23 24 4 11/16/2013 Significant Figures (Sig Figs) Significant Figures! For any measured value, sig figs are all of the certain digits plus an uncertain digit. The last digit is an estimate and is off by at least +1. Example: 5.2 really means between 5.1 and 5.3. 10.53 really means between 10.52 and 10.54 25 Significant Figure RULES 26 Significant Figure RULES Example 3. Zeros between two significant digits are 38.002 kg has 5 SF’s significant. Example 1. All non zero 34.554 m has 5 digits SF’s (1,2,3,4,5,6,7,8, and 9) are significant. 2. Trailing zeros to $2.00 has 3 SF’s, the right of the both trailing zero’s decimal point are are significant. significant. 0.05410 has 4 SF’s 4. Zeros used as placeholders are not significant. 200 m has 1 SF 0.002 g has only 1 SF But, 500. s has 3 SF’s 27 Significant Figure RULES Example 5. For numbers in scientific notation, all of the digits before the “x 10n” are significant. 6. Counting numbers and defined constants are considered to have an infinite number of significant figures. 28 Significant Figure RULES 7. When you add or subtract values, your final answer must have the same number of digits to the right of the decimal place as the value with the fewest number of decimal places. Example: 4.662 km +10.5 km 15.162 ≈ 15.2 km 5.23 x 105 km has 3 SF’s 6 coins 2.54 cm/1 in 29 30 5 11/16/2013 Significant Figure RULES Significant Figure RULES (Cont’d) 8. When you multiply or divide, your final answer can only have the same number of sig figs as the measurement with the fewest sig figs. Example: 3.444 m* 2.11 m= 7.2584 m2 which becomes 7.26 m2 Note: For simplicity, report 3 sig figs for all x and / calculations. 9. Figuring out the number of significant figures is the LAST thing you do. If you have more than one step, carry more digits than you think you need while you’re doing the calculation. This will minimize errors due to rounding. 31 Significant Figure Rules of Thumb Rounding Rules 1. 2. 32 When multiplying or dividing, report answer to 3 sig figs. If the digit to the right of the last significant figure is less than five, do not change the last significant figure. Ex. 4.433 4.43 If the digit to the immediate right of the last significant figure is equal to or greater than five, round up the last significant figure. Ex. 5.446 5.45 Ex. 3.335 3.34 This represents 3 orders of magnitude and your measuring device (meter stick, balance, graduated cylinder, etc.) will give you 3 or 4 sig figs. Start with first nonzero digit and report 3 digits, regardless of where the decimal point is. Example 1: 0.212 g/53.3 mL = 0.00398 g/mL Example 2: 45.8 mm x 53.2 mm = 2436.56 mm2 ≈ 2440 mm2 Note that 45.7 mm x 53.1 mm = 2426.67 mm2 ≈ 2430 mm2 Remember that the last digit represents an estimated value. 33 Significant Figures – why they are important!! More Dimensional Analysis Practice Convert and give answer w/correct # of sig figs 14.2 hours to seconds 34 Densities of Metals 51120 s 5.12 x 104 s 1.50 ft2 to in2 216 in2 17.8 ft3 to gallons 133 gallons Zinc: 7.14 g/cm3 Iron: 7.87 g/cm3 Chromium: 7.20 g/cm3 Zirconium: 6.51 g/cm3 Tin: 7.31 g/cm3 Manganese: 7.47 g/cm3 Three students measure mass and volume of an g/cm unknown 3 Student Mass, g theVolume, Density, metal. They will try and determine cm3 which metal it is by its density. 1 14 2 7 35 2 14.1 2.0 7.1 3 14.14 1.96 7.21 36 6