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2 In our experiment we will explore how to make a ferrofluid, a liquid apparently without anything special, but that turns out to be amazing as soon as you approach a magnetic field! It consists of very small magnetic particles, hundreds of thousands of times smaller than a millimeter, a few nanometers, immersed in mineral oil, vegetable oil or engine oil. The iron filings will not work well, they are too big. Good sources of magnetic particles are: toner of laser printers; magnetic powder control (sold in shops for welding); •particles from burned steel wool, filtered ; •particles obtained by scraping the surface of VHS-film or alternatively by burning it, separating the residue with a magnet. We have chosen to use the steel wool. . MATERIALS: - steel wool, 1 package - tights (to filter dust) - engine oil, about 30 mL - liquid soap (or other surfactants), a few drops TOOLS : - beakers and capsules - watch glass - glass chopsticks - aluminum container -lighter - magnets PROCEDURE : First you take your steel wool, which can be easily found in household goods shops or iron mongers, put it in an aluminum container and set it on fire. The "wool " burns out quickly, with a nice effect but without dangerous sparks, and as soon as it cools you can continue. Bracco Gloria Tibaldi Marco 3 What remains after combustion is a great base for the ferrofluid, but it needs to be pulverized before. To do this rub it with your hands very carefully, picking up the gray powder that comes off the steel wool. This powder is still too heterogeneous for the experiment, it's necessary to filter it. So, collect the filings in a glass or in a beaker, cover the opening with tights which act as a filter. By turning the glass upside down and shaking it you will get a fine smooth gray powder For best results you can still crush the filtrate with pestle and mortar, or repeate the filtration. In a capsule add engine or brake oil to iron powder, in a 1:1 ratio, and with a chopstick stir until obtaining a homogeneous mixture, adding gradually drops of liquid soap We made several attempts, using seed oil , engine , brakes , etc. . Our ferrofluid is ready! To observe its behavior under the influence of a magnetic field you just have to pour it on a capsule or on a watch glass and bring one or more magnets. The ferrofluid will lose its "puddle" shape and gather around the poles of the magnet, creating beautiful three dimensional forms. These vary from magnet to magnet and disappear as soon as the magnetic field moves away. The greater the strength of the magnet the more noticeable is the effect obtained. To find a very strong magnet we enjoyed ourselves opening an old hard-disk. The following pictures have been taken in our lab with a ferrofluid bought on the web for a better effect. Bracco Gloria Tibaldi Marco 4 Bracco Gloria Tibaldi Marco 5 THEORETICAL CONTENTS The ferrofluid is composed of particles of a ferromagnetic element dispersed in a fluid, in our case oil. These particles tend to form agglomerates and structures of greater dimensions, but the action of a surfactant, such as soap, avoids it. The soap molecules possess, in fact, a hydrophilic hydrophobic part that allows them to bind simultaneously with the particle of iron and with the molecule of fat (oil), practically by coating and isolating the individual particles. High temperatures also counteract the agglomeration, and are exploited to achieve commercial ferrofluids. To explain the behavior of ferrofluid under the action of a magnetic field you must imagine each particle as a small magnet that can move freely within the oil. The ferrofluid, however, does not behave like a "liquid magnet", in fact, it doesn't attract iron, but if we approach an external magnetic field, these tiny magnets leave their mess and get arranged parallel to the lines of force field. For example, if you move a A sinistra i dipoli che si orientano secondo il campo magnetico "north" pole to the right (semplificato in linee parallele.) of the ferrofluid, all the particles that are dispersed in the oil in an extreme disorder will rotate turning their pole "south" to the right. In addition, each magnetic field force line has characteristics that can be observed with a few iron filings and a white sheet of paper. Just as the filings on the sheet of paper, the particles of ferrofluid are arranged following the complex geometric patterns of the force lines, which vary according to the frequency and the amplitude of the magnetic field. Bracco Gloria Tibaldi Marco 6 To explain the behavior of a material subjected to a magnetic field, you need to further analyze its atomic structure. You've got to remember that all the coils crossed by an electric current generate a vertical magnetic field in the centre, behaving just like a compass needle. Every single electron that revolves around a core represent a microscopic electric current, so it is a magnetic dipole. The arrangement of the dipoles is disorganized, and the thermal agitation (the vibration of the molecules due to heat) prevents the wheel from being tidy. A ferrofluid doesn’t keep the polarization, obtained for orientation, when you remove the external magnetic field. Therefore it doesn’t work as a ferromagnet but as a super-paramagnet. Albert Einstein Bracco Gloria Tibaldi Marco