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Hydrocarbon Review Biology 6.0 Name: Date: Period: 1. The name for a hydrocarbon generally consists of two parts. The first part indicates the number of carbon atoms in the chain. Fill in the blanks. 1 C atom – 6 C atoms – 2 C atoms– 7 C atoms – 3 C atoms- 8 C atoms – 4 C atoms – 9 C atoms– 5 C atoms – 10 C atoms – 2. The second part of the name of a hydrocarbon is the same as that of its series. When you know the series to which a hydrocarbon belongs, you have other information available: Fill in the blanks. SERIES NAME ENDING GENERAL FORMULA BONDING IN C CHAIN Alkane Cn H2n+2 Double bond -C=C- Alkyne -yne 3. How many carbon atoms are in each hydrocarbon below? a) Methane f) Hexane k) Decane b) Ethane g) Ethyne l) Butyne c) Ethene h) Propane m) Butene d) Pentane i) Heptane n) Propyne e) Propene j) Octene o) Butane 4. Name each of the formulas by first writing down the carbon-count “prefix,” then add the ending indicating the series to which the compound belongs a) C2H2 h) C5H10 b) C5H12 i) C2H4 c) C3H8 j) C3H4 d) C7H14 k) C4H6 e) CH4 l) C6H12 f) C3H6 m) C8H18 g) C7H12 n) C10H18 1 Hydrocarbon Models & Naming Practice Name: 6.0 Biology Date: Period: Atoms bond with other atoms in specific ways. In this lab, you will construct the molecules indicated in the boxes below using the molecular model kits. Remember – carbon forms four bonds. These bonds can be single, double or triple. Oxygen and nitrogen can also form single and double bonds. Use the correct colors for the different elements: black = carbon, white = hydrogen, red = oxygen, blue = nitrogen. After you have constructed the molecules, draw the structure of the molecule in the space provided. Draw the molecule to the shape you see with the models. Substance Structure Formula Series Methane 2-Butyne 1-Pentene 2-Hexene Propane 2-Pentyne Hexane 2 Organic Names and Structures Name: ________________________ Honors Biology Date: Structure Name Period: Molecular Formula Type of Hydrocarbon (series) 1. 2. 3. 4. 5. CH3 CH 6. CH3 C CH CH2 CH3 C CH2 CH3 7. 3 Structure Name 8. 3-hexyne 9. ethene 10. decane 11. 3-heptene 12. 4-octyne 13. 2-butyne 14. 2-nonene Molecular Formula Type of Hydrocarbon (series) 4 Functional Group Practice Biology 6.0 Name: Date: Period: Directions: In the following activity, you are going to build different types of simple organic molecules. After each step you should return back to the original molecule, before proceeding to the next arrangement. Follow the directions to this lab very carefully. For each direction that cannot be followed you will lose one point. You have been warned! A. Build the molecule C. Draw the structure B. Name the molecule, when applicable D. Obtain Teacher’s Initial 1. Build the molecule, pentane, using your model kit. Draw the 2-D image of the model below. (You must draw the chemical symbol for Hydrogen wherever H is found) 2. Make the model from step #1 into an alkene by making a double bond between the 2nd and 3rd carbon. Name this molecule: __________________________ Teacher’s Initial: _____________ Draw a 2-D image of this molecule. 3. Remove a hydrogen atom from the 3rd carbon and in its place you are going to add a methyl group. A methyl group is a branch off of the carbon skeleton that has only one carbon surrounded by 3 hydrogen atoms. Build this molecule. Teacher’s Initial: _____________ Draw a 2-D Image of this molecule. Naming this molecule: Step 1: Which carbon does the branch connect to on the carbon skeleton? ________ Step 2: How many carbon atoms are in the branch (Not including the carbon that is a part of the carbon skeleton? ______ What is the prefix associated with that number? _________ Add the suffix –yl to the prefix from the previous question to make __________. Step 3: What would the name of the carbon skeleton be if there was no branch attached to the molecule? _____________ Step 4: Take the last blank in each of the previous steps and put them together! ____ __________ ________________ 5 4. Carbonyl Functional Group (Aldehydes) Remove two hydrogen atoms from the 1st carbon. In their place, attach one oxygen atom using a double bond. Name of Molecule: __________________________ Teacher’s Initial: _____________ Draw the 2-D image. (Circle the Aldehyde functional group including the carbon within the skeleton) 5. Carbonyl Functional Group (Ketones) Remove two hydrogen atoms from a carbon atom that is NOT on the end. (You have three to choose from!) In their place, add a double bonded oxygen. Name of Molecule: __________________________ Draw the 2-D image. (Circle the Functional Group) Teacher’s Initial: _____________ 6. Hydroxyl Functional Group (Alcohols): Remove one hydrogen from any carbon atom. In its place add a single bonded oxygen to the open location. Add another hydrogen atom to the unpaired location on the oxygen atom. Name of Molecule: _____________________________ Teacher’s Initial: _____________ Draw a 2-D model and circle the functional group. A functional group is anything that has been added to the carbon skeleton, but it also includes the carbon that within the carbon skeleton. 7. Carboxyl Functional Group (Acids): Remove three hydrogen atoms from an end carbon. Attach a double bonded oxygen to the end. Also, attach a 2nd oxygen atom to the open location via a single bond. Fill the unpaired electron on the second oxygen with a hydrogen atom. Name of Molecule: ___________________________________ Draw a 2-D model and circle the functional group. Teacher’s Initial: _____________ 6 8. Sulfhydryl functional group (thiols): Remove one hydrogen from ANY carbon atom. Attach a Sulfur atom to the carbon. A sulfur atom has 6 valence electrons. In the other unpaired electron, add a hydrogen atom. Teacher’s Initial: _____________ Name of Molecule: _________________________________ Draw a 2-D model and circle the functional group. Part 2: Circle the functional group on each of the following hydrocarbons. Name the compound. 1. 2. Functional Group: Functional Group: Compound Name: Compound Name: 3. 4. Functional Group: Functional Group: Compound Name: Compound Name: 7 Circle the functional groups that are in each molecule. More than one functional group can be found in a molecule. Formaldehyde is the starting point for making many chemicals. Functional Group(s): Formic acid gives ant venom its sting. Functional Group(s): Lactic acid builds up as a waste product in exercising muscles and makes them feel tired. Functional Group(s): Ethylene glycol is in automobile antifreeze. Functional Group(s): Acrolein is produced when meat is heated (burnt fat); it is the barbecue smell. Functional Group(s): Serine is part of many protein molecules. Functional Group(s): Urea is a waste product in urine. Functional Group(s): Putresine’s name is descriptive; it is produced in rotting flesh from the breakdown of amino acids. Functional Group(s): G3P is an intermediate step in plant’s production of sugar. Functional Group(s): 8 FUNCTIONAL GROUPS Functional Group Structure Compound Name Naming Properties Example Polar Attracts water (good solvent) Hydroxyl Alcohols -ol Carbonyl (end) Aldehydes -al Carbonyl (middle) Ketones -one Carboxyl Carboxylic Acid (Organic Acids) -oic acid Acidic properties Amino Amines -amine Basic properties Structural isomers with different properties X Makes the molecule and anion Transfer energy Methyl Methylated Compounds X May affect gene expression Sulfhydryl Thiols -thiol Phosphate Phosphates Stabilize proteins methanethiol 9 Functional Group & Hydrocarbon Review Name: 6.0 Biology Date: Period: Circle the functional group and identify the class of compounds formed (What it makes…) by the added functional group. H | A. __________________ A. H O B. H O H | // | | | H–C–C H-C- C -C-H B. ___________________ | \ | | | H OH H H H C. ___________________ D. ___________________ H H O H | | || | C. H – C – C – C –C – H | | | H H H H H O | | || D. H – C – C – C– H | | H H E. ____________________ H H H H | | | | E. H – N – C – C – C– H | | | H H H COMPLETION ____________________ 1. The name of a straight chain hydrocarbon having 6 carbon atoms contains the prefix -?-. ____________________ 2. A hydrocarbon with a double bond in the carbon chain is classified as a/an _____ ____________________ 3. The general formula to determine the number of hydrogen atoms for the hydrocarbon series having a triple bond is __________. ____________________ 4. The formula for an organic acid contains the functional group __________ ____________________ 5. The formula for ethane is __________ ____________________ 6. All organic compounds contain the element __________ ____________________ 7. For an alkane to have an isomer, there must be at least ______carbon atoms in the chain. ____________________ 8. A molecule of propane contains ______hydrogen atoms. 10 ____________________ 9. The prefix for four carbon atoms is __________ _____________________10. The amino group and carboxyl groups are both in a molecule of a/an _______ (Hint: It is the monomer for proteins.) _____________________11. The –OH functional group is found in compounds called __________ _____________________12. A double-bonded oxygen and an –OH are bonded onto the same carbon atom is in compounds called . _____________________13. Each carbon atom can make ____covalent bonds. MULTIPLE CHOICE ______ 1. C5H8 and C3H4 are classified as A. alkanes B. alkynes C. alkenes D. isomers ______ 2. C2H6 and C3H8 are members of an A. alkane series B. alkene series C. alkyne series D. alcohol series ______ 3. C3H6 and C8H16 are alike in that they both contain A. a double bond in the carbon chain C. only single-bonded carbon atoms B. a triple bond in the carbon chain D. a double-bonded hydrogen atom ______ 4. The functional group –NH2 is found in compounds called A. aldehydes B. organic acids C. esters D. amines ______ 5. An alkane has a general formula of A. CnH2n B. CnH2n+2 D. C2n-2Hn C. C2n+2Hn ______ 6. Compounds with the same composition and different properties are called A. isotopes B. isomers C. functional groups D. homologs ______ 7. The name for C7H12 is A. hexyne C. nonane D. heptyne ______ 8. Saturated hydrocarbons belong to the series called A. alkanes B. alkynes C. alkones D. alkenes ______ 9. The name for the ketone functional group is A. carbonyl B. hydroxyl D. phosphate B. octane C. carboxyl 11 Name the compounds: a) H – C≡C – H H H | | d) H – C = C – C – H | | H H a) ___________________________ b) ___________________________ c) ___________________________ H H H H | | | | b) H – C – C - C – C – H | | | | H H H H H | e). H – C – H | H d) ___________________________ e) ___________________________ H H H H | | | | c) H – C – C – C – C = C – H | | | | H H H H Answer the following questions 1. What is the general formula for all alkenes? _______________________________ 2. What is the general formula for all alkynes? _______________________________ 3. Why can there not be a methene or methyne? ______________________________________________ ____________________________________________________________________________________ 4. What type of bond is found in hydrocarbons? _______________________ 5. Hydrocarbons can store a lot of energy because of numerous _______________________. 12