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Chapter 5
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Ionic compound



In chemistry, an ionic compound is a chemical compound in which ions are held together in a structure by electrostatic forces termed ionic bonds. The positively charged ions are called cations and the negatively charged ions are called anions. These can be simple ions such as the sodium (Na+) and chloride (Cl−) in sodium chloride, or polyatomic species such as the carbonate ion (CO32−) in calcium carbonate. Individual ions within an ionic compound usually have multiple nearest neighbours, so are not considered to be part of molecules, but instead part of a continuous three-dimensional network, usually in a crystalline structure.Ionic compounds typically have high melting and boiling points, and are hard and brittle. As solids they are almost always electrically insulating, but when melted or dissolved they become highly conductive, because the ions are mobilized.Ionic compounds without the acidic hydrogen ion (H+), or the basic ions hydroxide (OH−) or oxide (O2−), are also known as salts and can be formed by acid-base reactions. Ionic compounds containing hydrogen ions are classified as acids and compounds containing hydroxide or oxide ions are classified as bases.
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