
Exam 2
... Chern 24 2 (w 2016) exam #2B 1. (10 pts) Circle what is true about Substitution and elimination reactions. ...
... Chern 24 2 (w 2016) exam #2B 1. (10 pts) Circle what is true about Substitution and elimination reactions. ...
Explanation
... 2. Dry litmus paper is used to test water-soluble gas 3. Blue litmus paper is used to identify acids 4. Blue litmus paper is used to identify bases 5. None of these Correct Answer : c) Blue litmus paper is used to identify acids Explanation: Blue litmus paper turns into red color when it dips in aci ...
... 2. Dry litmus paper is used to test water-soluble gas 3. Blue litmus paper is used to identify acids 4. Blue litmus paper is used to identify bases 5. None of these Correct Answer : c) Blue litmus paper is used to identify acids Explanation: Blue litmus paper turns into red color when it dips in aci ...
CHEM 1211 and CHEM 1212 National ACS Exams About the Exam
... submicroscopic (chemical) world. As such, the ACS tests seek to uncover such genuine understanding. CHEM 1211 Example Questions There is an emphasis on conceptual questions. The actual exam will be multiple choice. The below questions are guaranteed not to be on the exam. Atomic Structure 1 ...
... submicroscopic (chemical) world. As such, the ACS tests seek to uncover such genuine understanding. CHEM 1211 Example Questions There is an emphasis on conceptual questions. The actual exam will be multiple choice. The below questions are guaranteed not to be on the exam. Atomic Structure 1 ...
Slide 1
... A crown ether specifically binds certain metal ions or organic molecules to form a host–guest complex, an example of molecular recognition ...
... A crown ether specifically binds certain metal ions or organic molecules to form a host–guest complex, an example of molecular recognition ...
Honors Chemistry
... However, this is not the only driving force. Entropy (S): the measure of in a system. The higher disorder (more S), the likely the reaction is to occur (messy room, leaves on trees). Systems tend to go towards ...
... However, this is not the only driving force. Entropy (S): the measure of in a system. The higher disorder (more S), the likely the reaction is to occur (messy room, leaves on trees). Systems tend to go towards ...
I - USC Upstate: Faculty
... c) Conjugation of double bond – lower double bond character and increase bond order of C-C (1) C=O stretching frequency lowered by 20-30 cm-1for alpha-beta unsaturated (2) Isoprene 1637, 1604 (3) 1,4-pentadiene 1644 G. Constitutional (structural) Isomerism 1. C3H7O2N a) Amino acid alanine b) Urethan ...
... c) Conjugation of double bond – lower double bond character and increase bond order of C-C (1) C=O stretching frequency lowered by 20-30 cm-1for alpha-beta unsaturated (2) Isoprene 1637, 1604 (3) 1,4-pentadiene 1644 G. Constitutional (structural) Isomerism 1. C3H7O2N a) Amino acid alanine b) Urethan ...
Template for calculating the ΔH° in a multiple step chemical reaction
... 1. Calculate the Standard Enthalpy Δ for the reaction... 2 Al(s) + Fe2O2(s) → 2Fe(s) + Al2O3(s) ...given that... ...
... 1. Calculate the Standard Enthalpy Δ for the reaction... 2 Al(s) + Fe2O2(s) → 2Fe(s) + Al2O3(s) ...given that... ...
Rate of Reaction
... Rate of Reaction Rates of reactions are usually expressed in units of moles per liter per unit time. If we know the chemical equation for a reaction, its rate can be determined by following the change in concentration of any product or reactant that can be detected quantitatively. r = ∆ concentratio ...
... Rate of Reaction Rates of reactions are usually expressed in units of moles per liter per unit time. If we know the chemical equation for a reaction, its rate can be determined by following the change in concentration of any product or reactant that can be detected quantitatively. r = ∆ concentratio ...
(substituted) carbon
... Hydroboration-oxidation of alkenes allows stereospecific and regioselective synthesis of alcohols. The reaction sequence exhibits anti-Markovnikov regioselectivity which complements acid-catalyzed hydration and oxymercurationdemercuration. The reaction mechanism does not involve a carbocation and t ...
... Hydroboration-oxidation of alkenes allows stereospecific and regioselective synthesis of alcohols. The reaction sequence exhibits anti-Markovnikov regioselectivity which complements acid-catalyzed hydration and oxymercurationdemercuration. The reaction mechanism does not involve a carbocation and t ...
File - cpprashanths Chemistry
... 2. Question No. 1-8 are very short answer questions and carry 1 mark each. 3. Question No. 9-18 are short answer questions and carry 2 marks each. 4. Question No. 19-27 are also short answer questions and carry 3 marks each. 5. Question No. 28-30 are long answer questions and carry 5 marks each. 6. ...
... 2. Question No. 1-8 are very short answer questions and carry 1 mark each. 3. Question No. 9-18 are short answer questions and carry 2 marks each. 4. Question No. 19-27 are also short answer questions and carry 3 marks each. 5. Question No. 28-30 are long answer questions and carry 5 marks each. 6. ...
Part (d) The Birch Reduction of Nitrogen
... When nucleophiles attack the C=O group they do so by passing electrons from their highest occupied molecular orbital (HOMO) to the lowest unoccupied molecular orbital (LUMO) of the carbonyl ie. Negatively charged species are also attracted to the electron deficient carbon atom. So, in the addition ...
... When nucleophiles attack the C=O group they do so by passing electrons from their highest occupied molecular orbital (HOMO) to the lowest unoccupied molecular orbital (LUMO) of the carbonyl ie. Negatively charged species are also attracted to the electron deficient carbon atom. So, in the addition ...
chapter 1 - Revsworld
... Which of the following statements is/are correct? I. When heat energy flows from a system to the surroundings, we know that the temperature of the system is greater than that of the surroundings. II. Given the thermochemical equation 4NH3(g) + 5O2(g) ------> 4 NO(g) + 6H2O(g) H = -906 kJ, the therm ...
... Which of the following statements is/are correct? I. When heat energy flows from a system to the surroundings, we know that the temperature of the system is greater than that of the surroundings. II. Given the thermochemical equation 4NH3(g) + 5O2(g) ------> 4 NO(g) + 6H2O(g) H = -906 kJ, the therm ...
Page 1 - WordPress.com
... (b) A compound contains 10.1% carbon and 89.9% chlorine by mass. Calculate the molecular formula of this compound, given that its relative molecular mass (Mr) is 237.0 (3) (c) Sug ...
... (b) A compound contains 10.1% carbon and 89.9% chlorine by mass. Calculate the molecular formula of this compound, given that its relative molecular mass (Mr) is 237.0 (3) (c) Sug ...
QuickStudy - Organic Chemistry Fundamentals
... solvent molecules, creating a more stable system • miscible (2 or more substances form 1 phase): liquids with similar molecular properties (polar+polar, nonpolar+non-polar) • immiscible (separate phases): aqueous and organic layers do not mix • Compounds are partitioned between the layers based on c ...
... solvent molecules, creating a more stable system • miscible (2 or more substances form 1 phase): liquids with similar molecular properties (polar+polar, nonpolar+non-polar) • immiscible (separate phases): aqueous and organic layers do not mix • Compounds are partitioned between the layers based on c ...
CHEM 313 - Suraj @ LUMS
... There will be class quizzes and homework assignments on week-to-week basis. There will be additional class assignments along with a mid-term exam and final exam. Class quizzes will be taken as and when the instructor wishes to do so. Each homework assignment will involve class-based exercises and ke ...
... There will be class quizzes and homework assignments on week-to-week basis. There will be additional class assignments along with a mid-term exam and final exam. Class quizzes will be taken as and when the instructor wishes to do so. Each homework assignment will involve class-based exercises and ke ...
Chapter 8 – Covalent Bonding
... Double Covalent Bond – a bond that involves two shared pairs of electrons Triple Covalent Bond – a bond that involves three shared pairs of electrons Let’s Practice ...
... Double Covalent Bond – a bond that involves two shared pairs of electrons Triple Covalent Bond – a bond that involves three shared pairs of electrons Let’s Practice ...
Year 13 Organic Chemistry Test
... _____________________________________________________ _____________________________________________________ A second alcohol, 2-methyl propan-2-ol, will not give a positive breathalyzer test. Why not? _____________________________________________________ _____________________________________________ ...
... _____________________________________________________ _____________________________________________________ A second alcohol, 2-methyl propan-2-ol, will not give a positive breathalyzer test. Why not? _____________________________________________________ _____________________________________________ ...
File
... Acids will have a low pH (high pOH), which means there are more H3O+/H+ ions than OH- ions Bases will have a high pH (low pOH), which means there are more OH- ions than H3O+/H+ ions Need to know how to predict the direction of an acid-base reaction o Identify the acid or base on both the reactant si ...
... Acids will have a low pH (high pOH), which means there are more H3O+/H+ ions than OH- ions Bases will have a high pH (low pOH), which means there are more OH- ions than H3O+/H+ ions Need to know how to predict the direction of an acid-base reaction o Identify the acid or base on both the reactant si ...
Alkenes undergo Addition Reactions Predict the product of each
... α-Substituted amides are important building blocks in medicinal chemistry for the synthesis of antibiotics and peptide-based ...
... α-Substituted amides are important building blocks in medicinal chemistry for the synthesis of antibiotics and peptide-based ...
Carboxylic Acid Derivatives
... by the oxygen atom of that group. This type of reaction, in which an atom or group is replaced by another atom or group, is called a substitution reaction. We can begin to connect this reaction type with what we have seen earlier by thinking about the mechanism. We notice that the O- end of the grou ...
... by the oxygen atom of that group. This type of reaction, in which an atom or group is replaced by another atom or group, is called a substitution reaction. We can begin to connect this reaction type with what we have seen earlier by thinking about the mechanism. We notice that the O- end of the grou ...
Reaction rate and activation energy of the acidolysis
... 1.0 molar sodium hydroxide solution into a 1000 ml volumetric flask and filling up to the calibration mark with water. Fill the burette with 0.2 molar NaOH solution. Pipette 100 ml of 0.1 molar hydrochloric acid solution into an Erlenmeyer flask, seal it with a stopper, and temperature equilibrate i ...
... 1.0 molar sodium hydroxide solution into a 1000 ml volumetric flask and filling up to the calibration mark with water. Fill the burette with 0.2 molar NaOH solution. Pipette 100 ml of 0.1 molar hydrochloric acid solution into an Erlenmeyer flask, seal it with a stopper, and temperature equilibrate i ...
Chapter 10 Chemical Bonding Theories
... Bonds form using shared electrons between overlapping orbitals on adjacent atoms. Orbitals arrange around central atom to avoid each other. Two types of bonds: sigma and pi. ...
... Bonds form using shared electrons between overlapping orbitals on adjacent atoms. Orbitals arrange around central atom to avoid each other. Two types of bonds: sigma and pi. ...
Woodward–Hoffmann rules

The Woodward–Hoffmann rules, devised by Robert Burns Woodward and Roald Hoffmann, are a set of rules in organic chemistry predicting the barrier heights of pericyclic reactions based upon conservation of orbital symmetry. The Woodward–Hoffmann rules can be applied to understand electrocyclic reactions, cycloadditions (including cheletropic reactions), sigmatropic reactions, and group transfer reactions. Reactions are classified as allowed if the electronic barrier is low, and forbidden if the barrier is high. Forbidden reactions can still take place but require significantly more energy.The Woodward–Hoffmann rules were first formulated to explain the striking stereospecificity of electrocyclic reactions under thermal and photochemical control. Thermolysis of the substituted cyclobutene trans-1,2,3,4-tetramethylcyclobutene (1) gave only one diastereomer, the (E,E)-3,4-dimethyl-2,4-hexadiene (2) as shown below; the (Z,Z) and the (E,Z) diastereomers were not detected in the reaction. Similarly, thermolysis of cis-1,2,3,4-tetramethylcyclobutene (3) gave only the (E,Z) diastereomer (4).Due to their elegance and simplicity, the Woodward–Hoffmann rules are credited with first exemplifying the power of molecular orbital theory to experimental chemists. Hoffmann was awarded the 1981 Nobel Prize in Chemistry for this work, shared with Kenichi Fukui who developed a similar model using frontier molecular orbital (FMO) theory; because Woodward had died two years before, he was not eligible to win what would have been his second Nobel Prize for Chemistry.